Taking a page from Jonathan Swift's "Gulliver's Travels", a team of scientists has created malleable and microscopic self-assembling particles that can serve as the next generation of building blocks in the creation of synthetic materials.
"Our work turns the tiniest of particles from inflexible, Lego-like pieces into ones that can transform themselves into a range of shapes," explains Stefano Sacanna, an assistant professor in NYU's Department of Chemistry and the senior author of the paper, which appears in the journal Nature Communications. "With the ability to change their contours, these particles mimic alterations that occur in nature."
A team of NYU chemists has created malleable and microscopic self-assembling particles that can serve as the next generation of building blocks in the creation of synthetic materials. The research focused on engineering particles a micrometer in width -- about 1/200th the width of a strand of human hair (on which the particles [pink and blue] are placed in the above image).
Image courtesy of the Sacanna lab.
The research focused on engineering particles a micrometer in width--about 1/200th the width of a strand of human hair.
Specifically, it aimed to enhance the adaptability of colloids--small particles suspended within a fluid medium. Such everyday items such as paint, milk, gelatin, glass, and porcelain are composed of colloidal dispersions, but it's their potential to control the flow of light that has scientists focused on creating exotic colloidal geometries.
By triggering specific morphological changes in the singular colloidal unit, the Sacanna group hopes to advance colloidal crystal engineering.
The scientists discovered that, much like Gulliver tied down by Lilliputians, metallic particles encased in oil droplets were tethered by many chemical bonds. Breaking those tethers via a photocatalytic reaction--in which the absorption of light spurs a chemical response--caused the metallic particle to free itself, producing an overall shape change. In other words, shining a light on a simple crystal allowed the scientists to create a material that transforms its microstructure.
The study's other authors were: Mena Youssef and Theodore Hueckel, both NYU doctoral students, and Gi-Ra Yi, a professor at South Korea's Sungkyunkwan University.
This work was supported by the MRSEC Program of the National Science Foundation (DMR-1420073).
James Devitt | EurekAlert!
Rainbow colors reveal cell history: Uncovering β-cell heterogeneity
22.09.2017 | DFG-Forschungszentrum für Regenerative Therapien TU Dresden
The pyrenoid is a carbon-fixing liquid droplet
22.09.2017 | Max-Planck-Institut für Biochemie
Plants and algae use the enzyme Rubisco to fix carbon dioxide, removing it from the atmosphere and converting it into biomass. Algae have figured out a way to increase the efficiency of carbon fixation. They gather most of their Rubisco into a ball-shaped microcompartment called the pyrenoid, which they flood with a high local concentration of carbon dioxide. A team of scientists at Princeton University, the Carnegie Institution for Science, Stanford University and the Max Plank Institute of Biochemistry have unravelled the mysteries of how the pyrenoid is assembled. These insights can help to engineer crops that remove more carbon dioxide from the atmosphere while producing more food.
A warming planet
Our brains house extremely complex neuronal circuits, whose detailed structures are still largely unknown. This is especially true for the so-called cerebral cortex of mammals, where among other things vision, thoughts or spatial orientation are being computed. Here the rules by which nerve cells are connected to each other are only partly understood. A team of scientists around Moritz Helmstaedter at the Frankfiurt Max Planck Institute for Brain Research and Helene Schmidt (Humboldt University in Berlin) have now discovered a surprisingly precise nerve cell connectivity pattern in the part of the cerebral cortex that is responsible for orienting the individual animal or human in space.
The researchers report online in Nature (Schmidt et al., 2017. Axonal synapse sorting in medial entorhinal cortex, DOI: 10.1038/nature24005) that synapses in...
Whispering gallery mode (WGM) resonators are used to make tiny micro-lasers, sensors, switches, routers and other devices. These tiny structures rely on a...
Using ultrafast flashes of laser and x-ray radiation, scientists at the Max Planck Institute of Quantum Optics (Garching, Germany) took snapshots of the briefest electron motion inside a solid material to date. The electron motion lasted only 750 billionths of the billionth of a second before it fainted, setting a new record of human capability to capture ultrafast processes inside solids!
When x-rays shine onto solid materials or large molecules, an electron is pushed away from its original place near the nucleus of the atom, leaving a hole...
For the first time, physicists have successfully imaged spiral magnetic ordering in a multiferroic material. These materials are considered highly promising candidates for future data storage media. The researchers were able to prove their findings using unique quantum sensors that were developed at Basel University and that can analyze electromagnetic fields on the nanometer scale. The results – obtained by scientists from the University of Basel’s Department of Physics, the Swiss Nanoscience Institute, the University of Montpellier and several laboratories from University Paris-Saclay – were recently published in the journal Nature.
Multiferroics are materials that simultaneously react to electric and magnetic fields. These two properties are rarely found together, and their combined...
19.09.2017 | Event News
12.09.2017 | Event News
06.09.2017 | Event News
22.09.2017 | Life Sciences
22.09.2017 | Medical Engineering
22.09.2017 | Physics and Astronomy