The compound is a "piezoelectric," a material capable of changing one kind of energy into another—mechanical to electrical, or vice versa. Long employed in sonar systems to detect sound waves, more recently piezoelectrics have been applied in devices that require minuscule changes in position, such as the head that reads data from your computer's hard drive.
For decades, the industry standard piezoelectric has been PZT, a compound that contains titanium,zirconium, lead and oxygen. Crystals of PZT change a tiny fraction of a percent in size when a sound wave strikes them, and thisshape change creates an electrical impulse. Decades ago, it was discovered that PZT performs at its best when the titanium and zirconium appear in approximately equal proportions, but no one really understood why.
"The theories frequently concern what happens at the transition line between having a surplus of zirconium and one of titanium," says Peter Gehring of the NIST Center for Neutron Research (NCNR). "Some theories suggest that right near the transition zone, the atoms take on a special configuration that allows certain atoms to move more freely than they can otherwise. But because it's been hard to grow a crystal of PZT large enough to analyze, we couldn't completely test these ideas."
A breakthrough came when chemists at Canada's Simon Fraser University managed to grow single crystals of a few millimeters in size and sent them to the NCNR for examination with neutron scattering—a technique for determining the positions of individual atoms in a complex crystal structure by observing the patterns made by neutrons bouncing off it. The team, which also included researchers from the University of Oxford, the University of Tokyo, and the University of Warwick, was able to definitively rule out one of the proposed structures of PZT.
Instead, they found that each PZT crystal element likely assumes one of two possible forms that coexist within the larger crystal array. These forms are dictated by chemical composition, and they may influence how well the material performs on a large scale. Their findings also suggest that the change in behavior seen at the transition happens gradually, rather than at some sharply delineated proportion of zirconium to titanium.
Gehring says the results could be a step toward bettering PZT. "Determining the structure might give us the perspective necessary to design a piezoelectric material from first principles, instead of just playing around and seeing what works," he says. "That's what you need if you're ever going to build a better mousetrap."
* D. Phelan, X. Long, Y. Xie, Z.-G. Ye, A.M. Glazer, H. Yokota, P.A. Thomas and P.M. Gehring. Single crystal study of competing rhombohedral and monoclinic order in lead zirconate titanate. Physical Review Letters, Nov. 8, 2010, DOI: 10.1103/PhysRevLett.105.207601
Chad Boutin | Newswise Science News
Breaking the optical bandwidth record of stable pulsed lasers
24.01.2017 | Institut national de la recherche scientifique - INRS
European XFEL prepares for user operation: Researchers can hand in first proposals for experiments
24.01.2017 | European XFEL GmbH
A Swedish-German team of researchers has cleared up a key process for the artificial production of silk. With the help of the intense X-rays from DESY's...
For the first time ever, a cloud of ultra-cold atoms has been successfully created in space on board of a sounding rocket. The MAIUS mission demonstrates that quantum optical sensors can be operated even in harsh environments like space – a prerequi-site for finding answers to the most challenging questions of fundamental physics and an important innovation driver for everyday applications.
According to Albert Einstein's Equivalence Principle, all bodies are accelerated at the same rate by the Earth's gravity, regardless of their properties. This...
An important step towards a completely new experimental access to quantum physics has been made at University of Konstanz. The team of scientists headed by...
Yersiniae cause severe intestinal infections. Studies using Yersinia pseudotuberculosis as a model organism aim to elucidate the infection mechanisms of these...
Researchers from the University of Hamburg in Germany, in collaboration with colleagues from the University of Aarhus in Denmark, have synthesized a new superconducting material by growing a few layers of an antiferromagnetic transition-metal chalcogenide on a bismuth-based topological insulator, both being non-superconducting materials.
While superconductivity and magnetism are generally believed to be mutually exclusive, surprisingly, in this new material, superconducting correlations...
19.01.2017 | Event News
10.01.2017 | Event News
09.01.2017 | Event News
24.01.2017 | Physics and Astronomy
24.01.2017 | Life Sciences
24.01.2017 | Health and Medicine