Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Vise Squad: Putting the Squeeze on a Crystal Leads to Novel Electronics

11.05.2009
A clever materials science technique that uses a silicon crystal as a sort of nanoscale vise to squeeze another crystal into a more useful shape may launch a new class of electronic devices that remember their last state even after power is turned off.

Computers that could switch on instantly without the time-consuming process of “booting” an operating system is just one of the possibilities, according to a new paper by a team of researchers spanning four universities, two federal laboratories and three corporate labs.*

Almost exactly two years ago, a team led by Joseph Woicik of NIST and several other federal, academic and industrial laboratories combined precision X-ray spectroscopy data from the NIST beamlines at the National Synchrotron Light Source with theoretical calculations to demonstrate that by carefully layering a thin film of strontium titanate onto a pure silicon crystal, they could distort the titanium compound into something it normally wasn’t—a so-called “ferroelectric” compound that might serve as a fast, efficient medium for data storage.** The new paper adds a key experimental and technological demonstration—the ability to write, read, store and erase patterned bits of data in the strontium titanate film.

In contrast to a traditional data storage material, which records data as a pattern of magnetic regions pointing in different directions, a ferroelectric can do the same with tiny regions of polarized electric charges. Ferroelectric memories are used, for example, in “smart cards” for subway systems. Ferroelectric structures that could be built directly onto silicon crystals, the most common materials base for consumer electronics, have been sought for years for a variety of applications, including nonvolatile memory (data that is not lost when power is turned off) and temperature or pressure sensors integrated into silicon-based microelectronics. One of the potentially biggest prizes would be ferroelectric transistors that could retain their logic state (“on” or “off”) without power, which could enable computers that switch on instantly without needing a boot stage.

The breakthrough originated with researcher Hao Li of Motorola, Inc., who succeeded in depositing the metal oxide directly onto silicon with no intervening layer of silicon oxide producing “coherency” between the two crystal structures—the unique matching up perfectly of one atom to the next across the metal-oxide/Si interface. This is a difficult trick both because silicon is highly reactive to oxidation and because the crystal spacing of the two materials does not normally match. Guided by precision X-ray diffraction data from NIST, Li developed a finely controlled method of depositing the strontium titanate in stages, gradually building up layers that were only a few molecules thick. The result, X-ray data showed, was that the silicon atoms literally squeezed the cubic strontium-titanate crystal to make it fit, distorting it into an oblong shape. That distortion creates a structural instability in the film that makes the compound a ferroelectric.

While theoretical calculations and spectroscopic data demonstrated that the distorted crystal behaved like a ferroelectric, proof of the ferroelectric functionality waited on the new work led by Cornell University professor Darrell Schlom, whose team used a technique called piezoresponse force microscopy to write, read and erase polarized domains in the strontium titanate film.

Researchers from Cornell, the University of Pittsburgh, NIST, Pennsylvania State University, Northwestern University, Motorola, the Energy Department’s Ames Laboratory, Intel Corporation, and Tricorn Tech contributed to the latest paper. X-ray diffraction data were taken at the Advanced Photon Source, Argonne National Laboratory. The research was funded in part by the Office of Naval Research and the National Science Foundation.

* M.P. Warusawithana, C. Cen, C.R. Sleasman, J.C. Woicik, Y. Li, L.F. Kourkoutis, J.A. Klug, H. Li, P. Ryan, L.-P. Wang, M. Bedzyk, D.A. Muller, L.-Q. Chen, J. Levy and D.G. Schlom. A ferroelectric oxide made directly on silicon. Science V 324 17 April 17, 2009. DOI: 10.1126/science.1169678.

** J.C. Woicik, E.L. Shirley, C.S. Hellberg, K.E. Andersen, S. Sambasivan, D.A. Fischer, B.D. Chapman, E.A. Stern, P. Ryan, D.L. Ederer and H. Li. Ferroelectric distortion in SrTiO3 thin films on Si (001) by x-ray absorption fine structure spectroscopy: Experiment and first-principles calculations. Physical Review B 75, Rapid Communications, 140103 April 24, 2007. DOI: 10.1103/PhysRevB.75.140103.

Michael Baum | Newswise Science News
Further information:
http://www.nist.gov

More articles from Materials Sciences:

nachricht Cementless fly ash binder makes concrete 'green'
19.06.2018 | Rice University

nachricht Ground-breaking discoveries could create superior alloys with many applications
19.06.2018 | Chalmers University of Technology

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Overdosing on Calcium

Nano crystals impact stem cell fate during bone formation

Scientists from the University of Freiburg and the University of Basel identified a master regulator for bone regeneration. Prasad Shastri, Professor of...

Im Focus: AchemAsia 2019 will take place in Shanghai

Moving into its fourth decade, AchemAsia is setting out for new horizons: The International Expo and Innovation Forum for Sustainable Chemical Production will take place from 21-23 May 2019 in Shanghai, China. With an updated event profile, the eleventh edition focusses on topics that are especially relevant for the Chinese process industry, putting a strong emphasis on sustainability and innovation.

Founded in 1989 as a spin-off of ACHEMA to cater to the needs of China’s then developing industry, AchemAsia has since grown into a platform where the latest...

Im Focus: First real-time test of Li-Fi utilization for the industrial Internet of Things

The BMBF-funded OWICELLS project was successfully completed with a final presentation at the BMW plant in Munich. The presentation demonstrated a Li-Fi communication with a mobile robot, while the robot carried out usual production processes (welding, moving and testing parts) in a 5x5m² production cell. The robust, optical wireless transmission is based on spatial diversity; in other words, data is sent and received simultaneously by several LEDs and several photodiodes. The system can transmit data at more than 100 Mbit/s and five milliseconds latency.

Modern production technologies in the automobile industry must become more flexible in order to fulfil individual customer requirements.

Im Focus: Sharp images with flexible fibers

An international team of scientists has discovered a new way to transfer image information through multimodal fibers with almost no distortion - even if the fiber is bent. The results of the study, to which scientist from the Leibniz-Institute of Photonic Technology Jena (Leibniz IPHT) contributed, were published on 6thJune in the highly-cited journal Physical Review Letters.

Endoscopes allow doctors to see into a patient’s body like through a keyhole. Typically, the images are transmitted via a bundle of several hundreds of optical...

Im Focus: Photoexcited graphene puzzle solved

A boost for graphene-based light detectors

Light detection and control lies at the heart of many modern device applications, such as smartphone cameras. Using graphene as a light-sensitive material for...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

VideoLinks
Industry & Economy
Event News

Munich conference on asteroid detection, tracking and defense

13.06.2018 | Event News

2nd International Baltic Earth Conference in Denmark: “The Baltic Sea region in Transition”

08.06.2018 | Event News

ISEKI_Food 2018: Conference with Holistic View of Food Production

05.06.2018 | Event News

 
Latest News

Carbon nanotube optics provide optical-based quantum cryptography and quantum computing

19.06.2018 | Physics and Astronomy

How to track and trace a protein: Nanosensors monitor intracellular deliveries

19.06.2018 | Life Sciences

New material for splitting water

19.06.2018 | Physics and Astronomy

VideoLinks
Science & Research
Overview of more VideoLinks >>>