Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Killer pulses help characterize special surfaces

30.07.2008
Detecting deadly fumes in subways, toxic gases in chemical spills, and hidden explosives in baggage is becoming easier and more efficient with a measurement technique called surface-enhanced Raman scattering. To further improve the technique’s sensitivity, scientists must design better scattering surfaces, and more effective ways of evaluating them

Researchers at the University of Illinois, led by chemistry professor Dana Dlott, have devised a method to evaluate substrate surfaces by using a series of killer laser pulses.

They describe the method and report measurements for a commonly used substrate in the July 18 issue of the journal Science.

Surface-enhanced Raman scattering, which functions by adsorbing molecules of interest onto rough metal surfaces, typically enhances the Raman spectrum a million times. Hot spots can occur, however, where the electric field enhancement can be a billion or more.

... more about:
»Dlott »Enhancement »Laser »Raman »Substrate »technique

Current surface characterization techniques cannot tell hot spots from cold spots, and create an average value across the entire substrate surface.

“Looking at a spectrum, you can’t tell if it’s the result of a small number of molecules in hot spots or a large number of molecules in cold spots,” Dlott said. “Two materials could have the same average spectrum, but behave quite differently.”

Dlott, graduate student Ying Fang and postdoctoral research associate Nak-Hyun Seong came up with a way to measure the distribution of site enhancements on the substrate surface. Using killer laser pulses, their technique can count how many molecules are sitting in the hottest spots, how many are sitting in the coldest spots, and how many are sitting between the two extremes.

The killer pulse is a short duration laser pulse with a variable electric field. When the electric field is strong enough, it rips a molecule apart, “killing” it.

“If a molecule is in a very hot spot on the substrate, where the electric field enhancement is really big, it takes only a weak pulse to kill it,” Dlott said. “If the molecule is in a very cold spot, then it takes a really big laser pulse to kill it.”

Dlott, Fang and Seong demonstrated their technique by measuring the distribution of local enhancements for benzenethiolate molecules on a substrate of silver-coated nanospheres 330 nanometers in diameter.

To characterize the surface, the researchers first measured the initial Raman intensity. Then they put in a weak killer pulse, which destroyed the molecules in the hottest spots. After measuring the new Raman intensity, they put in a bigger pulse and destroyed the molecules in slightly colder spots. The researchers continued with bigger and bigger pulses until all the benzenethiolate molecules were destroyed.

“We found the hottest spots comprised just 63 molecules per million, but contributed 24 percent of the overall Raman intensity,” Dlott said. “We also found the coldest spots contained 61 percent of the molecules, but contributed only 4 percent of the overall intensity.”

Measurements like these, of the distribution of local site enhancements, will help researchers design better scattering surfaces for sensor applications.

Prior to this work, no one knew if the Raman intensity was dominated by a small number of hot molecules or a large number of cold ones. Dlott, Fang and Seong have answered that important scientific question; not just with a yes or no, but with a full determination of exactly how many molecules there are in each level of hot or cold.

“Now, when evaluating a new surface-enhanced Raman material, instead of knowing just the average intensity, we know the highest, the lowest, and everything in between,” Dlott said.

Funding was provided by the National Science Foundation, the Air Force Office of Scientific Research, and the Army Research Office. Electron microscopy was carried out in the university’s Center for Microanalysis of Materials, which is supported by the U.S. Department of Energy.

James E. Kloeppel | University of Illinois
Further information:
http://www.uiuc.edu.

Further reports about: Dlott Enhancement Laser Raman Substrate technique

More articles from Life Sciences:

nachricht Newly designed molecule binds nitrogen
23.02.2018 | Julius-Maximilians-Universität Würzburg

nachricht Atomic Design by Water
23.02.2018 | Max-Planck-Institut für Eisenforschung GmbH

All articles from Life Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Attoseconds break into atomic interior

A newly developed laser technology has enabled physicists in the Laboratory for Attosecond Physics (jointly run by LMU Munich and the Max Planck Institute of Quantum Optics) to generate attosecond bursts of high-energy photons of unprecedented intensity. This has made it possible to observe the interaction of multiple photons in a single such pulse with electrons in the inner orbital shell of an atom.

In order to observe the ultrafast electron motion in the inner shells of atoms with short light pulses, the pulses must not only be ultrashort, but very...

Im Focus: Good vibrations feel the force

A group of researchers led by Andrea Cavalleri at the Max Planck Institute for Structure and Dynamics of Matter (MPSD) in Hamburg has demonstrated a new method enabling precise measurements of the interatomic forces that hold crystalline solids together. The paper Probing the Interatomic Potential of Solids by Strong-Field Nonlinear Phononics, published online in Nature, explains how a terahertz-frequency laser pulse can drive very large deformations of the crystal.

By measuring the highly unusual atomic trajectories under extreme electromagnetic transients, the MPSD group could reconstruct how rigid the atomic bonds are...

Im Focus: Developing reliable quantum computers

International research team makes important step on the path to solving certification problems

Quantum computers may one day solve algorithmic problems which even the biggest supercomputers today can’t manage. But how do you test a quantum computer to...

Im Focus: In best circles: First integrated circuit from self-assembled polymer

For the first time, a team of researchers at the Max-Planck Institute (MPI) for Polymer Research in Mainz, Germany, has succeeded in making an integrated circuit (IC) from just a monolayer of a semiconducting polymer via a bottom-up, self-assembly approach.

In the self-assembly process, the semiconducting polymer arranges itself into an ordered monolayer in a transistor. The transistors are binary switches used...

Im Focus: Demonstration of a single molecule piezoelectric effect

Breakthrough provides a new concept of the design of molecular motors, sensors and electricity generators at nanoscale

Researchers from the Institute of Organic Chemistry and Biochemistry of the CAS (IOCB Prague), Institute of Physics of the CAS (IP CAS) and Palacký University...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

VideoLinks
Industry & Economy
Event News

2nd International Conference on High Temperature Shape Memory Alloys (HTSMAs)

15.02.2018 | Event News

Aachen DC Grid Summit 2018

13.02.2018 | Event News

How Global Climate Policy Can Learn from the Energy Transition

12.02.2018 | Event News

 
Latest News

Basque researchers turn light upside down

23.02.2018 | Physics and Astronomy

Finnish research group discovers a new immune system regulator

23.02.2018 | Health and Medicine

Attoseconds break into atomic interior

23.02.2018 | Physics and Astronomy

VideoLinks
Science & Research
Overview of more VideoLinks >>>