Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Crystals on a ball

14.03.2003


Researchers attack 100-year-old puzzle, learn how a single layer of particles can pack on the surface of a sphere

ARLINGTON, Va. - In a discovery that is likely to impact fields as diverse as medicine and nanomanufacture, researchers have determined how nature arranges charged particles in a thin layer around a sphere. The leap forward in understanding this theoretical problem may help reveal structural chinks in the outer armor of viruses and bacteria (revealing potential drug targets) and guide engineers designing new molecules.

On a flat surface, particles that repel each other will arrange themselves to create a stable energy state, eventually settling at vertices within a lattice of identical triangles much like billiard balls at the start of a game.

Yet, for nearly a century, researchers studying spherical structures have known that a flat lattice cannot be simply wrapped around a sphere because the lattice of perfect triangles breaks down. Since as early as 1904, when Nobel prize-winning physicist J.J. Thomson theorized about electron shells in atoms, researchers have wondered what structure the thin web of particles would choose, from among myriad possibilities, if wrapped around a sphere.

In the March 14 issue of the journal Science, researchers describe a major breakthrough in the puzzle, supported by experiments with water droplets and tiny, self-assembling beads. The researchers demonstrate how spherical crystals compensate for the curved surface on which they exist by developing "scars," defects that allow the beads to pack into place.

NSF-supported scientists Mark Bowick of Syracuse University, David Nelson of Harvard University, and Alex Travesset of Iowa State University and Ames National Laboratory designed the study with concepts they had developed earlier.

"The theoretical work from our laboratories, and others, suggested that crystals on a curved surface would pack unusually, in a way not found in flat crystals," said Bowick, although the packing depends upon the size of the crystal relative to the surface particles.

The researchers were joined by experimentalists Andreas Bausch and Michael Nikolaides of Technische Universität München in Germany and Angelo Cacciuto of the FOM Institute for Atomic and Molecular Physics in the Netherlands, along with NSF-supported researcher David Weitz and his research team at Harvard University. With experimentation, the team was able to test, and ultimately support, their models of how spherical crystals form in various natural settings.

"This study’s interplay between theory and experiment reveals fascinating insights," said Daryl Hess, the NSF program officer who oversees support for the project. "This is curiosity driven research - from the structure of biological systems to the venerable old problem framed before quantum mechanics - these findings will likely have impact across many fields of science."

Unlike previous approaches using computer models to determine how the charged particles arrange themselves, the new research involves experimentation, instead targeting the simple defects in the crystal structure and determining how the particles and defects find their most stable arrangement.

To create the spherical crystals, the researchers coaxed polystyrene beads (only one micron in diameter) to congregate around and completely cover tiny balls of water (tens of microns in diameter) suspended in an oily mixture.

The team then used a light microscope to view the spheres and digitally traced images of the crystalline patterns. Whereas a flat crystal pattern would consist of a regular pattern of adjacent, equilateral triangles, the researchers found the triangular pattern of the spherical crystal was disrupted and squeezed due to defects (a bead would have five or seven close neighbors instead of the six it would in a perfect lattice).

"We found that curvature can fundamentally change the arrangement of particles on the surface," said Bowick.

Smaller spheres had twelve isolated defects, but larger spheres showed jagged strings of defects the researchers dubbed scars. The scars are a coalescence of simple defects in the lattice pattern that begin and end within the crystal, unlike similar structures in flat crystals which begin and end at crystal surfaces. The researchers observed that the scars erupt in a predictable way based upon the size of the sphere and consistent with the predictions of their theory.

"These structures are a signature of the curved geometry and do not depend on the details of the particle interactions on the surface," said Bowick. "The scars should appear in any type of spherical packing or crystallization."

In addition to confirmation of the researchers’ approach, the new findings also shed light on how such structures form and persist in nature. Some viruses, such as the monkey cancer virus SV40, and some bacteria have similar spherical structures - knowledge of scar formation may reveal how to target chemical reactions at those sites, potentially leading to treatments for similar pathogens.

The research also sheds light on some of the most prevalent structures in nanoscale science and engineering, the fullerenes. Knowing how defects can arise within nanostructures may help researchers devise better methods to create fullerenes or other large molecules with desirable characteristics.

Josh Chamot | NSF News
Further information:
http://www.physics.iastate.edu/staff/travesset/Collo.htm
http://www.deas.harvard.edu/projects/weitzlab/
http://www.nsf.gov

More articles from Physics and Astronomy:

nachricht Further Improvement of Qubit Lifetime for Quantum Computers
09.12.2016 | Forschungszentrum Jülich

nachricht Electron highway inside crystal
09.12.2016 | Julius-Maximilians-Universität Würzburg

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Electron highway inside crystal

Physicists of the University of Würzburg have made an astonishing discovery in a specific type of topological insulators. The effect is due to the structure of the materials used. The researchers have now published their work in the journal Science.

Topological insulators are currently the hot topic in physics according to the newspaper Neue Zürcher Zeitung. Only a few weeks ago, their importance was...

Im Focus: Significantly more productivity in USP lasers

In recent years, lasers with ultrashort pulses (USP) down to the femtosecond range have become established on an industrial scale. They could advance some applications with the much-lauded “cold ablation” – if that meant they would then achieve more throughput. A new generation of process engineering that will address this issue in particular will be discussed at the “4th UKP Workshop – Ultrafast Laser Technology” in April 2017.

Even back in the 1990s, scientists were comparing materials processing with nanosecond, picosecond and femtosesecond pulses. The result was surprising:...

Im Focus: Shape matters when light meets atom

Mapping the interaction of a single atom with a single photon may inform design of quantum devices

Have you ever wondered how you see the world? Vision is about photons of light, which are packets of energy, interacting with the atoms or molecules in what...

Im Focus: Novel silicon etching technique crafts 3-D gradient refractive index micro-optics

A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.

Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...

Im Focus: Quantum Particles Form Droplets

In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.

“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

ICTM Conference 2017: Production technology for turbomachine manufacturing of the future

16.11.2016 | Event News

Innovation Day Laser Technology – Laser Additive Manufacturing

01.11.2016 | Event News

#IC2S2: When Social Science meets Computer Science - GESIS will host the IC2S2 conference 2017

14.10.2016 | Event News

 
Latest News

Researchers identify potentially druggable mutant p53 proteins that promote cancer growth

09.12.2016 | Life Sciences

Scientists produce a new roadmap for guiding development & conservation in the Amazon

09.12.2016 | Ecology, The Environment and Conservation

Satellites, airport visibility readings shed light on troops' exposure to air pollution

09.12.2016 | Health and Medicine

VideoLinks
B2B-VideoLinks
More VideoLinks >>>