The same material that formed the first primitive transistors more than 60 years ago can be modified in a new way to advance future electronics, according to a new study.
Chemists at The Ohio State University have developed the technology for making a one-atom-thick sheet of germanium, and found that it conducts electrons more than ten times faster than silicon and five times faster than conventional germanium.
The material’s structure is closely related to that of graphene—a much-touted two-dimensional material comprised of single layers of carbon atoms. As such, graphene shows unique properties compared to its more common multilayered counterpart, graphite. Graphene has yet to be used commercially, but experts have suggested that it could one day form faster computer chips, and maybe even function as a superconductor, so many labs are working to develop it.
Joshua Goldberger, assistant professor of chemistry at Ohio State, decided to take a different direction and focus on more traditional materials.
“Most people think of graphene as the electronic material of the future,” Goldberger said. “But silicon and germanium are still the materials of the present. Sixty years’ worth of brainpower has gone into developing techniques to make chips out of them. So we’ve been searching for unique forms of silicon and germanium with advantageous properties, to get the benefits of a new material but with less cost and using existing technology.”
In a paper published online in the journal ACS Nano, he and his colleagues describe how they were able to create a stable, single layer of germanium atoms. In this form, the crystalline material is called germanane.
Researchers have tried to create germanane before. This is the first time anyone has succeeded at growing sufficient quantities of it to measure the material’s properties in detail, and demonstrate that it is stable when exposed to air and water.
In nature, germanium tends to form multilayered crystals in which each atomic layer is bonded together; the single-atom layer is normally unstable. To get around this problem, Goldberger’s team created multi-layered germanium crystals with calcium atoms wedged between the layers. Then they dissolved away the calcium with water, and plugged the empty chemical bonds that were left behind with hydrogen. The result: they were able to peel off individual layers of germanane.
Studded with hydrogen atoms, germanane is even more chemically stable than traditional silicon. It won’t oxidize in air and water, as silicon does. That makes germanane easy to work with using conventional chip manufacturing techniques.
The primary thing that makes germanane desirable for optoelectronics is that it has what scientists call a “direct band gap,” meaning that light is easily absorbed or emitted. Materials such as conventional silicon and germanium have indirect band gaps, meaning that it is much more difficult for the material to absorb or emit light.
“When you try to use a material with an indirect band gap on a solar cell, you have to make it pretty thick if you want enough energy to pass through it to be useful. A material with a direct band gap can do the same job with a piece of material 100 times thinner,” Goldberger said.
The first-ever transistors were crafted from germanium in the late 1940s, and they were about the size of a thumbnail. Though transistors have grown microscopic since then—with millions of them packed into every computer chip—germanium still holds potential to advance electronics, the study showed.
According to the researchers’ calculations, electrons can move through germanane ten times faster through silicon, and five times faster than through conventional germanium. The speed measurement is called electron mobility.
With its high mobility, germanane could thus carry the increased load in future high-powered computer chips.
“Mobility is important, because faster computer chips can only be made with faster mobility materials,” Golberger said. “When you shrink transistors down to small scales, you need to use higher mobility materials or the transistors will just not work,” Goldberger explained.
Next, the team is going to explore how to tune the properties of germanane by changing the configuration of the atoms in the single layer.
Lead author of the paper was Ohio State undergraduate chemistry student Elizabeth Bianco, who recently won the first place award for this research at the nationwide nanotechnology competition NDConnect, hosted by the University of Notre Dame. Other co-authors included Sheneve Butler and Shishi Jiang of the Department of Chemistry and Biochemistry, and Oscar Restrepo and Wolfgang Windl of the Department of Materials Science and Engineering.
The research was supported in part by an allocation of computing time from the Ohio Supercomputing Center, with instrumentation provided by the Analytical Surface Facility in the Department of Chemistry and Biochemistry and the Ohio State University Undergraduate Instrumental Analysis Program. Funding was provided by the National Science Foundation, the Army Research Office, the Center for Emergent Materials at Ohio State, and the university’s Materials Research Seed Grant Program.Contact: Joshua Goldberger, (614) 247-7438; Goldberger@chemistry.ohio-state.edu
Pam Frost Gorder | Newswise
New material could lead to erasable and rewriteable optical chips
07.12.2016 | University of Texas at Austin
Porous crystalline materials: TU Graz researcher shows method for controlled growth
07.12.2016 | Technische Universität Graz
In recent years, lasers with ultrashort pulses (USP) down to the femtosecond range have become established on an industrial scale. They could advance some applications with the much-lauded “cold ablation” – if that meant they would then achieve more throughput. A new generation of process engineering that will address this issue in particular will be discussed at the “4th UKP Workshop – Ultrafast Laser Technology” in April 2017.
Even back in the 1990s, scientists were comparing materials processing with nanosecond, picosecond and femtosesecond pulses. The result was surprising:...
Have you ever wondered how you see the world? Vision is about photons of light, which are packets of energy, interacting with the atoms or molecules in what...
A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.
Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...
In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.
“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...
The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.
The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...
16.11.2016 | Event News
01.11.2016 | Event News
14.10.2016 | Event News
07.12.2016 | Health and Medicine
07.12.2016 | Life Sciences
07.12.2016 | Health and Medicine