The nanoparticles in question are spheres of magnetite so tiny that a few thousand of them lined up would stretch a hair's width, and they have potential uses both as the basis of better data storage systems and in biological applications such as hyperthermia treatment for cancer. A key to all these applications is a full understanding of how large numbers of the particles interact magnetically with one another across relatively large distances so that scientists can manipulate them with magnetism.
"It's been known for a long time that a big chunk of magnetite has greater magnetic 'moment'—think of it as magnetic strength—than an equivalent mass of nanoparticles," says Kathryn Krycka, a researcher at the NIST Center for Neutron Research. "No one really knows why, though. We decided to probe the particles with beams of low-energy neutrons, which can tell you a great deal about a material's internal structure."
The team applied a magnetic field to nanocrystals composed of 9 nm-wide particles, made by collaborators at Carnegie Mellon University. The field caused the particles to line up like iron filings on a piece of paper held above a bar magnet. But when the team looked closer using the neutron beam, what they saw revealed a level of complexity never seen before.
"When the field is applied, the inner 7 nm-wide 'core' orients itself along the field's north and south poles, just like large iron filings would," Krycka says. "But the outer 1 nm 'shell' of each nanoparticle behaves differently. It also develops a moment, but pointed at right angles to that of the core."
In a word, bizarre. But potentially useful.
The shells are not physically different than the interiors; without the magnetic field, the distinction vanishes. But once formed, the shells of nearby particles seem to heed one another: A local group of them will have their shells' moments all lined up one way, but then another group's shells will point elsewhere. This finding leads Krycka and her team to believe that there is more to be learned about the role that particle interaction has on determining internal, magnetic nanoparticle structure—perhaps something nanotechnologists can harness.
The research team, which also included scientists from Oberlin College and Los Alamos National Laboratory, used neutron instrumentation supported in part by the National Science Foundation (NSF). Research at Carnegie Mellon and Oberlin also received support from NSF.
* K.L. Krycka, R.A. Booth, C. Hogg, Y. Ijiri, J.A. Borchers, W.C. Chen, S.M. Watson, M. Laver, T.R. Gentile, L.R. Dedon, S. Harris, J.J. Rhyne and S.A. Majetich. Core-shell magnetic morphology of structurally uniform magnetite nanoparticles. Physical Review Letters, 104, 207203 (2010), DOI 10.1103/PhysRevLett.104.207203
Chad Boutin | EurekAlert!
Meteoritic stardust unlocks timing of supernova dust formation
19.01.2018 | Carnegie Institution for Science
Artificial agent designs quantum experiments
19.01.2018 | Universität Innsbruck
On the way to an intelligent laboratory, physicists from Innsbruck and Vienna present an artificial agent that autonomously designs quantum experiments. In initial experiments, the system has independently (re)discovered experimental techniques that are nowadays standard in modern quantum optical laboratories. This shows how machines could play a more creative role in research in the future.
We carry smartphones in our pockets, the streets are dotted with semi-autonomous cars, but in the research laboratory experiments are still being designed by...
What enables electrons to be transferred swiftly, for example during photosynthesis? An interdisciplinary team of researchers has worked out the details of how...
For the first time, scientists have precisely measured the effective electrical charge of a single molecule in solution. This fundamental insight of an SNSF Professor could also pave the way for future medical diagnostics.
Electrical charge is one of the key properties that allows molecules to interact. Life itself depends on this phenomenon: many biological processes involve...
At the JEC World Composite Show in Paris in March 2018, the Fraunhofer Institute for Laser Technology ILT will be focusing on the latest trends and innovations in laser machining of composites. Among other things, researchers at the booth shared with the Aachen Center for Integrative Lightweight Production (AZL) will demonstrate how lasers can be used for joining, structuring, cutting and drilling composite materials.
No other industry has attracted as much public attention to composite materials as the automotive industry, which along with the aerospace industry is a driver...
Scientists at Tokyo Institute of Technology (Tokyo Tech) and Tohoku University have developed high-quality GFO epitaxial films and systematically investigated their ferroelectric and ferromagnetic properties. They also demonstrated the room-temperature magnetocapacitance effects of these GFO thin films.
Multiferroic materials show magnetically driven ferroelectricity. They are attracting increasing attention because of their fascinating properties such as...
08.01.2018 | Event News
11.12.2017 | Event News
08.12.2017 | Event News
19.01.2018 | Materials Sciences
19.01.2018 | Health and Medicine
19.01.2018 | Physics and Astronomy