Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:


Scientists uncover origin of high-temperature superconductivity in copper-oxide compound


Analysis of thousands of samples reveals that the compound becomes superconducting at an unusually high temperature because local electron pairs form a 'superfluid' that flows without resistance

Since the 1986 discovery of high-temperature superconductivity in copper-oxide compounds called cuprates, scientists have been trying to understand how these materials can conduct electricity without resistance at temperatures hundreds of degrees above the ultra-chilled temperatures required by conventional superconductors. Finding the mechanism behind this exotic behavior may pave the way for engineering materials that become superconducting at room temperature. Such a capability could enable lossless power grids, more affordable magnetically levitated transit systems, and powerful supercomputers, and change the way energy is produced, transmitted, and used globally.

Brookhaven Lab physicist Ivan Bozovic explains why a copper-oxide compound can conduct electricity without resistance at temperatures well above those required by conventional superconductors.

Credit: Brookhaven National Laboratory

Now, physicists at the U.S. Department of Energy's (DOE) Brookhaven National Laboratory have an explanation for why the temperature at which cuprates become superconducting is so high. After growing and analyzing thousands of samples of a cuprate known as LSCO for the four elements it contains (lanthanum, strontium, copper, and oxygen), they determined that this "critical" temperature is controlled by the density of electron pairs--the number of electron pairs per unit area. This finding, described in a Nature paper published August 17, challenges the standard theory of superconductivity, which proposes that the critical temperature depends instead on the strength of the electron pairing interaction.

"Solving the enigma of high-temperature superconductivity has been the focus of condensed matter physics for more than 30 years," said Ivan Bozovic, a senior physicist in Brookhaven Lab's Condensed Matter Physics and Materials Science Department who led the study. "Our experimental finding provides a basis for explaining the origin of high-temperature superconductivity in the cuprates--a basis that calls for an entirely new theoretical framework."

According to Bozovic, one of the reasons cuprates have been so difficult to study is because of the precise engineering required to generate perfect crystallographic samples that contain only the high-temperature superconducting phase.

"It is a materials science problem. Cuprates can have up to 50 atoms per unit cell and the elements can form hundreds of different compounds, likely resulting in a mixture of different phases," said Bozovic.

That's why Bozovic and his research team grew their more than 2,500 LSCO samples by using a custom-designed molecular beam epitaxy system that places single atoms onto a substrate, layer by layer. This system is equipped with advanced surface-science tools, such as those for absorption spectroscopy and electron diffraction, that provide real-time information about the surface morphology, thickness, chemical composition, and crystal structure of the resulting thin films.

"Monitoring these characteristics ensures there aren't any irregular geometries, defects, or precipitates from secondary phases in our samples," Bozovic explained.

In engineering the LSCO films, Bozovic chemically added strontium atoms, which produce mobile electrons that pair up in the copper-oxide layers where superconductivity occurs. This "doping" process allows LSCO and other cuprates--normally insulating materials--to become superconducting.

For this study, Bozovic added strontium in amounts beyond the doping level required to induce superconductivity. Earlier studies on this "overdoping" had indicated that the density of electron pairs decreases as the doping concentration is increased. Scientists had tried to explain this surprising experimental finding by attributing it to different electronic orders competing with superconductivity, or electron pair breaking caused by impurities or disorder in the lattice. For example, they had thought that geometrical defects, such as displaced or missing atoms, could be at play.

To test these explanations, Bozovic and his team measured the magnetic and electronic properties of their engineered LSCO films. They used a technique called mutual inductance to determine the magnetic penetration depth (the distance a magnetic field transmits through a superconductor), which indicates the density of electron pairs.

Their measurements established a precise linear relationship between the critical temperature and electron pair density: both continue to decrease as more dopant is added, until no electrons pair up at all, while the critical temperature drops to near-zero Kelvin (minus 459 degrees Fahrenheit). According to the standard understanding of metals and conventional superconductors, this result is unexpected because LSCO becomes more metallic the more it is overdoped.

"Disorder, phase separation, or electron pair breaking would have the reverse effect by introducing scattering that impedes the flow of electrons, thus making the material more resistive, i.e. less metallic," said Bozovic.

If Bozovic's team is correct that critical temperature is controlled by electron pair density, then it seems that small, local pairs of electrons are behind the high temperature at which cuprates become superconducting. Previous experiments have established that the size of electron pairs is much smaller in cuprates than in conventional superconductors, whose pairs are so large that they overlap. Understanding what interaction makes the electron pairs so small in cuprates is the next step in the quest to solve the mystery of high-temperature superconductivity.


Bozovic's team included Brookhaven physicists Anthony Bollinger and Jie Wu, supported by funding provided by DOE's Office of Science, and postdoctoral researcher Xi He, supported by the Gordon and Betty Moore Foundation.

Brookhaven National Laboratory is supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit

Media Contact

Ariana Tantillo


Ariana Tantillo | EurekAlert!

More articles from Physics and Astronomy:

nachricht Prediction: More gas-giants will be found orbiting Sun-like stars
22.02.2017 | Carnegie Institution for Science

nachricht NASA's fermi finds possible dark matter ties in andromeda galaxy
22.02.2017 | NASA/Goddard Space Flight Center

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Breakthrough with a chain of gold atoms

In the field of nanoscience, an international team of physicists with participants from Konstanz has achieved a breakthrough in understanding heat transport

In the field of nanoscience, an international team of physicists with participants from Konstanz has achieved a breakthrough in understanding heat transport

Im Focus: DNA repair: a new letter in the cell alphabet

Results reveal how discoveries may be hidden in scientific “blind spots”

Cells need to repair damaged DNA in our genes to prevent the development of cancer and other diseases. Our cells therefore activate and send “repair-proteins”...

Im Focus: Dresdner scientists print tomorrow’s world

The Fraunhofer IWS Dresden and Technische Universität Dresden inaugurated their jointly operated Center for Additive Manufacturing Dresden (AMCD) with a festive ceremony on February 7, 2017. Scientists from various disciplines perform research on materials, additive manufacturing processes and innovative technologies, which build up components in a layer by layer process. This technology opens up new horizons for component design and combinations of functions. For example during fabrication, electrical conductors and sensors are already able to be additively manufactured into components. They provide information about stress conditions of a product during operation.

The 3D-printing technology, or additive manufacturing as it is often called, has long made the step out of scientific research laboratories into industrial...

Im Focus: Mimicking nature's cellular architectures via 3-D printing

Research offers new level of control over the structure of 3-D printed materials

Nature does amazing things with limited design materials. Grass, for example, can support its own weight, resist strong wind loads, and recover after being...

Im Focus: Three Magnetic States for Each Hole

Nanometer-scale magnetic perforated grids could create new possibilities for computing. Together with international colleagues, scientists from the Helmholtz Zentrum Dresden-Rossendorf (HZDR) have shown how a cobalt grid can be reliably programmed at room temperature. In addition they discovered that for every hole ("antidot") three magnetic states can be configured. The results have been published in the journal "Scientific Reports".

Physicist Dr. Rantej Bali from the HZDR, together with scientists from Singapore and Australia, designed a special grid structure in a thin layer of cobalt in...

All Focus news of the innovation-report >>>



Event News

Booth and panel discussion – The Lindau Nobel Laureate Meetings at the AAAS 2017 Annual Meeting

13.02.2017 | Event News

Complex Loading versus Hidden Reserves

10.02.2017 | Event News

International Conference on Crystal Growth in Freiburg

09.02.2017 | Event News

Latest News

Organ-on-a-chip mimics heart's biomechanical properties

23.02.2017 | Health and Medicine

Light-driven reaction converts carbon dioxide into fuel

23.02.2017 | Life Sciences

Oil and gas wastewater spills alter microbes in West Virginia waters

23.02.2017 | Life Sciences

More VideoLinks >>>