That is the surprising result of a new characterization method that uses a combination of lasers and acoustic waves to provide scientists with a capability tantamount to X-ray vision: It allows them to peer through solid materials to pinpoint the size and location of detects buried deep inside with unprecedented precision.
The research, which was conducted by post-doctoral fellow Andrew Steigerwald under the supervision of Physics Professor Norman Tolk, was published online on July 19 in the Journal of Applied Physics.
"The ability to accurately measure the defects in electronic materials becomes increasingly important as the size of microelectronic devices continues to shrink," Tolk explained. "When an individual transistor contains millions of atoms, it can absorb quite a bit of damage before it fails. But when a transistor contains a few thousand atoms, a single defect can cause it to stop working."
Previous methods used to study damage in electronic materials have been limited to looking at defects and deformations in the atomic lattice. The new method is the first that is capable of detecting disruption in the positions of the electrons that are attached to the atoms. This is particularly important because it is the behavior of the electrons that determine a material's electrical and optical properties.
"An analogy is a thousand people floating in a swimming pool. The people represent the atoms and the water represents the electrons," said Steigerwald. "If another person – representing an energetic particle – jumps into the pool, the people in his vicinity change their positions slightly to make room for him. However, these shifts can be fairly subtle and difficult to measure. But the jumper will also cause quite a splash and cause the level of the water in the pool to rise. Much like the water in the pool, the electrons in a material are more sensitive to defects than the atoms."
To detect the electron dislocations, the physicists upgraded a 15-year-old method called coherent acoustic phonon spectroscopy (CAPS).
"CAPS is similar to the seismic techniques that energy companies use to search for underground oil deposits, only on a much smaller scale," said Steigerwald.
Oil explorers set off a series of small explosions on the surface and measure the sound waves that are reflected back to the surface. That allows them to identify and map the layers of different types of rock thousands of feet underground.
Similarly, CAPS generates a pressure wave that passes through a chunk of semiconductor by blasting its surface with an ultrafast pulse of laser light. As this happens, the researchers bounce a second laser off the pressure wave and measure the strength of the reflection. As the pressure wave encounters defects and deformities in the material, its reflectivity changes and this alters the strength of the reflected laser light. By measuring these variations, the physicists can detect individual defects and measure the effect that they have on the material's electrical and optical properties.
The physicists tested their technique on a layer of gallium arsenide semiconductor that they had irradiated with high-energy neon atoms. They found that the structural damage caused by an embedded neon atom spread over a volume containing 1,000 atoms – considerably more extensive than that shown by other techniques.
"This is significant because today people are creating nanodevices that contain thousands of atoms," said Steigerwald. One of these devices is a solar collector made from quantum dots, tiny semiconductor beads that each contains a few thousand atoms. "Our results may explain recent studies that have found that these quantum-dot solar collectors are less efficient than predicted," he said.
"The fact is that we really don't understand how any atomic-scale defect affects the performance on an optoelectronic device," said Tolk. "Techniques like the one that we have developed will give us the detailed information we need to figure this out and so help people make nanodevices that work properly."
Research Associate Professor Anthony B. Hmelo, Assistant Professor Kalman Varga and Stevenson Professor of Physics Leonard Feldman also contributed to the research.
The research was supported by Department of Energy grant FG02-99ER45781, Army Research Office grant W911NF-07-R-0003-02 and National Science Foundation grant ECCS0925422. In addition, portions of the work were performed at the Vanderbilt Institute of Nanoscale Science and Engineering, using facilities renovated with the NSF grant ARI-RW DMR-096331.
Visit Research News @ Vanderbilt for more research news from Vanderbilt. [Media Note: Vanderbilt has a 24/7 TV and radio studio with a dedicated fiber optic line and ISDN line. Use of the TV studio with Vanderbilt experts is free, except for reserving fiber time.]
David Salisbury | EurekAlert!
Further reports about: > Caps > Radiation > atomic-scale defect affects > coherent acoustic phonon spectroscopy > combination of lasers > electronic material > energetic particle > gallium arsenide semiconductor > laser light > optical properties > quantum dot > solar collector > sound wave > ultrafast pulse of laser light
Significantly more productivity in USP lasers
06.12.2016 | Fraunhofer-Institut für Lasertechnik ILT
Shape matters when light meets atom
05.12.2016 | Centre for Quantum Technologies at the National University of Singapore
In recent years, lasers with ultrashort pulses (USP) down to the femtosecond range have become established on an industrial scale. They could advance some applications with the much-lauded “cold ablation” – if that meant they would then achieve more throughput. A new generation of process engineering that will address this issue in particular will be discussed at the “4th UKP Workshop – Ultrafast Laser Technology” in April 2017.
Even back in the 1990s, scientists were comparing materials processing with nanosecond, picosecond and femtosesecond pulses. The result was surprising:...
Have you ever wondered how you see the world? Vision is about photons of light, which are packets of energy, interacting with the atoms or molecules in what...
A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.
Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...
In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.
“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...
The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.
The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...
16.11.2016 | Event News
01.11.2016 | Event News
14.10.2016 | Event News
06.12.2016 | Materials Sciences
06.12.2016 | Medical Engineering
06.12.2016 | Power and Electrical Engineering