Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Linking superconductivity and structure

27.05.2015

Superconductivity is a rare physical state in which matter is able to conduct electricity--maintain a flow of electrons--without any resistance. It can only be found in certain materials, and even then it can only be achieved under controlled conditions of low temperatures and high pressures. New research from a team including Carnegie's Elissaios Stavrou, Xiao-Jia Chen, and Alexander Goncharov hones in on the structural changes underlying superconductivity in iron arsenide compounds--those containing iron and arsenic. It is published by Scientific Reports.

Although superconductivity has many practical applications for electronics (including scientific research instruments), medical engineering (MRI and NMR machines), and potential future applications including high-performance power transmission and storage, and very fast train travel, the difficulty of creating superconducting materials prevents it from being used to its full potential. As such, any newly discovered superconducting ability is of great interest to scientists and engineers.


This is the tetragonal crystal structure of NaFe2As2, courtesy of Alexander Goncharov. Sodium (Na) is represented by the black balls, iron (Fe) by the red balls, and arsenic (As) by the yellow balls. Courtesy of Alexander Goncharov.

Credit: Alexander Goncharov


This is the collapsed tetragonal crystal structure of NaFe2As2, with arsenic (As) atoms in a 5-fold coordination, courtesy of Alexander Goncharov. Sodium (Na) is represented by the black balls, iron (Fe) by the red balls, and arsenic (As) by the yellow balls. Courtesy of Alexander Goncharov.

Credit: Alexander Goncharov

Iron arsenides are relatively recently discovered superconductors. The nature of superconductivity in these particular materials remains a challenge for modern solid state physics. If the complex links between superconductivity, structure, and magnetism in these materials are unlocked, then iron arsenides could potentially be used to reveal superconductivity at much higher temperatures than previously seen, which would vastly increase the ease of practical applications for superconductivity.

When iron arsenide is combined with a metal--such as in the sodium-containing NaFe2As2 compound studied here--it was known that the ensuing compound is crystallized in a tetrahedral structure. But until now, a detailed structure of the atomic positions involved and how they change under pressure had not been determined.

The layering of arsenic and iron (As-Fe-As) in this structure is believed to be key to the compound's superconductivity. However, under pressure, this structure is thought to be partially misshapen into a so-called collapsed tetragonal lattice, which is no longer capable of superconducting, or has diminished superconducting ability.

The team used experimental evidence and modeling under pressure to actually demonstrate these previously theorized structural changes--tetragonal to collapsed tetragonal--on the atomic level. This is just the first step toward definitively determining the link between structure and superconductivity, which could potentially make higher-temperature superconductivity a real possibility.

They showed that at about 40,000 times normal atmospheric pressure (4 gigapascals), NaFe2As2 takes on the collapsed tetragonal structure. This changes the angles in the arsenic-iron-arsenic layers and is coincident with the loss in superconductivity. Moreover, they found that this transition is accompanied by a major change in bonding coordination in the formation of the interlayer arsenic-arsenic bonds. A direct consequence of this new coordination is that the system loses its two-dimensionality, and with it, superconductivity.

"Our findings are an important step in identifying the hypothesized connection between structure and superconductivity in iron-containing compounds," Goncharov said. "Understanding the loss of superconductivity on an atomic level could enhance our ease of manufacturing such compounds for practical applications, as well as improving our understanding of condensed matter physics."

###

The paper's other co-authors are: Artem Oganov of Stony Brook University, the Moscow Institute of Physics and Technology, and Northwestern Polytechnical University Xi'an; and Ai-Feng Wang, Ya-Jun Yan, Xi-Gang Luo, and Xian-Hui Chen of the University of Science and Technology of China, Hefei, Anhui;

This work was supported by DARPA, the Carnegie Institution of Canada, EFree (the DOE EFRC center at the Carnegie Institution for Science), the government of the Russian Federation, the Ministry of Education and Science of the Russian Federation.

GSECARS is supported by the U.S. NSF and DOE Geosciences. Use of the APS was supported by the DOE-BES. Calculations were performed on XSEDE facilities and on the cluster of the Center for Functional Nanomaterials, BNL, which is supported by the DOE-BES. Sample growth was supported by the Natural Science Foundation of China, the ''Strategic Priority Research Program (B)'' of the Chinese Academy of Sciences, and the National Basic Research Program of China.

The Carnegie Institution for Science is a private, nonprofit organization headquartered in Washington, D.C., with six research departments throughout the U.S. Since its founding in 1902, the Carnegie Institution has been a pioneering force in basic scientific research. Carnegie scientists are leaders in plant biology, developmental biology, astronomy, materials science, global ecology, and Earth and planetary science.

Media Contact

Alexander Goncharov
agoncharov@carnegiescience.edu
202-478-8947

 @carnegiescience

http://www.ciw.edu 

Alexander Goncharov | EurekAlert!

More articles from Physics and Astronomy:

nachricht Significantly more productivity in USP lasers
06.12.2016 | Fraunhofer-Institut für Lasertechnik ILT

nachricht Shape matters when light meets atom
05.12.2016 | Centre for Quantum Technologies at the National University of Singapore

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Significantly more productivity in USP lasers

In recent years, lasers with ultrashort pulses (USP) down to the femtosecond range have become established on an industrial scale. They could advance some applications with the much-lauded “cold ablation” – if that meant they would then achieve more throughput. A new generation of process engineering that will address this issue in particular will be discussed at the “4th UKP Workshop – Ultrafast Laser Technology” in April 2017.

Even back in the 1990s, scientists were comparing materials processing with nanosecond, picosecond and femtosesecond pulses. The result was surprising:...

Im Focus: Shape matters when light meets atom

Mapping the interaction of a single atom with a single photon may inform design of quantum devices

Have you ever wondered how you see the world? Vision is about photons of light, which are packets of energy, interacting with the atoms or molecules in what...

Im Focus: Novel silicon etching technique crafts 3-D gradient refractive index micro-optics

A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.

Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...

Im Focus: Quantum Particles Form Droplets

In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.

“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...

Im Focus: MADMAX: Max Planck Institute for Physics takes up axion research

The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.

The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

ICTM Conference 2017: Production technology for turbomachine manufacturing of the future

16.11.2016 | Event News

Innovation Day Laser Technology – Laser Additive Manufacturing

01.11.2016 | Event News

#IC2S2: When Social Science meets Computer Science - GESIS will host the IC2S2 conference 2017

14.10.2016 | Event News

 
Latest News

NTU scientists build new ultrasound device using 3-D printing technology

07.12.2016 | Health and Medicine

The balancing act: An enzyme that links endocytosis to membrane recycling

07.12.2016 | Life Sciences

How to turn white fat brown

07.12.2016 | Health and Medicine

VideoLinks
B2B-VideoLinks
More VideoLinks >>>