Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:


Dual solidification mechanisms of liquid ternary Fe-Cu-Sn alloy

Peritectic solidification involves the nucleation and growth of the primary phase, the peritectic reaction of the primary phase with the remnant liquid phase, and the microstructural evolution of the product peritectic phase.
It provides an effective approach for the synthesis or processing of various kinds of advanced materials. Professor WEI Bingbo and his group from the Department of Applied Physics, Northwestern Polytechnical University (NPU), in Xi'an, China, have demonstrated novel dual solidification mechanisms for a ternary Fe47.5Cu47.5Sn5 peritectic-type alloy. Their work, entitled "Dual Solidification Mechanisms of Liquid Ternary Fe-Cu-Sn Alloy", was published in SCIENCE CHINA Physics, Mechanics & Astronomy. 2012; 55 (3): 450-459.

A ternary Fe47.5Cu47.5Sn5 alloy was rapidly solidified under bulk undercooling conditions. Two distinct solidification mechanisms for a ternary Fe47.5Cu47.5Sn5 alloy were noted under these conditions: peritectic solidification at moderate undercoolings below 196K, and macroscopic phase separation at greater undercoolings, which is shown in Fig.1. The alloy's microstructures consisted of an aFe solid solution, a (Cu) solid solution, and a b-Cu5.6Sn intermetallic compound. At small undercoolings such as DT=112K, a homogeneous macrostructure and only about 0.1% volume of a Cu-rich zone at the sample bottom were formed. As the bulk undercooling increased to 196K, liquid phase separation proceeded to a larger extent; this resulted in the Cu-rich zone taking up about 7% of sample volume.
Macrosegregation took place when undercooling exceeded 196K. In this case, the homogeneous alloy was separated into an Fe-rich zone floating up to the sample top and a Cu-rich zone descending down to the sample bottom. The Cu-rich zone maintained a slightly decreasing volume fraction of (from 53% down to -47%) in the still greater undercooling range of 246�K. The progression of macrosegregation was found to depend also on the time interval allowed for phase separation. When the phase separation time Dtps

(0.19TL), gFe dendrites display a growth velocity of only 100 mm/s. The reduction of dendritic growth velocity is caused mainly by two factors: (1) the solute diffusion speed is slowed down if bulk undercooling is continually increased, and (2) the tiny Cu-rich globules formed by phase separation may hinder the progression of the solid/liquid interface. However, it should be noted that the absolute values of dendritic growth velocity are one order of magnitude larger than those at the moderate undercooling range, although the latter case shows an increasing tendency of dendritic growth velocity. Credit: ©Science China Press

The Stokes motion driven by the density difference between the Fe-rich and Cu-rich liquid phases plays the dominant role in the progression of macroscopic segregation. As the thermodynamic barrier against the nucleation of a secondary liquid phase is usually much smaller than in the case of solid phase nucleation, a great number of Fe-rich and Cu-rich globules can be formed in the liquid phase. Once the size of an individual globule becomes sufficiently large, its Stokes motion prevails over all other kinds of movement. The calculated results show that the Stokes motion velocity increases rapidly along with an increase in globule size. A small Fe-rich globule with a 10mm radius displays a moving velocity of only 8.1mm/s in the alloy sample undercooled by 305K, while a large globule with a 100mm radius achieves a floating velocity of 805.5mm/s. Considering that the phase separation time Dtps of this alloy sample attains 11.8s, the large globules can float for a distance of 9.5mm. Such a moving distance covers the entire alloy sample, confirming that the Stokes motion is indeed responsible for the progression of macroscopic segregation.

The calculations also reveal that the Stokes motion velocity increases with bulk undercooling. The main reason for this lies in the fact that a greater bulk undercooling facilitates the achievement of macrosegregation and consequently leads to a larger density difference. It is evident that the subsequent solidification process of a macroscopically segregated Fe47.5Cu47.5Sn5 alloy should involve two successive stages: (1) the Fe-rich zone solidifies because of its higher liquidus temperature, and (2) the Cu-rich zone crystallizes at some lower temperatures T
... more about:
»5Cu47 »5Sn5 »6Sn »Astronomy »Cu-rich »Fe-Cu-Sn »Fe-rich »Fe47 »Mechanics

Whether or not metastable phase separation occurs, the rapid dendritic growth of the primary gFe phase always induces a thermal recalescence effect. Since gFe dendrites spread quickly throughout he alloy sample in the course of recalescence, the alloy's growth velocity may be roughly measured as the ratio of the sample size divided by its recalescence time. As bulk undercooling increases from 112 to 236K, the actually measured dendritic growth velocity rises from 7.8 to 68.3mm/s. These results indicate that the primary dendritic growth of the gFe phase in a ternary Fe47.5Cu47.5Sn5 alloy is quite sluggish when compared to the dendtritic growth displayed by a similar Co-Cu-Ni alloy. One reason for this finding is that this Fe47.5Cu47.5Sn5 alloy has a broad solidification temperature range and hence its primary dendritic growth remains consistently in the regime of solute diffusion-controlled growth. On the other hand, the introdution of an Sn solute further suppresses the advancement of a solid/liquid interface.

The occurrence of macrosegregation imposes a drastic suppression effect on primary dendritic growth. The maximum dendritic growth velocity of the gFe phase attains 400 mm/s at the bulk undercooling of 246K. In contrast, under the maximum bulk undercooling of 329K

Peritectic solidification requires a mutual reaction between the primary solid phase and the remnant liquid phase to form a new solid phase when the undercooling is below 196K. This is a typical solute diffusion-limited process, and it is rare for such a process to be completed. Two successive peritectic reactions are required for the successful completion of this process. First, primary gFe phase nucleates within the undercooled alloy must melt, grow dendritically, and react with the surrounding liquid phase to form the peritectic (Cu) phase, that is gFe+L®(Cu). This peritectic transformation is only partially fulfilled, resulting in the remains of many gFe dendrites that subsequently transform into the aFe phase. As a morphological feature of the peritectic product phase, a (Cu) solid solution always appears as haloes enveloping the dendritic fragments of the aFe phase. It is interesting to note that the (Cu) phase haloes often display two layers: an inner layer directly adjacent to the aFe phase that is designated as (Cu)i, and an outer layer marked as (Cu)o that surrounds the previous central part. This structural distinction results from the microsegregation of solutes within the peritectic (Cu) phase.

Next, as the undercooling increases, the macroscopic boundary between the Fe-rich and Cu-rich zones becomes gradually smooth and the gFe dendrites in the Fe-rich zone degenerate into an interconnected structure. (Cu) phase haloes appear around these decayed gFe dendrites, resulting from the peritectic reaction gFe+L®(Cu). The residual liquid phase then becomes so enriched with an Sn solute that the other peritectic transformation (Cu)+L®b-Cu5.6Sn is brought about in the Fe-rich zone. Thus, the white b-Cu5.6Sn intermetallic compound phase appears as the fillings of intergranular spacings between neighbouring (Cu) phase grains. Conversely, peritectic products are also characteristic of the solidified microstructures of the Cu-rich zone. The structural morphology of the Cu-rich zone is also typical of peritectic solidification. The peritectic (Cu) phase always envelops the fragments of primary gFe dendrites, whereas the peritectic b-Cu5.6Sn phase forms around the (Cu) phase in due sequence.

At the bulk undercooling of 305K, the Fe-rich zone and Cu-rich zone become clearly separated from each other during the phase separation time of 11.8s. It appears that the boundary between Fe-rich and Cu-rich zones has evolved into a sharp interface during this phase separation time. There are not discernible gFe dendrites in the Fe-rich zone, where (Cu) and b-Cu5.6Sn phases are distributed as dispersive particles inside an aFe phase matrix. The two sucessive peritectic transformations of the Cu-rich zone are gFe+L®(Cu) and (Cu)+L®b-Cu5.6Sn. As the remnant undercooling of the Cu-rich zone is still quite large at the end of the macroscopic phase separation process, the primary gFe phase can grow rapidly into well-branched dendrites.
EDS analyses have been performed on the solidification microstructures. Even at the small 112K undercooling, the aFe phase is found to contain 10.13 at%Cu and 0.27 at%Sn. Since the equilibrium solubility of Cu in the aFe phase is merely 1.9 at%Cu, this means that the aFe phase is highly supersaturated with a Cu element as a result of the solute trapping effect accompanying the rapid dendritic growth of the gFe phase. Both the inner and outer layers of the (Cu) phase possess roughly the same Fe content. However, they display quite different Sn contents: the (Cu)i layer has 9.11 at%Sn, whereas the (Cu)o layer dissolves only 5.47 at%Sn. The b-Cu5.6Sn intermetallic compound exhibits a remarkable Fe content of 4.02 at%Fe.

Reference: Wang W L, Zhang X M, Li L H et al. Dual solidification mechanisms of liquid ternary Fe-Cu-Sn alloy. SCIENCE CHINA Physics, Mechanics & Astronomy. 2012; 55 (3): 450-459. DOI: 10.1007/s11434-012-9930-1

W.L. Wang | EurekAlert!
Further information:

Further reports about: 5Cu47 5Sn5 6Sn Astronomy Cu-rich Fe-Cu-Sn Fe-rich Fe47 Mechanics

More articles from Physics and Astronomy:

nachricht Quantum optics allows us to abandon expensive lasers in spectroscopy
22.11.2017 | Lomonosov Moscow State University

nachricht Nano-watch has steady hands
22.11.2017 | University of Vienna

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Nanoparticles help with malaria diagnosis – new rapid test in development

The WHO reports an estimated 429,000 malaria deaths each year. The disease mostly affects tropical and subtropical regions and in particular the African continent. The Fraunhofer Institute for Silicate Research ISC teamed up with the Fraunhofer Institute for Molecular Biology and Applied Ecology IME and the Institute of Tropical Medicine at the University of Tübingen for a new test method to detect malaria parasites in blood. The idea of the research project “NanoFRET” is to develop a highly sensitive and reliable rapid diagnostic test so that patient treatment can begin as early as possible.

Malaria is caused by parasites transmitted by mosquito bite. The most dangerous form of malaria is malaria tropica. Left untreated, it is fatal in most cases....

Im Focus: A “cosmic snake” reveals the structure of remote galaxies

The formation of stars in distant galaxies is still largely unexplored. For the first time, astron-omers at the University of Geneva have now been able to closely observe a star system six billion light-years away. In doing so, they are confirming earlier simulations made by the University of Zurich. One special effect is made possible by the multiple reflections of images that run through the cosmos like a snake.

Today, astronomers have a pretty accurate idea of how stars were formed in the recent cosmic past. But do these laws also apply to older galaxies? For around a...

Im Focus: Visual intelligence is not the same as IQ

Just because someone is smart and well-motivated doesn't mean he or she can learn the visual skills needed to excel at tasks like matching fingerprints, interpreting medical X-rays, keeping track of aircraft on radar displays or forensic face matching.

That is the implication of a new study which shows for the first time that there is a broad range of differences in people's visual ability and that these...

Im Focus: Novel Nano-CT device creates high-resolution 3D-X-rays of tiny velvet worm legs

Computer Tomography (CT) is a standard procedure in hospitals, but so far, the technology has not been suitable for imaging extremely small objects. In PNAS, a team from the Technical University of Munich (TUM) describes a Nano-CT device that creates three-dimensional x-ray images at resolutions up to 100 nanometers. The first test application: Together with colleagues from the University of Kassel and Helmholtz-Zentrum Geesthacht the researchers analyzed the locomotory system of a velvet worm.

During a CT analysis, the object under investigation is x-rayed and a detector measures the respective amount of radiation absorbed from various angles....

Im Focus: Researchers Develop Data Bus for Quantum Computer

The quantum world is fragile; error correction codes are needed to protect the information stored in a quantum object from the deteriorating effects of noise. Quantum physicists in Innsbruck have developed a protocol to pass quantum information between differently encoded building blocks of a future quantum computer, such as processors and memories. Scientists may use this protocol in the future to build a data bus for quantum computers. The researchers have published their work in the journal Nature Communications.

Future quantum computers will be able to solve problems where conventional computers fail today. We are still far away from any large-scale implementation,...

All Focus news of the innovation-report >>>



Event News

Ecology Across Borders: International conference brings together 1,500 ecologists

15.11.2017 | Event News

Road into laboratory: Users discuss biaxial fatigue-testing for car and truck wheel

15.11.2017 | Event News

#Berlin5GWeek: The right network for Industry 4.0

30.10.2017 | Event News

Latest News

Corporate coworking as a driver of innovation

22.11.2017 | Business and Finance

PPPL scientists deliver new high-resolution diagnostic to national laser facility

22.11.2017 | Physics and Astronomy

Quantum optics allows us to abandon expensive lasers in spectroscopy

22.11.2017 | Physics and Astronomy

More VideoLinks >>>