Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Discovery of nonblinking semiconductor nanocrystals advances their applications

18.05.2009
Substantial advances for applications of nanocrystals in the fields requiring a continuous output of photons and high quantum efficiency may soon be realized due to discovery of non-blinking semiconductor nanocrystals.

This discovery recently announced by scientists at the Naval Research Laboratory (NRL), University of Rochester, Cornell University and Eastman Kodak Company is an important step to the use of the nanocrystals in various practical devices ranging from low-threshold lasers to the solar cells and biological imaging and tracking. The complete findings of the study are published on line in the May 10, 2009, issue of the journal Nature.

Colloidal nanocrystals are a new class of optical materials that essentially constitute a new form of matter that can be considered as "artificial atoms." Like atoms, they have discrete optical energy spectra that are tunable over a wide range of wavelengths by varying the nanocrystals' size. The widely tunable absorption band edge is controlled mainly by the nanocrystal size, resulting in widely tunable emission spectra. This tunability combined with the optical stability of nanocrystals and the great chemical flexibility in the nanocrystal growth have resulted in the widespread nanocrystal applications in use today.

Nanocrystals show quite high photoluminescence quantum efficiency of up to 70% at room temperature. The missing 30% efficiency turns out to be an intrinsic property of nanocrystals. Studies of single colloidal nanocrystals show that they randomly turn their photoluminescence on and off even under continuous light illumination. Dr. Alexander Efros, from NRL's Center for Computational Material Science, describes the blinking problem in this way, "Imagine the irritation and frustration you would feel if the bulb in your reading lamp started to blink. These same emotions are experienced by engineers and scientists who study single colloidal nanocrystals and try to use their fluorescent properties for biological imaging or lasing" (Nature Materials, vol. 7, 612 (2008)).

The blinking in nanocrystals was first reported 13 years ago, and it came as a surprise to researchers. Today, researchers agree that the blinking happens because when illuminated, nanocrystals can be charged (or ionized) and then neutralized. Under normal conditions when nanocrystal is neutral, a photon excites an electron-hole pair, which then recombines, emitting another photon and leading to photoluminescence. This process is called radiative recombination. If however, the nanocrystal is charged, the extra carrier triggers a process called non-radiative Auger recombination, where exciton energy is transferred to an extra electron or hole. Auger recombination occurs orders of magnitude faster than the radiative recombination. So photoluminescence is almost entirely suppressed in charged nanocrystals. Scientists still do not fully understand the origin of the charging and neutralization process. One of the photoexcited carriers (the electron or the hole) must be ejected from the nanocrystal. At some later time, the ejected charge returns to the nanocrystal (restoring charge neutrality and therefore radiative recombination). The details of these processes occur still are not understood.

Scientists are attempting to eliminate the problem of blinking nanocrystals. One common solution is to suppress nanocrystal ionization. This could be done, for example, by growing a very thick semiconductor shell around the nanocrystal core. However, blinking was reduced, not eliminated, because the fundament processes responsible for blinking - the non-radiative Auger recombination- were still present.

The team of researchers at University of Rochester, Eastman Kodak Company, Cornell University and NRL have taken a significant step toward solving this problem by synthesizing gradually-graded alloy CdZnSe core nanocrystals capped with a ZnSe semiconductor shell that never blinks. The highly unusual multi-peaked photoluminescence spectra clearly indicates also that these nanocrystals always have an extra charge. The observation of photoluminescence from charged (ionized) nanocrystals is direct proof that the nonradiative Auger recombination has been weakened by three orders of magnitude.

The Auger rate suppression is connected with softening the abrupt confined potential of typical core/shell nanocrystals in the structures with a radially graded alloy of CdZnSe into ZnSe. Future efforts will be focused on optimization of these nanocrystal structures with a goal to eliminate the nonradiative Auger processes completely. By completely suppressing blinking associated with Auger processes and "keeping the nanocrystal light bulb turned on," as Dr. Efros explains, researchers look to future breakthroughs for photonics, laser, and other optical applications of nanocrystals.

The research was conducted by Dr. Xiaoyong Wang, Dr. Megan Hahn and Prof. Todd Krauss from the Department of Chemistry at the University of Rochester; Dr. Xiaofan Ren, Dr. Keith Kahen and Dr. Manju Rajeswaran from Eastman Kodak Company; Mrs. Sara Maccagnano-Zacher and Prof. John Silcox, from School of Applied and Engineering Physics at Cornell University; and Dr. George Cragg and Dr. Alexander Efros from NRL's Material Science and Technology Division.

Donna McKinney | EurekAlert!
Further information:
http://www.nrl.navy.mil

More articles from Physics and Astronomy:

nachricht Strathclyde-led research develops world's highest gain high-power laser amplifier
29.05.2017 | University of Strathclyde

nachricht Camera on NASA's Lunar Orbiter survived 2014 meteoroid hit
29.05.2017 | NASA/Goddard Space Flight Center

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Strathclyde-led research develops world's highest gain high-power laser amplifier

The world's highest gain high power laser amplifier - by many orders of magnitude - has been developed in research led at the University of Strathclyde.

The researchers demonstrated the feasibility of using plasma to amplify short laser pulses of picojoule-level energy up to 100 millijoules, which is a 'gain'...

Im Focus: Can the immune system be boosted against Staphylococcus aureus by delivery of messenger RNA?

Staphylococcus aureus is a feared pathogen (MRSA, multi-resistant S. aureus) due to frequent resistances against many antibiotics, especially in hospital infections. Researchers at the Paul-Ehrlich-Institut have identified immunological processes that prevent a successful immune response directed against the pathogenic agent. The delivery of bacterial proteins with RNA adjuvant or messenger RNA (mRNA) into immune cells allows the re-direction of the immune response towards an active defense against S. aureus. This could be of significant importance for the development of an effective vaccine. PLOS Pathogens has published these research results online on 25 May 2017.

Staphylococcus aureus (S. aureus) is a bacterium that colonizes by far more than half of the skin and the mucosa of adults, usually without causing infections....

Im Focus: A quantum walk of photons

Physicists from the University of Würzburg are capable of generating identical looking single light particles at the push of a button. Two new studies now demonstrate the potential this method holds.

The quantum computer has fuelled the imagination of scientists for decades: It is based on fundamentally different phenomena than a conventional computer....

Im Focus: Turmoil in sluggish electrons’ existence

An international team of physicists has monitored the scattering behaviour of electrons in a non-conducting material in real-time. Their insights could be beneficial for radiotherapy.

We can refer to electrons in non-conducting materials as ‘sluggish’. Typically, they remain fixed in a location, deep inside an atomic composite. It is hence...

Im Focus: Wafer-thin Magnetic Materials Developed for Future Quantum Technologies

Two-dimensional magnetic structures are regarded as a promising material for new types of data storage, since the magnetic properties of individual molecular building blocks can be investigated and modified. For the first time, researchers have now produced a wafer-thin ferrimagnet, in which molecules with different magnetic centers arrange themselves on a gold surface to form a checkerboard pattern. Scientists at the Swiss Nanoscience Institute at the University of Basel and the Paul Scherrer Institute published their findings in the journal Nature Communications.

Ferrimagnets are composed of two centers which are magnetized at different strengths and point in opposing directions. Two-dimensional, quasi-flat ferrimagnets...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

Marine Conservation: IASS Contributes to UN Ocean Conference in New York on 5-9 June

24.05.2017 | Event News

AWK Aachen Machine Tool Colloquium 2017: Internet of Production for Agile Enterprises

23.05.2017 | Event News

Dortmund MST Conference presents Individualized Healthcare Solutions with micro and nanotechnology

22.05.2017 | Event News

 
Latest News

Camera on NASA's Lunar Orbiter survived 2014 meteoroid hit

29.05.2017 | Physics and Astronomy

Strathclyde-led research develops world's highest gain high-power laser amplifier

29.05.2017 | Physics and Astronomy

A 3-D look at the 2015 El Niño

29.05.2017 | Earth Sciences

VideoLinks
B2B-VideoLinks
More VideoLinks >>>