Many chemical processes run so fast that they are only roughly understood. To clarify these processes, a team from the Technical University of Munich (TUM) has now developed a methodology with a resolution of quintillionths of a second. The new technology stands to help better understand processes like photosynthesis and develop faster computer chips.
An important intermediary step in many chemical processes is ionization. A typical example of this is photosynthesis. The reactions take only a few femtoseconds (quadrillionths of a second) or even merely a few hundred attoseconds (quintillionths of a second). Because they run so extremely fast, only the initial and final products are known, but not the reaction paths or the intermediate products.
Prof. Dr. Birgitta Bernhardt measuring at the Department of Physics at the Technical University of Munich.
Photo: Michael Mittermair / TUM
To observe such ultrafast processes, science needs a measurement technology that is faster than the observed process itself. So-called “pump-probe spectroscopy” makes this possible.
Here, the sample is excited using an initial laser pulse, which sets the reaction into motion. A second, time-delayed pulse queries the momentary state of the process. Multiple repetitions of the reaction with different time delays result in individual stop-motion images, which can then be compiled into a “film clip”.
Two eyes see more than one
Now, a team of scientists headed by Birgitta Bernhardt, a former staff member at the Chair of Laser and X-ray Physics at TU Munich and meanwhile junior professor at the Institute of Applied Physics at the University of Jena, have for the first time succeeded in combining two pump-probe spectroscopy techniques using the inert gas krypton. This allowed them to shed light on the ultrafast ionization processes in a precision that has simply not been possible hitherto.
“Prior to our experiment, one could observe either which part of the exciting light was absorbed by the sample over time or measure what kind of and how many ions were created in the process,” explains Bernhardt. “We have now combined the two techniques, which allows us to observe the precise steps by which the ionization takes place, how long these intermediate products exist and what precisely the exciting laser pulse causes in the sample.”
Ultrafast processes under control
The combination of the two measuring techniques allows the scientists not only to record the ultrafast ionization processes. Thanks to the variation in the intensity of the second, probing laser pulse, they can now, for the first time, also control and in this way also influence the ionization dynamics.
“This kind of control is a very powerful instrument,” explains Bernhardt. “If we can precisely understand and even influence fast ionization processes, we are able to learn a lot about light-driven processes like photosynthesis – especially about the initial moments in which this complex machinery is set into motion and which is hardly understood to date.”
The technology developed by Bernhardt and her colleagues is also interesting for the development of new, faster computer chips in which the ionization of silicon plays a significant role. If the ionization states of silicon can not only be sampled on such a short time scale, but can also be set – as the first experiments with krypton suggest – scientists might one day be able to use this to develop novel and even faster computer technologies.
The work is the result of a collaboration between the workgroups led by Prof. Reinhard Kienberger, who heads the Chair of Laser and X-ray Physics at TU Munich and Stephan Fritzsche, professor at the Institute of Theoretical Physics of the Friedrich Schiller University of Jena.
The research was funded by the European Research Council (ERC), the German Federal Ministry of Education and Research (BMBF), the Max Planck Society, the Max Planck Institute of Quantum Optics, the German Research Foundation (in the context of the Cluster of Excellence Munich Center for Advanced Photonics, MAP), the Alexander von Humboldt Foundation, the Carl Zeiss Foundation, the Donostia International Physics Center of the Donostia-San Sebastián University (Spain) and the workgroup Small Quantum Systems of the European XFEL in Hamburg.
Konrad Hütten, Michael Mittermair, Sebastian O. Stock, Randolf Beerwerth, Vahe Shirvanyan, Johann Riemensberger, Andreas Duensing, Rupert Heider, Martin S. Wagner, Alexander Guggenmos, Stephan Fritzsche, Nikolay M. Kabachnik, Reinhard Kienberger and Birgitta Bernhardt.
Ultrafast Quantum Control of Ionization Dynamics in Krypton
Nature Communications, 9, 719 (218) – DOI: 10.1038/s41467-018-03122-1
Prof. Dr. Birgitta Bernhardt (Jun.-Prof.)
Abbe Center of Photonics
Albert-Einstein-Straße 6, 07745 Jena, Germany
Tel.: +49 3641 94 7818 – E-mail: Birgitta.Bernhardt@uni-jena.de
Prof. Dr. Reinhard Kienberger
Technical University of Munich
Chair for Laser and X-ray Physics, E11
James Frank Str., 85748 Garching, Germany
Tel.: +49 89 289 12840 – E-mail: firstname.lastname@example.org
https://www.tum.de/nc/en/about-tum/news/press-releases/detail/article/34499/ Link to the press release
Dr. Ulrich Marsch | Technische Universität München
One-way roads for spin currents
23.05.2018 | Singapore University of Technology and Design
Tunable diamond string may hold key to quantum memory
23.05.2018 | Harvard John A. Paulson School of Engineering and Applied Sciences
A research team led by physicists at the Technical University of Munich (TUM) has developed molecular nanoswitches that can be toggled between two structurally different states using an applied voltage. They can serve as the basis for a pioneering class of devices that could replace silicon-based components with organic molecules.
The development of new electronic technologies drives the incessant reduction of functional component sizes. In the context of an international collaborative...
At the LASYS 2018, from June 5th to 7th, the Laser Zentrum Hannover e.V. (LZH) will be showcasing processes for the laser material processing of tomorrow in hall 4 at stand 4E75. With blown bomb shells the LZH will present first results of a research project on civil security.
At this year's LASYS, the LZH will exhibit light-based processes such as cutting, welding, ablation and structuring as well as additive manufacturing for...
There are videos on the internet that can make one marvel at technology. For example, a smartphone is casually bent around the arm or a thin-film display is rolled in all directions and with almost every diameter. From the user's point of view, this looks fantastic. From a professional point of view, however, the question arises: Is that already possible?
At Display Week 2018, scientists from the Fraunhofer Institute for Applied Polymer Research IAP will be demonstrating today’s technological possibilities and...
So-called quantum many-body scars allow quantum systems to stay out of equilibrium much longer, explaining experiment | Study published in Nature Physics
Recently, researchers from Harvard and MIT succeeded in trapping a record 53 atoms and individually controlling their quantum state, realizing what is called a...
The historic first detection of gravitational waves from colliding black holes far outside our galaxy opened a new window to understanding the universe. A...
02.05.2018 | Event News
13.04.2018 | Event News
12.04.2018 | Event News
24.05.2018 | Power and Electrical Engineering
23.05.2018 | Life Sciences
23.05.2018 | Life Sciences