This method, which utilizes ionic liquids to separate the heavy viscous oil from sand, is also capable of cleaning oil spills from beaches and separating oil from drill cuttings, the solid particles that must be removed from drilling fluids in oil and gas wells.
Tar sands, also known as bituminous sands or oil sands, represent approximately two-thirds of the world’s estimated oil reserves. Canada is the world’s major producer of unconventional petroleum from sands, and the U.S. imports more than one million barrels of oil per day from Canada, about twice as much as from Saudi Arabia. Much of this oil is produced from the Alberta tar sands.
However, the production of petroleum from tar sands causes environmental damage. Part of the damage comes from the storage of contaminated wastewater from the separation process in large open air ponds. Wastewater from the ponds can seep into groundwater and pollute lakes and rivers. In addition, the requirement for large amounts of water can deplete the supply of local fresh water resources. The Penn State separation method uses very little energy and water, and all solvents are recycled and reused.
Paul Painter, professor of polymer science in the Department of Materials Science and Engineering at Penn State, and his group have spent the past 18 months developing a technique that uses ionic liquids (salt in a liquid state) to facilitate separation. The separation takes place at room temperature without the generation of waste process water. “Essentially, all of the bitumen is recovered in a very clean form, without any contamination from the ionic liquids,” Painter explained. Because the bitumen, solvents and sand/clay mixture separate into three distinct phases, each can be removed separately and the solvent can be reused.
The process can also be used to extract oil and tar from beach sand after oil spills, such as the Exxon Valdez and Deepwater Horizon incidents. Unlike other methods of cleanup, the Penn State process completely removes the hydrocarbons, and the cleaned sand can be returned to the beach instead of being sent to landfills. In an experiment using sand polluted by the BP oil spill, the team was able to separate hydrocarbons from the sand within seconds. A small amount of water was used to clean the remaining ionic liquids from the sand, but that water was also recoverable. “It was so clean you could toss it back on the beach. Plus, the only extra energy you need is enough to stir the mixture,” said Aron Lupinsky, a researcher in Painter’s group.
The researchers work with a group of ionic liquids based on 1-alkyl-3-methylimidazolium cations, a positively charged material with high chemical and thermal stability, a low degree of flammability, and almost negligible vapor pressure, which makes recovering the ionic liquid relatively simple. The team has built a functioning bench top model system and is in the process of reducing their discovery to practice for patenting.
In addition to Painter, team members include Bruce Miller, senior research associate in the EMS Energy Institute, and former students Aron Lupinsky and Phil Williams. A more detailed explanation of the research, along with photos and video, is posted on the departmental website: http://www.matse.psu.edu/news/ionicliquids. Prof. Painter can be contacted at email@example.com.
The Materials Research Institute coordinates Penn State’s more than 200 materials-related faculty in interdisciplinary research activities. MRI’s new home for 21st century science, the Millennium Science Complex, will open in the summer of 2011. Learn more about the Millennium Science Complex and materials research at Penn State at http://www.mri.psu.edu/.
Nanomaterial makes laser light more applicable
28.03.2017 | Christian-Albrechts-Universität zu Kiel
New value added to the ICSD (Inorganic Crystal Structure Database)
27.03.2017 | FIZ Karlsruhe – Leibniz-Institut für Informationsinfrastruktur GmbH
The Institute of Semiconductor Technology and the Institute of Physical and Theoretical Chemistry, both members of the Laboratory for Emerging Nanometrology (LENA), at Technische Universität Braunschweig are partners in a new European research project entitled ChipScope, which aims to develop a completely new and extremely small optical microscope capable of observing the interior of living cells in real time. A consortium of 7 partners from 5 countries will tackle this issue with very ambitious objectives during a four-year research program.
To demonstrate the usefulness of this new scientific tool, at the end of the project the developed chip-sized microscope will be used to observe in real-time...
Astronomers from Bonn and Tautenburg in Thuringia (Germany) used the 100-m radio telescope at Effelsberg to observe several galaxy clusters. At the edges of these large accumulations of dark matter, stellar systems (galaxies), hot gas, and charged particles, they found magnetic fields that are exceptionally ordered over distances of many million light years. This makes them the most extended magnetic fields in the universe known so far.
The results will be published on March 22 in the journal „Astronomy & Astrophysics“.
Galaxy clusters are the largest gravitationally bound structures in the universe. With a typical extent of about 10 million light years, i.e. 100 times the...
Researchers at the Goethe University Frankfurt, together with partners from the University of Tübingen in Germany and Queen Mary University as well as Francis Crick Institute from London (UK) have developed a novel technology to decipher the secret ubiquitin code.
Ubiquitin is a small protein that can be linked to other cellular proteins, thereby controlling and modulating their functions. The attachment occurs in many...
In the eternal search for next generation high-efficiency solar cells and LEDs, scientists at Los Alamos National Laboratory and their partners are creating...
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are less stable. Now researchers at the Technical University of Munich (TUM) have, for the first time ever, produced a composite material combining silicon nanosheets and a polymer that is both UV-resistant and easy to process. This brings the scientists a significant step closer to industrial applications like flexible displays and photosensors.
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are...
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