Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:


Recipe for Low-Cost, Biomass-Derived Catalyst for Hydrogen Production

Promising results are a step toward a range of renewable energy strategies fueled by Nature

In a paper to be published in an upcoming issue of Energy & Environmental Science (now available online), researchers at the U.S. Department of Energy’s Brookhaven National Laboratory describe details of a low-cost, stable, effective catalyst that could replace costly platinum in the production of hydrogen.

The catalyst, made from renewable soybeans and abundant molybdenum metal, produces hydrogen in an environmentally friendly, cost-effective manner, potentially increasing the use of this clean energy source.

The research has already garnered widespread recognition for Shilpa and Shweta Iyer, twin-sister high school students who contributed to the research as part of an internship under the guidance of Brookhaven chemist Wei-Fu Chen, supported by projects led by James Muckerman, Etsuko Fujita, and Kotaro Sasaki.

“This paper reports the ‘hard science’ from what started as the Iyer twins’ research project and has resulted in the best-performing, non-noble-metal-containing hydrogen evolution catalyst yet known—even better than bulk platinum metal,” Muckerman said.

The project branches off from the Brookhaven group’s research into using sunlight to develop alternative fuels. Their ultimate goal is to find ways to use solar energy—either directly or via electricity generated by solar cells—to convert the end products of hydrocarbon combustion, water and carbon dioxide, back into a carbon-based fuel. Dubbed “artificial photosynthesis,” this process mimics how plants convert those same ingredients to energy in the form of sugars. One key step is splitting water, or water electrolysis.

“By splitting liquid water (H2O) into hydrogen and oxygen, the hydrogen can be regenerated as a gas (H2) and used directly as fuel,” Sasaki explained. “We sought to fabricate a commercially viable catalyst from earth-abundant materials for application in water electrolysis, and the outcome is indeed superb.”

This form of hydrogen production could help the scientists achieve their ultimate goal.

“A very promising route to making a carbon-containing fuel is to hydrogenate carbon dioxide (or carbon monoxide) using solar-produced hydrogen,” said Fujita, who leads the artificial photosynthesis group in the Brookhaven Chemistry Department.

But with platinum as the main ingredient in the most effective water-splitting catalysts, the process is currently too costly to be economically viable.

Comsewogue High School students Shweta and Shilpa Iyer entered the lab as the search for a cost-effective replacement was on.

The Brookhaven team had already identified some promising leads with experiments demonstrating the potential effectiveness of low-cost molybdenum paired with carbon, as well as the use of nitrogen to confer some resistance to the corrosive, acidic environment required in proton exchange membrane water electrolysis cells. But these two approaches had not yet been tried together.

The students set out to identify plentiful and inexpensive sources of carbon and nitrogen, and test ways to combine them with a molybdenum salt.

“The students became excited about using familiar materials from their everyday lives to meet a real-world energy challenge,” Chen recounted. The team tested a wide variety of sources of biomass—leaves, stems, flowers, seeds, and legumes—with particular interest in those with high protein content because the amino acids that make up proteins are a rich source of nitrogen. High-protein soybeans turned out to be the best.

To make the catalyst the team ground the soybeans into a powder, mixed the powder with ammonium molybdate in water, then dried and heated the samples in the presence of inert argon gas. “A subsequent high temperature treatment (carburization) induced a reaction between molybdenum and the carbon and nitrogen components of the soybeans to produce molybdenum carbides and molybdenum nitrides,” Chen explained. “The process is simple, economical, and environmentally friendly.”

Electrochemical tests of the separate ingredients showed that molybdenum carbide is effective for converting H2O to H2, but not stable in acidic solution, while molybdenum nitride is corrosion-resistant but not efficient for hydrogen production. A nanostructured hybrid of these two materials, however, remained active and stable even after 500 hours of testing in a highly acidic environment.

“We attribute the high activity of the molybdenum-soy catalyst (MoSoy) to the synergistic effect between the molybdenum-carbide phase and the molybdenum-nitride phase in the composite material,” Chen said.

Structural and chemical studies of the new catalyst conducted at Brookhaven’s National Synchrotron Light Source (NSLS) and the Center for Functional Nanomaterials (CFN) are also reported in the paper, and provide further details underlying the high performance of this new catalyst.

“The presence of nitrogen and carbon atoms in the vicinity of the catalytic molybdenum center facilitates the production of hydrogen from water,” Muckerman said.

The scientists also tested the MoSoy catalyst anchored on sheets of graphene—an approach that has proven effective for enhancing catalyst performance in electrochemical devices such as batteries, supercapacitors, fuel cells, and water electrolyzers. Using a high-resolution transmission microscope in Brookhven’s Condensed Matter Physics and Materials Science Department, the scientists were able to observe the anchored MoSoy nanocrystals on 2D graphene sheets.

The graphene-anchored MoSoy catalyst surpassed the performance of pure platinum metal. Though not quite as active as commercially available platinum catalysts, the high performance of graphene-anchored MoSoy was extremely encouraging to the scientific team.

“The direct growth of anchored MoSoy nanocrystals on graphene sheets may enhance the formation of strongly coupled hybrid materials with intimate, seamless electron transfer pathways, thus accelerating the electron transfer rate for the chemical desorption of hydrogen from the catalyst, further reducing the energy required for the reaction to take place,” Sasaki said.

The scientists are conducting additional studies to gain a deeper understanding of the nature of the interaction at the catalyst-graphene interface, and exploring ways to further improve its performance.

In the paper, the authors—including the two high-school students—conclude: “This study unambiguously provides evidence that a cheap and earth-abundant transition metal such as molybdenum can be turned into an active catalyst by the controlled solid-state reaction with soybeans…The preparation of the MoSoy catalyst is simple and can be easily scaled up. Its long-term durability and ultra-low capital cost satisfy the prerequisites for its application in the construction of large-scale devices. These findings thus open up new prospects for combining inexpensive biomass and transition metals…to produce catalysts for electro-catalytic reactions.”

Additional collaborators in this research were Chiu-Hui Wang and Yimei Zhu of Brookhaven Lab.

This research was funded by the DOE Office of Science, Brookhaven’s Laboratory Directed Research and Development program, its Technology Maturation program, and funding through the Office of Science for Brookhaven’s Office of Educational Programs. NSLS and CFN are also supported by the DOE Office of Science.

The Center for Functional Nanomaterials is one of the five DOE Nanoscale Science Research Centers, premier national user facilities for interdisciplinary research at the nanoscale supported by the U.S. Department of Energy, Office of Science. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge, Sandia and Los Alamos National Laboratories. For more information about the DOE NSRCs, please click here.

DOE’s Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit

One of ten national laboratories overseen and primarily funded by the Office of Science of the U.S. Department of Energy (DOE), Brookhaven National Laboratory conducts research in the physical, biomedical, and environmental sciences, as well as in energy technologies and national security. Brookhaven Lab also builds and operates major scientific facilities available to university, industry, and government researchers. Brookhaven is operated and managed for DOE’s Office of Science by Brookhaven Science Associates, a limited-liability company founded by the Research Foundation of the State University of New York, for and on behalf of Stony Brook University, the largest academic user of Laboratory facilities; and Battelle Memorial Institute, a nonprofit, applied science and technology organization. Visit Brookhaven Lab's electronic newsroom for links, news archives, graphics, and more ( or follow Brookhaven Lab on Twitter (

People pic:
Wei-Fu Chen, Shweta Iyer, James Muckerman, Sasaki Kotaro, Etsuko Fujita, and Shilpa Iyer
Splitting hydrogen from water: This illustration depicts the synthesis of a new hydrogen-production catalyst from soybean proteins and ammonium molybdate. Mixing and heating the ingredients leads to a solid-state reaction and the formation of nanostructured molybdenum carbide and molybdenum nitride crystals. The hybrid material effectively catalyzes the conversion of liquid water to hydrogen gas while remaining stable in an acidic environment.

Karen McNulty Walsh | Newswise
Further information:

More articles from Power and Electrical Engineering:

nachricht Producing electricity during flight
20.09.2017 | Albert-Ludwigs-Universität Freiburg im Breisgau

nachricht Solar-to-fuel system recycles CO2 to make ethanol and ethylene
19.09.2017 | DOE/Lawrence Berkeley National Laboratory

All articles from Power and Electrical Engineering >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: The pyrenoid is a carbon-fixing liquid droplet

Plants and algae use the enzyme Rubisco to fix carbon dioxide, removing it from the atmosphere and converting it into biomass. Algae have figured out a way to increase the efficiency of carbon fixation. They gather most of their Rubisco into a ball-shaped microcompartment called the pyrenoid, which they flood with a high local concentration of carbon dioxide. A team of scientists at Princeton University, the Carnegie Institution for Science, Stanford University and the Max Plank Institute of Biochemistry have unravelled the mysteries of how the pyrenoid is assembled. These insights can help to engineer crops that remove more carbon dioxide from the atmosphere while producing more food.

A warming planet

Im Focus: Highly precise wiring in the Cerebral Cortex

Our brains house extremely complex neuronal circuits, whose detailed structures are still largely unknown. This is especially true for the so-called cerebral cortex of mammals, where among other things vision, thoughts or spatial orientation are being computed. Here the rules by which nerve cells are connected to each other are only partly understood. A team of scientists around Moritz Helmstaedter at the Frankfiurt Max Planck Institute for Brain Research and Helene Schmidt (Humboldt University in Berlin) have now discovered a surprisingly precise nerve cell connectivity pattern in the part of the cerebral cortex that is responsible for orienting the individual animal or human in space.

The researchers report online in Nature (Schmidt et al., 2017. Axonal synapse sorting in medial entorhinal cortex, DOI: 10.1038/nature24005) that synapses in...

Im Focus: Tiny lasers from a gallery of whispers

New technique promises tunable laser devices

Whispering gallery mode (WGM) resonators are used to make tiny micro-lasers, sensors, switches, routers and other devices. These tiny structures rely on a...

Im Focus: Ultrafast snapshots of relaxing electrons in solids

Using ultrafast flashes of laser and x-ray radiation, scientists at the Max Planck Institute of Quantum Optics (Garching, Germany) took snapshots of the briefest electron motion inside a solid material to date. The electron motion lasted only 750 billionths of the billionth of a second before it fainted, setting a new record of human capability to capture ultrafast processes inside solids!

When x-rays shine onto solid materials or large molecules, an electron is pushed away from its original place near the nucleus of the atom, leaving a hole...

Im Focus: Quantum Sensors Decipher Magnetic Ordering in a New Semiconducting Material

For the first time, physicists have successfully imaged spiral magnetic ordering in a multiferroic material. These materials are considered highly promising candidates for future data storage media. The researchers were able to prove their findings using unique quantum sensors that were developed at Basel University and that can analyze electromagnetic fields on the nanometer scale. The results – obtained by scientists from the University of Basel’s Department of Physics, the Swiss Nanoscience Institute, the University of Montpellier and several laboratories from University Paris-Saclay – were recently published in the journal Nature.

Multiferroics are materials that simultaneously react to electric and magnetic fields. These two properties are rarely found together, and their combined...

All Focus news of the innovation-report >>>



Event News

“Lasers in Composites Symposium” in Aachen – from Science to Application

19.09.2017 | Event News

I-ESA 2018 – Call for Papers

12.09.2017 | Event News

EMBO at Basel Life, a new conference on current and emerging life science research

06.09.2017 | Event News

Latest News

Rainbow colors reveal cell history: Uncovering β-cell heterogeneity

22.09.2017 | Life Sciences

Penn first in world to treat patient with new radiation technology

22.09.2017 | Medical Engineering

Calculating quietness

22.09.2017 | Physics and Astronomy

More VideoLinks >>>