Superconductivity is a rare physical state in which matter is able to conduct electricity--maintain a flow of electrons--without any resistance. It can only be found in certain materials, and even then it can only be achieved under controlled conditions of low temperatures and high pressures. New research from a team including Carnegie's Elissaios Stavrou, Xiao-Jia Chen, and Alexander Goncharov hones in on the structural changes underlying superconductivity in iron arsenide compounds--those containing iron and arsenic. It is published by Scientific Reports.
Although superconductivity has many practical applications for electronics (including scientific research instruments), medical engineering (MRI and NMR machines), and potential future applications including high-performance power transmission and storage, and very fast train travel, the difficulty of creating superconducting materials prevents it from being used to its full potential. As such, any newly discovered superconducting ability is of great interest to scientists and engineers.
This is the tetragonal crystal structure of NaFe2As2, courtesy of Alexander Goncharov. Sodium (Na) is represented by the black balls, iron (Fe) by the red balls, and arsenic (As) by the yellow balls. Courtesy of Alexander Goncharov.
Credit: Alexander Goncharov
This is the collapsed tetragonal crystal structure of NaFe2As2, with arsenic (As) atoms in a 5-fold coordination, courtesy of Alexander Goncharov. Sodium (Na) is represented by the black balls, iron (Fe) by the red balls, and arsenic (As) by the yellow balls. Courtesy of Alexander Goncharov.
Credit: Alexander Goncharov
Iron arsenides are relatively recently discovered superconductors. The nature of superconductivity in these particular materials remains a challenge for modern solid state physics. If the complex links between superconductivity, structure, and magnetism in these materials are unlocked, then iron arsenides could potentially be used to reveal superconductivity at much higher temperatures than previously seen, which would vastly increase the ease of practical applications for superconductivity.
When iron arsenide is combined with a metal--such as in the sodium-containing NaFe2As2 compound studied here--it was known that the ensuing compound is crystallized in a tetrahedral structure. But until now, a detailed structure of the atomic positions involved and how they change under pressure had not been determined.
The layering of arsenic and iron (As-Fe-As) in this structure is believed to be key to the compound's superconductivity. However, under pressure, this structure is thought to be partially misshapen into a so-called collapsed tetragonal lattice, which is no longer capable of superconducting, or has diminished superconducting ability.
The team used experimental evidence and modeling under pressure to actually demonstrate these previously theorized structural changes--tetragonal to collapsed tetragonal--on the atomic level. This is just the first step toward definitively determining the link between structure and superconductivity, which could potentially make higher-temperature superconductivity a real possibility.
They showed that at about 40,000 times normal atmospheric pressure (4 gigapascals), NaFe2As2 takes on the collapsed tetragonal structure. This changes the angles in the arsenic-iron-arsenic layers and is coincident with the loss in superconductivity. Moreover, they found that this transition is accompanied by a major change in bonding coordination in the formation of the interlayer arsenic-arsenic bonds. A direct consequence of this new coordination is that the system loses its two-dimensionality, and with it, superconductivity.
"Our findings are an important step in identifying the hypothesized connection between structure and superconductivity in iron-containing compounds," Goncharov said. "Understanding the loss of superconductivity on an atomic level could enhance our ease of manufacturing such compounds for practical applications, as well as improving our understanding of condensed matter physics."
The paper's other co-authors are: Artem Oganov of Stony Brook University, the Moscow Institute of Physics and Technology, and Northwestern Polytechnical University Xi'an; and Ai-Feng Wang, Ya-Jun Yan, Xi-Gang Luo, and Xian-Hui Chen of the University of Science and Technology of China, Hefei, Anhui;
This work was supported by DARPA, the Carnegie Institution of Canada, EFree (the DOE EFRC center at the Carnegie Institution for Science), the government of the Russian Federation, the Ministry of Education and Science of the Russian Federation.
GSECARS is supported by the U.S. NSF and DOE Geosciences. Use of the APS was supported by the DOE-BES. Calculations were performed on XSEDE facilities and on the cluster of the Center for Functional Nanomaterials, BNL, which is supported by the DOE-BES. Sample growth was supported by the Natural Science Foundation of China, the ''Strategic Priority Research Program (B)'' of the Chinese Academy of Sciences, and the National Basic Research Program of China.
The Carnegie Institution for Science is a private, nonprofit organization headquartered in Washington, D.C., with six research departments throughout the U.S. Since its founding in 1902, the Carnegie Institution has been a pioneering force in basic scientific research. Carnegie scientists are leaders in plant biology, developmental biology, astronomy, materials science, global ecology, and Earth and planetary science.
Alexander Goncharov | EurekAlert!
NASA's SDO sees partial eclipse in space
29.05.2017 | NASA/Goddard Space Flight Center
Strathclyde-led research develops world's highest gain high-power laser amplifier
29.05.2017 | University of Strathclyde
The world's highest gain high power laser amplifier - by many orders of magnitude - has been developed in research led at the University of Strathclyde.
The researchers demonstrated the feasibility of using plasma to amplify short laser pulses of picojoule-level energy up to 100 millijoules, which is a 'gain'...
Staphylococcus aureus is a feared pathogen (MRSA, multi-resistant S. aureus) due to frequent resistances against many antibiotics, especially in hospital infections. Researchers at the Paul-Ehrlich-Institut have identified immunological processes that prevent a successful immune response directed against the pathogenic agent. The delivery of bacterial proteins with RNA adjuvant or messenger RNA (mRNA) into immune cells allows the re-direction of the immune response towards an active defense against S. aureus. This could be of significant importance for the development of an effective vaccine. PLOS Pathogens has published these research results online on 25 May 2017.
Staphylococcus aureus (S. aureus) is a bacterium that colonizes by far more than half of the skin and the mucosa of adults, usually without causing infections....
Physicists from the University of Würzburg are capable of generating identical looking single light particles at the push of a button. Two new studies now demonstrate the potential this method holds.
The quantum computer has fuelled the imagination of scientists for decades: It is based on fundamentally different phenomena than a conventional computer....
An international team of physicists has monitored the scattering behaviour of electrons in a non-conducting material in real-time. Their insights could be beneficial for radiotherapy.
We can refer to electrons in non-conducting materials as ‘sluggish’. Typically, they remain fixed in a location, deep inside an atomic composite. It is hence...
Two-dimensional magnetic structures are regarded as a promising material for new types of data storage, since the magnetic properties of individual molecular building blocks can be investigated and modified. For the first time, researchers have now produced a wafer-thin ferrimagnet, in which molecules with different magnetic centers arrange themselves on a gold surface to form a checkerboard pattern. Scientists at the Swiss Nanoscience Institute at the University of Basel and the Paul Scherrer Institute published their findings in the journal Nature Communications.
Ferrimagnets are composed of two centers which are magnetized at different strengths and point in opposing directions. Two-dimensional, quasi-flat ferrimagnets...
24.05.2017 | Event News
23.05.2017 | Event News
22.05.2017 | Event News
29.05.2017 | Earth Sciences
29.05.2017 | Life Sciences
29.05.2017 | Physics and Astronomy