Super-small particles of silicon react with water to produce hydrogen almost instantaneously, according to University at Buffalo researchers.
Transmission electron microscopy image showing spherical silicon nanoparticles about 10 nanometers in diameter. These particles, created in a UB lab, react with water to quickly produce hydrogen, according to new UB research. Credit: Swihart Research Group, University at Buffalo.
In a series of experiments, the scientists created spherical silicon particles about 10 nanometers in diameter. When combined with water, these particles reacted to form silicic acid (a nontoxic byproduct) and hydrogen — a potential source of energy for fuel cells.
The reaction didn’t require any light, heat or electricity, and also created hydrogen about 150 times faster than similar reactions using silicon particles 100 nanometers wide, and 1,000 times faster than bulk silicon, according to the study.
The findings appeared online in Nano Letters on Jan. 14. The scientists were able to verify that the hydrogen they made was relatively pure by testing it successfully in a small fuel cell that powered a fan.
“When it comes to splitting water to produce hydrogen, nanosized silicon may be better than more obvious choices that people have studied for a while, such as aluminum,” said researcher Mark T. Swihart, UB professor of chemical and biological engineering and director of the university’s Strategic Strength in Integrated Nanostructured Systems.
“With further development, this technology could form the basis of a ‘just add water’ approach to generating hydrogen on demand,” said researcher Paras Prasad, executive director of UB’s Institute for Lasers, Photonics and Biophotonics (ILPB) and a SUNY Distinguished Professor in UB’s Departments of Chemistry, Physics, Electrical Engineering and Medicine. “The most practical application would be for portable energy sources.”
Swihart and Prasad led the study, which was completed by UB scientists, some of whom have affiliations with Nanjing University in China or Korea University in South Korea. Folarin Erogbogbo, a research assistant professor in UB’s ILPB and a UB PhD graduate, was first author.
The speed at which the 10-nanometer particles reacted with water surprised the researchers. In under a minute, these particles yielded more hydrogen than the 100-nanometer particles yielded in about 45 minutes. The maximum reaction rate for the 10-nanometer particles was about 150 times as fast.
Swihart said the discrepancy is due to geometry. As they react, the larger particles form nonspherical structures whose surfaces react with water less readily and less uniformly than the surfaces of the smaller, spherical particles, he said.
Though it takes significant energy and resources to produce the super-small silicon balls, the particles could help power portable devices in situations where water is available and portability is more important than low cost. Military operations and camping trips are two examples of such scenarios.
“It was previously unknown that we could generate hydrogen this rapidly from silicon, one of Earth’s most abundant elements,” Erogbogbo said. “Safe storage of hydrogen has been a difficult problem even though hydrogen is an excellent candidate for alternative energy, and one of the practical applications of our work would be supplying hydrogen for fuel cell power. It could be military vehicles or other portable applications that are near water.”
“Perhaps instead of taking a gasoline or diesel generator and fuel tanks or large battery packs with me to the campsite (civilian or military) where water is available, I take a hydrogen fuel cell (much smaller and lighter than the generator) and some plastic cartridges of silicon nanopowder mixed with an activator,” Swihart said, envisioning future applications. “Then I can power my satellite radio and telephone, GPS, laptop, lighting, etc. If I time things right, I might even be able to use excess heat generated from the reaction to warm up some water and make tea.”Media Contact Information
Charlotte Hsu | EurekAlert!
Silicon solar cell of ISFH yields 25% efficiency with passivating POLO contacts
08.12.2016 | Institut für Solarenergieforschung GmbH
Robot on demand: Mobile machining of aircraft components with high precision
06.12.2016 | Fraunhofer IFAM
In recent years, lasers with ultrashort pulses (USP) down to the femtosecond range have become established on an industrial scale. They could advance some applications with the much-lauded “cold ablation” – if that meant they would then achieve more throughput. A new generation of process engineering that will address this issue in particular will be discussed at the “4th UKP Workshop – Ultrafast Laser Technology” in April 2017.
Even back in the 1990s, scientists were comparing materials processing with nanosecond, picosecond and femtosesecond pulses. The result was surprising:...
Have you ever wondered how you see the world? Vision is about photons of light, which are packets of energy, interacting with the atoms or molecules in what...
A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.
Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...
In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.
“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...
The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.
The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...
16.11.2016 | Event News
01.11.2016 | Event News
14.10.2016 | Event News
08.12.2016 | Life Sciences
08.12.2016 | Physics and Astronomy
08.12.2016 | Materials Sciences