The alloy may prove to be a long-sought material that will permit magnetic cooling instead of the gas-compression systems used for home refrigeration and air conditioning. The magnetic cooling technique, though used for decades in science and industry, has yet to find application in the home because of technical and environmental hurdles—but the NIST collaboration may have overcome them.
Magnetic cooling relies on materials called magnetocalorics, which heat up when exposed to a powerful magnetic field. After they cool off by radiating this heat away, the magnetic field is removed, and their temperature drops again, this time dramatically. The effect can be used in a classic refrigeration cycle, and scientists have attained temperatures of nearly absolute zero this way. Two factors have kept magnetic cooling out of the consumer market: most magnetocalorics that function at close to room temperature require both the prohibitively expensive rare metal gadolinium and arsenic, a deadly toxin.But conventional gas-compression refrigerators have their own drawbacks. They commonly use hydrofluorocarbons (HFCs), greenhouse gases that can contribute to climate change if they escape into the atmosphere. In addition, it is becoming increasingly difficult to improve traditional refrigeration. “The efficiency of the gas cycle has pretty much maxed out,” said Jeff Lynn of NCNR. “The idea is to replace that cycle with something else.”
Working alongside (and inspired by) visiting scientists from the Beijing University of Technology, the team used NIST’s neutron diffraction equipment to analyze the novel alloy. They found that when exposed to a magnetic field, the newfound material’s crystal structure completely changes, which explains its exceptional performance.
“Understanding how to fine-tune this change in crystal structure may allow us to get our alloy’s efficiency even higher,” says NIST crystallographer Qing Huang. “We are still playing with the composition, and if we can get it to magnetize uniformly, we may be able to further improve the efficiency.”
* D. Liu, M. Yue, J. Zhang, T.M. McQueen, J.W. Lynn, X. Wang, Y. Chen, J. Li, R.J. Cava, X. Liu, Z. Altounian and Q. Huang. Origin and tuning of the magnetocaloric effect for the magnetic refrigerant MnFe(P1-xGex). Physical Review B. Vol. 79, 014435 (2009)
Members of the collaboration include scientists from NIST, Beijing University of Technology, Princeton University and McGill University. Funding for the project was provided by NIST.
Chad Boutin | EurekAlert!
Further reports about: > Huang > NIST > air conditioning > classic refrigeration cycle > consumer market > crystal structure > electricity-guzzling cooling system > exotic metal > gas-compression systems > greenhouse gas > home refrigeration > hydrofluorocarbons > magnetic cooling > magnetic cooling technique > magnetic field > magnetocalorics > material’s crystal structure > powerful magnetic field > refrigerator’s humming
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