Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Linking superconductivity and structure

27.05.2015

Superconductivity is a rare physical state in which matter is able to conduct electricity--maintain a flow of electrons--without any resistance. It can only be found in certain materials, and even then it can only be achieved under controlled conditions of low temperatures and high pressures. New research from a team including Carnegie's Elissaios Stavrou, Xiao-Jia Chen, and Alexander Goncharov hones in on the structural changes underlying superconductivity in iron arsenide compounds--those containing iron and arsenic. It is published by Scientific Reports.

Although superconductivity has many practical applications for electronics (including scientific research instruments), medical engineering (MRI and NMR machines), and potential future applications including high-performance power transmission and storage, and very fast train travel, the difficulty of creating superconducting materials prevents it from being used to its full potential. As such, any newly discovered superconducting ability is of great interest to scientists and engineers.


This is the tetragonal crystal structure of NaFe2As2, courtesy of Alexander Goncharov. Sodium (Na) is represented by the black balls, iron (Fe) by the red balls, and arsenic (As) by the yellow balls. Courtesy of Alexander Goncharov.

Credit: Alexander Goncharov


This is the collapsed tetragonal crystal structure of NaFe2As2, with arsenic (As) atoms in a 5-fold coordination, courtesy of Alexander Goncharov. Sodium (Na) is represented by the black balls, iron (Fe) by the red balls, and arsenic (As) by the yellow balls. Courtesy of Alexander Goncharov.

Credit: Alexander Goncharov

Iron arsenides are relatively recently discovered superconductors. The nature of superconductivity in these particular materials remains a challenge for modern solid state physics. If the complex links between superconductivity, structure, and magnetism in these materials are unlocked, then iron arsenides could potentially be used to reveal superconductivity at much higher temperatures than previously seen, which would vastly increase the ease of practical applications for superconductivity.

When iron arsenide is combined with a metal--such as in the sodium-containing NaFe2As2 compound studied here--it was known that the ensuing compound is crystallized in a tetrahedral structure. But until now, a detailed structure of the atomic positions involved and how they change under pressure had not been determined.

The layering of arsenic and iron (As-Fe-As) in this structure is believed to be key to the compound's superconductivity. However, under pressure, this structure is thought to be partially misshapen into a so-called collapsed tetragonal lattice, which is no longer capable of superconducting, or has diminished superconducting ability.

The team used experimental evidence and modeling under pressure to actually demonstrate these previously theorized structural changes--tetragonal to collapsed tetragonal--on the atomic level. This is just the first step toward definitively determining the link between structure and superconductivity, which could potentially make higher-temperature superconductivity a real possibility.

They showed that at about 40,000 times normal atmospheric pressure (4 gigapascals), NaFe2As2 takes on the collapsed tetragonal structure. This changes the angles in the arsenic-iron-arsenic layers and is coincident with the loss in superconductivity. Moreover, they found that this transition is accompanied by a major change in bonding coordination in the formation of the interlayer arsenic-arsenic bonds. A direct consequence of this new coordination is that the system loses its two-dimensionality, and with it, superconductivity.

"Our findings are an important step in identifying the hypothesized connection between structure and superconductivity in iron-containing compounds," Goncharov said. "Understanding the loss of superconductivity on an atomic level could enhance our ease of manufacturing such compounds for practical applications, as well as improving our understanding of condensed matter physics."

###

The paper's other co-authors are: Artem Oganov of Stony Brook University, the Moscow Institute of Physics and Technology, and Northwestern Polytechnical University Xi'an; and Ai-Feng Wang, Ya-Jun Yan, Xi-Gang Luo, and Xian-Hui Chen of the University of Science and Technology of China, Hefei, Anhui;

This work was supported by DARPA, the Carnegie Institution of Canada, EFree (the DOE EFRC center at the Carnegie Institution for Science), the government of the Russian Federation, the Ministry of Education and Science of the Russian Federation.

GSECARS is supported by the U.S. NSF and DOE Geosciences. Use of the APS was supported by the DOE-BES. Calculations were performed on XSEDE facilities and on the cluster of the Center for Functional Nanomaterials, BNL, which is supported by the DOE-BES. Sample growth was supported by the Natural Science Foundation of China, the ''Strategic Priority Research Program (B)'' of the Chinese Academy of Sciences, and the National Basic Research Program of China.

The Carnegie Institution for Science is a private, nonprofit organization headquartered in Washington, D.C., with six research departments throughout the U.S. Since its founding in 1902, the Carnegie Institution has been a pioneering force in basic scientific research. Carnegie scientists are leaders in plant biology, developmental biology, astronomy, materials science, global ecology, and Earth and planetary science.

Media Contact

Alexander Goncharov
agoncharov@carnegiescience.edu
202-478-8947

 @carnegiescience

http://www.ciw.edu 

Alexander Goncharov | EurekAlert!

More articles from Physics and Astronomy:

nachricht Tiny lasers from a gallery of whispers
20.09.2017 | American Institute of Physics

nachricht New quantum phenomena in graphene superlattices
19.09.2017 | Graphene Flagship

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Tiny lasers from a gallery of whispers

New technique promises tunable laser devices

Whispering gallery mode (WGM) resonators are used to make tiny micro-lasers, sensors, switches, routers and other devices. These tiny structures rely on a...

Im Focus: Ultrafast snapshots of relaxing electrons in solids

Using ultrafast flashes of laser and x-ray radiation, scientists at the Max Planck Institute of Quantum Optics (Garching, Germany) took snapshots of the briefest electron motion inside a solid material to date. The electron motion lasted only 750 billionths of the billionth of a second before it fainted, setting a new record of human capability to capture ultrafast processes inside solids!

When x-rays shine onto solid materials or large molecules, an electron is pushed away from its original place near the nucleus of the atom, leaving a hole...

Im Focus: Quantum Sensors Decipher Magnetic Ordering in a New Semiconducting Material

For the first time, physicists have successfully imaged spiral magnetic ordering in a multiferroic material. These materials are considered highly promising candidates for future data storage media. The researchers were able to prove their findings using unique quantum sensors that were developed at Basel University and that can analyze electromagnetic fields on the nanometer scale. The results – obtained by scientists from the University of Basel’s Department of Physics, the Swiss Nanoscience Institute, the University of Montpellier and several laboratories from University Paris-Saclay – were recently published in the journal Nature.

Multiferroics are materials that simultaneously react to electric and magnetic fields. These two properties are rarely found together, and their combined...

Im Focus: Fast, convenient & standardized: New lab innovation for automated tissue engineering & drug

MBM ScienceBridge GmbH successfully negotiated a license agreement between University Medical Center Göttingen (UMG) and the biotech company Tissue Systems Holding GmbH about commercial use of a multi-well tissue plate for automated and reliable tissue engineering & drug testing.

MBM ScienceBridge GmbH successfully negotiated a license agreement between University Medical Center Göttingen (UMG) and the biotech company Tissue Systems...

Im Focus: Silencing bacteria

HZI researchers pave the way for new agents that render hospital pathogens mute

Pathogenic bacteria are becoming resistant to common antibiotics to an ever increasing degree. One of the most difficult germs is Pseudomonas aeruginosa, a...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

“Lasers in Composites Symposium” in Aachen – from Science to Application

19.09.2017 | Event News

I-ESA 2018 – Call for Papers

12.09.2017 | Event News

EMBO at Basel Life, a new conference on current and emerging life science research

06.09.2017 | Event News

 
Latest News

Molecular Force Sensors

20.09.2017 | Life Sciences

Producing electricity during flight

20.09.2017 | Power and Electrical Engineering

Tiny lasers from a gallery of whispers

20.09.2017 | Physics and Astronomy

VideoLinks
B2B-VideoLinks
More VideoLinks >>>