Stephan Link wants to understand how nanomaterials align, and his lab's latest work is a step in the right direction.
Link's Rice University group has found a way to use gold nanorods as orientation sensors by combining their plasmonic properties with polarization imaging techniques.
That may make it possible to see and perhaps track single nanoparticles over long periods. It would give researchers new information about materials, including living systems, that incorporate them.
"With a spherical particle, you don't have any information about how it's oriented," said Link, an assistant professor of chemistry and electrical and computer engineering at Rice. "We wanted to see if we could determine the orientation of the nanorods, and eventually we'd like to be able to measure the orientation of the environment they're in. We think this technique could be really useful for that."
Link, primary author Wei-Shun Chang, a Rice research scientist, and their collaborators reported their results this week in the online edition of the Proceedings of the National Academy of Sciences.
Seeing a single nanoparticle is nothing new. A scanning tunneling microscope (STM) can capture images of particles down to a few nanometers; particles tagged with fluorescent molecules can be seen for as long as the fluorophores are active. Link used this latter method to show nanocars rolling at room temperature last year.
But there are problems with each of those techniques. STMs see nanotubes or quantum dots just fine as long as they're more or less isolated on a conductive surface. But in the wild, the particles would get lost amid the clutter of everything else the microscope sees. And while fluorophores can help pick particles out of the crowd, they can deteriorate in as little as 30 seconds, which limits their usefulness.
Gold nanorods can be "lit up" at will. Lasers at particular wavelengths excite surface plasmons that absorb the energy and emit a heat signature that can be detected by a probe laser. Because plasmons are highly polarized along a nanorod's length, reading the signal while turning the polarization of the laser tells researchers precisely how the rod is oriented.
An electron microscope photo from the new paper shows nanorods about 75 nanometers long and 25 nanometers wide on a glass slide at 90-degree angles to each other. An adjacent photothermal image shows them as pixilated smudges. The smudges are strongest when the laser polarization aligns lengthwise with the nanorods, but they disappear when the laser polarization and rods are 90 degrees out of phase.
"With plasmonics, you always have two properties: absorption and scattering," Link said. "Depending on the size, one or the other dominates. What's unique is that it's now possible to do both on the same structure or do it individually -- so we can only measure absorption or only measure scattering."
Nanorods much smaller than 50 nanometers are not detectable by some scattering methods, Link said, but photothermal detection should work with metallic particles as small as five nanometers; this makes them useful for biological applications. "These gold nanorods are biocompatible. They are not toxic to cells," said Chang, noting their similarity to gold nanoshells currently in human cancer therapy trials based on research by Rice scientists Naomi Halas and Jennifer West.
"Our work is more geared to the fundamentals," Link said of the basic nature of his group's research. "Maybe we can optimize the conditions, and then a physician or somebody who's engineering a probe can take it from there.
"Our place is a little further down the chain of development. I'm happy with that."
Co-authors of the paper are Rice graduate students Ji Won Ha and Liane Slaughter. The Robert A. Welch Foundation and 3M supported the work.
View the paper at http://www.pnas.org/content/early/2010/01/25/0910127107.abstract.
Download images at http://www.rice.edu/nationalmedia/images/NANOROD.
David Ruth | EurekAlert!
Move over, Superman! NIST method sees through concrete to detect early-stage corrosion
27.04.2017 | National Institute of Standards and Technology (NIST)
Control of molecular motion by metal-plated 3-D printed plastic pieces
27.04.2017 | Ecole Polytechnique Fédérale de Lausanne
More and more automobile companies are focusing on body parts made of carbon fiber reinforced plastics (CFRP). However, manufacturing and repair costs must be further reduced in order to make CFRP more economical in use. Together with the Volkswagen AG and five other partners in the project HolQueSt 3D, the Laser Zentrum Hannover e.V. (LZH) has developed laser processes for the automatic trimming, drilling and repair of three-dimensional components.
Automated manufacturing processes are the basis for ultimately establishing the series production of CFRP components. In the project HolQueSt 3D, the LZH has...
Reflecting the structure of composites found in nature and the ancient world, researchers at the University of Illinois at Urbana-Champaign have synthesized thin carbon nanotube (CNT) textiles that exhibit both high electrical conductivity and a level of toughness that is about fifty times higher than copper films, currently used in electronics.
"The structural robustness of thin metal films has significant importance for the reliable operation of smart skin and flexible electronics including...
The nearby, giant radio galaxy M87 hosts a supermassive black hole (BH) and is well-known for its bright jet dominating the spectrum over ten orders of magnitude in frequency. Due to its proximity, jet prominence, and the large black hole mass, M87 is the best laboratory for investigating the formation, acceleration, and collimation of relativistic jets. A research team led by Silke Britzen from the Max Planck Institute for Radio Astronomy in Bonn, Germany, has found strong indication for turbulent processes connecting the accretion disk and the jet of that galaxy providing insights into the longstanding problem of the origin of astrophysical jets.
Supermassive black holes form some of the most enigmatic phenomena in astrophysics. Their enormous energy output is supposed to be generated by the...
The probability to find a certain number of photons inside a laser pulse usually corresponds to a classical distribution of independent events, the so-called...
Microprocessors based on atomically thin materials hold the promise of the evolution of traditional processors as well as new applications in the field of flexible electronics. Now, a TU Wien research team led by Thomas Müller has made a breakthrough in this field as part of an ongoing research project.
Two-dimensional materials, or 2D materials for short, are extremely versatile, although – or often more precisely because – they are made up of just one or a...
28.04.2017 | Event News
20.04.2017 | Event News
18.04.2017 | Event News
28.04.2017 | Medical Engineering
28.04.2017 | Earth Sciences
28.04.2017 | Life Sciences