A paperlike battery electrode developed by a Kansas State University engineer may improve tools for space exploration or unmanned aerial vehicles.
Gurpreet Singh, associate professor of mechanical and nuclear engineering, and his research team created the battery electrode using silicon oxycarbide-glass and graphene.
The battery electrode has all the right characteristics. It is more than 10 percent lighter than other battery electrodes. It has close to 100 percent cycling efficiency for more than 1000 charge discharge cycles. It is made of low-cost materials that are byproducts of the silicone industry. And it functions at temperatures as low as minus 15 degrees C, which gives it numerous aerial and space applications.
The research appears in Nature Communications article "Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries."
Singh's research team has been exploring new material combinations for batteries and electrode design. It has been difficult to incorporate graphene and silicon into practical batteries because of challenges that arise at high mass loadings -- such as low capacity per volume, poor cycling efficiency and chemical-mechanical instability.
Singh's team has addressed these challenges by manufacturing a self-supporting and ready-to-go electrode that consists of a glassy ceramic called silicon oxycarbide sandwiched between large platelets of chemically modified graphene, or CMG. The electrode has a high capacity of approximately 600 miliampere-hours per gram -- 400 miliampere-hours per cubic centimeter -- that is derived from silicon oxycarbide. The paperlike design is made of 20 percent chemically modified graphene platelets.
"The paperlike design is markedly different from the electrodes used in present day batteries because it eliminates the metal foil support and polymeric glue -- both of which do not contribute toward capacity of the battery," Singh said.
The design that Singh's team developed saved approximately 10 percent in total weight of the cell. The result is a lightweight electrode capable of storing lithium-ion and electrons with near 100 percent cycling efficiency for more than 1000 charge discharge cycles. The most important aspect is that the material is able to demonstrate such performance at practical levels, Singh said.
The paper electrode cells also are able to deliver a capacity of 200 miliampere-hour per gram even when kept at minus 15 degrees C for about a month, which is quite remarkable considering that most batteries fail to perform at such low temperatures, Singh said.
"This suggests that rechargeable batteries from silicon-glass and graphene electrodes may also be suitable for unmanned aerial vehicles flying at high altitudes, or maybe even space applications," Singh said.
The silicon oxycarbide material itself is quite special, Singh said. It is prepared by heating a liquid resin to the point where it decomposes and transforms into sharp glasslike particles. The silicon, carbon and oxygen atoms get rearranged into random 3-D structure and any excess carbon precipitates out into cellular regions. Such an open 3-D structure creates large sites for reversible lithium storage and smooth channels for lithium-ion transportation. This structure and mechanism of lithium storage is different than crystalline silicon electrodes. Silicon oxycarbide electrodes are expected to be low cost because the raw material -- liquid resin -- is a byproduct of the silicone industry.
Moving forward, Singh and his team want to address practical challenges. Singh's goal is to produce this electrode material at even larger dimensions. For example, present-day pencil-cell batteries use graphite-coated copper foil electrodes that are more than one foot in length. The team also would like to perform mechanical bending tests to see how they affect performance parameters.
"Ultimately, we would like to work with industry to explore production of lithium-ion battery full-cells," Singh said. "Silicon oxycarbide can also be prepared by 3-D printing, which is another area of interest to us."
The research received funding from the National Science Foundation, including Singh's $500,000 CAREER award.
Other Kansas State University researchers involved include Lamuel David, 2015 doctoral graduate in mechanical engineering, Oak Ridge, Tennessee; Romil Bhandavat, 2013 doctoral graduate in mechanical engineering, Hillsboro, Oregon; and Uriel Barrera, 2015 bachelors graduate in mechanical engineering, Olathe.
Gurpreet Singh | EurekAlert!
Perovskite-silicon solar cell research collaboration hits 25.2% efficiency
15.06.2018 | Helmholtz-Zentrum Berlin für Materialien und Energie GmbH
Second heat source optimises heat pump system
12.06.2018 | FIZ Karlsruhe – Leibniz-Institut für Informationsinfrastruktur GmbH
Moving into its fourth decade, AchemAsia is setting out for new horizons: The International Expo and Innovation Forum for Sustainable Chemical Production will take place from 21-23 May 2019 in Shanghai, China. With an updated event profile, the eleventh edition focusses on topics that are especially relevant for the Chinese process industry, putting a strong emphasis on sustainability and innovation.
Founded in 1989 as a spin-off of ACHEMA to cater to the needs of China’s then developing industry, AchemAsia has since grown into a platform where the latest...
The BMBF-funded OWICELLS project was successfully completed with a final presentation at the BMW plant in Munich. The presentation demonstrated a Li-Fi communication with a mobile robot, while the robot carried out usual production processes (welding, moving and testing parts) in a 5x5m² production cell. The robust, optical wireless transmission is based on spatial diversity; in other words, data is sent and received simultaneously by several LEDs and several photodiodes. The system can transmit data at more than 100 Mbit/s and five milliseconds latency.
Modern production technologies in the automobile industry must become more flexible in order to fulfil individual customer requirements.
An international team of scientists has discovered a new way to transfer image information through multimodal fibers with almost no distortion - even if the fiber is bent. The results of the study, to which scientist from the Leibniz-Institute of Photonic Technology Jena (Leibniz IPHT) contributed, were published on 6thJune in the highly-cited journal Physical Review Letters.
Endoscopes allow doctors to see into a patient’s body like through a keyhole. Typically, the images are transmitted via a bundle of several hundreds of optical...
Light detection and control lies at the heart of many modern device applications, such as smartphone cameras. Using graphene as a light-sensitive material for...
Water molecules exist in two different forms with almost identical physical properties. For the first time, researchers have succeeded in separating the two forms to show that they can exhibit different chemical reactivities. These results were reported by researchers from the University of Basel and their colleagues in Hamburg in the scientific journal Nature Communications.
From a chemical perspective, water is a molecule in which a single oxygen atom is linked to two hydrogen atoms. It is less well known that water exists in two...
13.06.2018 | Event News
08.06.2018 | Event News
05.06.2018 | Event News
15.06.2018 | Materials Sciences
15.06.2018 | Ecology, The Environment and Conservation
15.06.2018 | Power and Electrical Engineering