New method verifies carbon capture in concrete

Carbon emissions from burning fossil fuels contains very little carbon-14 (14C) because it has decayed so much over time. This makes carbon-14 very useful for tracing carbon emissions from natural compared to human sources.
Credit: 2023, Ippei Maruyama

Confirming CO2 origins could be useful for emissions trading.

Carbon capture is essential to reduce the impact of human carbon dioxide emissions on our climate. Researchers at the University of Tokyo and Nagoya University in Japan have developed a method to confirm whether carbon in concrete originates from the raw materials, or from carbon in the air which has been trapped when it reacts with the concrete to form the mineral calcium carbonate. By measuring the ratio of certain carbon isotopes in concrete that had been exposed to the air and concrete that hadn’t, the team could successfully verify that direct air carbon capture had occurred.  This method could be useful for the industrial sector and countries looking to offset their carbon emissions.

2023 is on the way to becoming the hottest year on record. Rice crops wilted in Japan and roads melted in the U.S. Despite international agreements and calls to action, greenhouse gas emissions from fossil fuels have continued to increase. If we are to prevent the planet from tipping over the critical threshold of a 2-degree-Celsius temperature rise by 2100 (compared to preindustrial levels), we need to do more. According to the United Nations’ Intergovernmental Panel on Climate Change, reducing and preventing further emissions alone is not enough. We must also remove carbon dioxide from the atmosphere if we are to hit our target.

Direct air capture (DAC) pulls carbon dioxide from the air using chemicals or physical processes. Increasing the use of DAC technologies is part of the International Energy Agency’s (IEA) net-zero emissions scenario, a proposed range of methods to enable the global energy sector to remove as much carbon dioxide (CO2) as it emits by 2050. According to the IEA, industry was responsible for a quarter of global energy system CO2 emissions in 2022. Cement is the second-most widely used industrial product (after water), and it comes with a high environmental burden.

“As much as 800 kilograms of CO2 is emitted per ton of cement during its production, so reducing emissions has become a significant issue in the concrete industry,” explained Professor Ippei Maruyama from the Department of Architecture at the University of Tokyo Graduate School of Engineering. “Concrete has long been known to react with CO2 in the air to form calcium carbonate, an undesirable phenomenon because it induces corrosion of the steel bars inside concrete structures. However, the concrete industry is now considering ways to make effective use of this reaction.”

Although problematic for construction, the reaction which causes calcium carbonate to form fixes or traps CO2, removing the gas from the atmosphere. Calcium carbonate is also found naturally in rocks, such as limestone, which are used in concrete manufacturing. “This makes it difficult to distinguish whether or not CO2 identified in concrete has been freshly extracted from the air or comes from rocks,” said Maruyama. “So we developed a method to verify this, which could be used to determine whether the concrete produced can be certified as offsetting CO2 emissions.”

Researchers carried out the study by making hydrated cement paste samples as a concrete replica. After getting sufficiently hydrated, they ground the paste sample into powder, keeping the nonexposed powder contained and leaving the exposed powder open to the air. After seven and 28 days, they dissolved the powder in acid to collect the gas and using a technique called accelerator mass spectrometry analyzed the ratio of several carbon isotopes (atoms with the same chemical properties but different physical properties), namely carbon-12, carbon-13 and carbon-14. This enabled the team to evaluate where the carbon came from, and whether it was already present in the raw materials, as the carbon ratios reflected the known proportion of carbon isotopes in the air at the time the gas was sealed.

Next the researchers want to apply this lab-based method to real-world locations and test how the varied quantities of raw materials used in local concrete production may affect results. “Fixing carbon dioxide from the air is certified as an act of offsetting CO2 emissions, so it is economically valuable in terms of emissions trading. Digging up calcium carbonate for use in concrete is not, so the distinction is very important and this research can help to support a healthy market,” said Maruyama. “We believe that the carbon neutrality and a circular economy in the construction industry are essential to our future, particularly in Japan where this industry has a role in supporting business continuity and recovery from natural disasters.”

Paper Title:

Zhenzhen Wang, Abudushalamu Aili, Masayo Minami and Ippei Maruyama. Verification method of Direct Air Capture by Cementitious Material Using Carbon Isotopes. Journal of Advanced Concrete Technology Vol. 21, 934-941 Nov 2023. doi: 10.3151/jact.21.934

Funding:

This article is based on results from a project, JPNP21023, by the New Energy and Industrial Technology Development Organization (NEDO).

Useful Links
Graduate School of Engineering: https://www.t.u-tokyo.ac.jp/en/soe

Building Material Engineering Lab: https://bme.t.u-tokyo.ac.jp/eng/

Journal paper: https://www.jstage.jst.go.jp/article/jact/21/11/21_934/_article/-char/en

Research Contact:
Professor Ippei Maruyama
Graduate School Engineering, The University of Tokyo
Hongo 7-3-1, Bunkyo-ku, Tokyo 113-8654
Email: i.maruyama@bme.arch.t.u-tokyo.ac.jp
Tel.: +81-30-5841-6196

Press contact:
Mrs. Nicola Burghall
Public Relations Group, The University of Tokyo,
7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8654, Japan
press-releases.adm@gs.mail.u-tokyo.ac.jp

About the University of Tokyo
The University of Tokyo is Japan’s leading university and one of the world’s top research universities. The vast research output of some 6,000 researchers is published in the world’s top journals across the arts and sciences. Our vibrant student body of around 15,000 undergraduate and 15,000 graduate students includes over 4,000 international students. Find out more at www.u-tokyo.ac.jp/en/ or follow us on Twitter at @UTokyo_News_en.

Journal: Journal of Advanced Concrete Technology
DOI: 10.3151/jact.21.934
Method of Research: Experimental study
Subject of Research: Not applicable
Article Title: Verification method of Direct Air Capture by Cementitious Material Using Carbon Isotopes.
Article Publication Date: 22-Nov-2023

Media Contact

Joseph Krisher
University of Tokyo
press-releases.adm@gs.mail.u-tokyo.ac.jp

Expert Contact

Professor Ippei Maruyama
University of Tokyo
i.maruyama@bme.arch.t.u-tokyo.ac.jp

Media Contact

Joseph Krisher
University of Tokyo

All latest news from the category: Ecology, The Environment and Conservation

This complex theme deals primarily with interactions between organisms and the environmental factors that impact them, but to a greater extent between individual inanimate environmental factors.

innovations-report offers informative reports and articles on topics such as climate protection, landscape conservation, ecological systems, wildlife and nature parks and ecosystem efficiency and balance.

Back to home

Comments (0)

Write a comment

Newest articles

New technique can quickly detect fentanyl and other opioids

Testing method can analyze blood samples twice as quickly as other techniques. University of Waterloo researchers have developed a new blood testing method that can detect potent opioids much faster…

Photon upconversion: Steering light with supercritical coupling

Researchers from the National University of Singapore (NUS) have unveiled a novel concept termed “supercritical coupling” that enables several folds increase in photon upconversion efficiency. This discovery not only challenges…

Researchers harness 2D magnetic materials for energy-efficient computing

An MIT team precisely controlled an ultrathin magnet at room temperature, which could enable faster, more efficient processors and computer memories. Experimental computer memories and processors built from magnetic materials…

Partners & Sponsors