Graphene, a material that consists of a lattice of carbon atoms, one atom thick, is widely touted as being the most electrically conductive material ever studied. However, not all graphene is the same. With so few atoms comprising the entirety of the material, the arrangement of each one has an impact on its overall function.
Now, for the first time, researchers from the University of Pennsylvania have used a cutting-edge microscope to study the relationship between the atomic geometry of a ribbon of graphene and its electrical properties.
A deeper understanding of this relationship will be necessary for the design of graphene-based integrated circuits, computer chips and other electronic devices.
The study was led by professors A.T. Charlie Johnson and Marija Drndić, both of the Department of Physics and Astronomy in Penn’s School of Arts & Sciences, along with Zhengqing John Qi, a member of Johnson’s lab, and Julio Rodríguez-Manzo from Drndic’s lab. Sung Ju Hong, then a member of Johnson’s lab, also contributed to the study.
Their study was published in the journal Nano Letters.
The team’s experiments were enabled by Brookhaven’s aberration-corrected transmission electron microscope, or AC-TEM. By focusing the microscope’s electron beam, the researchers were able to controllably cut sheets of graphene into ribbons with widths as small as 10 nanometers, while keeping them connected to an electricity source outside the microscope. They then could use the AC-TEM’s nanoscopic resolution to distinguish between individual carbon atoms within those ribbons. This level of precision was necessary to determine how the carbon atoms on the edges of the nanoribbons were oriented.
“We’re relating the structure of the graphene — its atomic arrangement — to its electrical transport properties,” said Drndić. “In particular, we were looking at the edges, which we were able to identify the geometry of.”
“Graphene looks like chicken wire, and you can cut up this hexagonal lattice of carbon atoms in different ways, producing different shapes on the edge,” she said. “But if you cut it one way, it might behave more like a metal, and, if you cut it another way, it could be more like a semiconductor.”
For any piece of graphene, either the pointy or flat sides of its carbon hexagons might be at the piece’s edge. Where the pointy sides face outward, the edge has a “zig-zag” pattern. Flat sides produce “armchair” pattern when they are on an edge. Any given edge might also display a mix of the two, depending on how the piece of graphene was initially cut and how that edge degrades under stress.
Because the graphene nanoribbons were connected to an electricity source while they were inside the AC-TEM, the researchers were able to simultaneously trace the outline of the ribbons and measure their conductivity. This allowed the two figures to be correlated.
“If you want to use graphene nanoribbons in computer chips, for example, you absolutely need to have this information,” Johnson said. “People have looked at these ribbons under the microscope, and people have measured their electrical properties without looking at them but never both at the same time.”
After studying the nanoribbons with relatively low levels of electron flow, the researchers turned up the intensity, much like turning up a light bulb using a dimmer switch The combination of the electron bombardment from the microscope and the large amount of electrons flowing through the nanoribbons caused their structures to gradually degrade. As carbon bonds within the nanoribbons broke, they became thinner and the shape of their edges changed, providing additional data points.
“By doing everything within the microscope,” Rodríguez-Manzo said, “we can just follow this transformation to the end, measuring currents for the nanoribbons even when the get smaller than 1 nanometer across. That’s five atoms wide.”
This kind of stress testing is critical to the future design of graphene electronics.
“We have to see how much current we can transport before these nanoribbons fall apart. Our data shows that this figure is high compared to copper,” Rodríguez-Manzo said.
The harsh conditions also caused some of the ribbons to fold up on themselves, producing nanoscopic graphene loops. Serendipitously, the team found that these loops had desirable properties.
“When the edges wrap around and form the loops we see,” Johnson said, “it helps hold the structure together, and it makes the current density a thousand higher than what is currently state of the art. That structure would be useful in making interconnects [which are the conducting paths that connect transistors together in integrated circuits].”
Future research in this field will involve directly comparing the electrical properties of graphene nanoribbons with different widths and edge shapes.
“Once we can cut these nanoribbons atom by atom,” Drndić said, “there will be a lot more we can achieve.”
The research was supported by the National Science Foundation, the National Institutes of Health, the U.S. Department of Energy, Belgium’s Fonds de la Recherche Scientifique, South Korea’s Ministry of Education, Science and Technology and National Research Foundation and the European Union’s Graphene Flagship Consortium.
Andrés R. Botello-Méndez and Jean-Christophe Charlierof the Université Catholique de Louvain in Belgium, Eric Stach of Brookhaven National Laboratory and Yung Woo Park of Seoul National University also contributed to the study.
Evan Lerner | Eurek Alert!
OSU researchers prove magnetism can control heat, sound
29.05.2015 | Ohio Supercomputer Center
Engineering phase changes in nanoparticle arrays
26.05.2015 | DOE/Brookhaven National Laboratory
Many joining and cutting processes are possible only with lasers. New technologies make it possible to manufacture metal components with hollow structures that are significantly lighter and yet just as stable as solid components. In addition, lasers can be used to combine various lightweight construction materials and steels with each other. The Fraunhofer Institute for Laser Technology ILT in Aachen is presenting a range of such solutions at the LASER World of Photonics trade fair from June 22 to 25, 2015 in Munich, Germany, (Hall A3, Stand 121).
Lightweight construction materials are popular: aluminum is used in the bodywork of cars, for example, and aircraft fuselages already consist in large part of...
Using ultrashort laser pulses, scientists in Max Planck Institute of Quantum Optics have demonstrated the emission of extreme ultraviolet radiation from thin dielectric films and have investigated the underlying mechanisms.
In 1961, only shortly after the invention of the first laser, scientists exposed silicon dioxide crystals (also known as quartz) to an intense ruby laser to...
The only professorship in Germany to date, one master's programme, one laboratory with worldwide unique equipment and the corresponding research results: The University of Würzburg is leading in the field of biofabrication.
Paul Dalton is presently the only professor of biofabrication in Germany. About a year ago, the Australian researcher relocated to the Würzburg department for...
Physicists have developed an innovative method that could enable the efficient use of nanocomponents in electronic circuits. To achieve this, they have developed a layout in which a nanocomponent is connected to two electrical conductors, which uncouple the electrical signal in a highly efficient manner. The scientists at the Department of Physics and the Swiss Nanoscience Institute at the University of Basel have published their results in the scientific journal “Nature Communications” together with their colleagues from ETH Zurich.
Electronic components are becoming smaller and smaller. Components measuring just a few nanometers – the size of around ten atoms – are already being produced...
Development and implementation of an advanced automobile parking navigation platform for parking services
To fulfill the requirements of the industry, PolyU researchers developed the Advanced Automobile Parking Navigation Platform, which includes smart devices,...
20.05.2015 | Event News
18.05.2015 | Event News
12.05.2015 | Event News
29.05.2015 | Life Sciences
29.05.2015 | Earth Sciences
29.05.2015 | Physics and Astronomy