Electromagnetic waves created on a layer of organic molecules could provide the perfect on-chip light source for future quantum communication systems.
A team of scientists including A*STAR researchers has captured tiny flashes of light from an ultrathin layer of organic molecules sandwiched between two electrodes that could replace lasers and LEDs as signal sources for future miniature, ultrafast quantum computing and light-based communication systems1.
Electron tunneling (pink) through a single organic molecule gives rise to plasmons (blue ripples) at the interface between the organic layer and the electrode below.
© 2016 Tao Wang, NUS.
To investigate electromagnetic waves called plasmons, which skim along the interface between two materials, Nikodem Tomczak from the A*STAR Institute of Materials Research and Engineering and colleagues collaborated with Christian A. Nijhuis from the National University of Singapore to construct a junction consisting of a layer of thiol molecules on a metal electrode and liquid gallium-indium alloy as a top electrode.
The team created plasmons by applying a voltage across the thiol layer. Although thiol is an insulator, the layer was thin enough for electrons to quantum tunnel between the electrodes, exciting plasmons on the thiol layer’s surface in the process. The plasmons then decayed into photons, tiny pulses of light that Tomczak and his colleagues were able to detect.
“We were surprised that the light did not come from the whole junction, but instead just from very small spots that blink at different frequencies,” said Tomczak.
The team found that the light generated by the plasmons was polarized, and that both the polarization and the wavelength of the light varied with the voltage applied across the junction and the molecules used to form the organic layer.
“The spots are diffraction-limited, polarized and their blinking follows power-law statistics,” said Tomczak. “We need further experiments to confirm, but it is very similar to emission from other single photon sources, such as quantum dots or nanodiamonds.”
Further evidence that the light is from plasmons decaying into a single photon came from Chu Hong Son and his team at the A*STAR Institute of High Performance Computing who modeled the spots as the product of the smallest possible source, a single dipole emitter, and achieved results consistent with the experimental observations.
Tomczak believes the layers can be scaled down to junctions built from a single molecule, opening up the potential to integrate plasmonic light sources on to silicon-based circuits, replacing large external light sources such as a laser.
The team also explored one-molecule thick layers of carbon chains terminated with a metallic ferrocene group developed by the group of Christian A. Nijhuis. Because this compound is asymmetric, it allows tunneling in one direction, effectively acting as a diode.
“By keeping the same architecture and tuning the chemistry of the monolayer you can create a range of different devices,” said Tomczak.
A*STAR Research | Research SEA
A better way to weigh millions of solitary stars
15.12.2017 | Vanderbilt University
A chip for environmental and health monitoring
15.12.2017 | Friedrich-Alexander-Universität Erlangen-Nürnberg
DNA molecules that follow specific instructions could offer more precise molecular control of synthetic chemical systems, a discovery that opens the door for engineers to create molecular machines with new and complex behaviors.
Researchers have created chemical amplifiers and a chemical oscillator using a systematic method that has the potential to embed sophisticated circuit...
MPQ scientists achieve long storage times for photonic quantum bits which break the lower bound for direct teleportation in a global quantum network.
Concerning the development of quantum memories for the realization of global quantum networks, scientists of the Quantum Dynamics Division led by Professor...
Researchers have developed a water cloaking concept based on electromagnetic forces that could eliminate an object's wake, greatly reducing its drag while...
Tiny pores at a cell's entryway act as miniature bouncers, letting in some electrically charged atoms--ions--but blocking others. Operating as exquisitely sensitive filters, these "ion channels" play a critical role in biological functions such as muscle contraction and the firing of brain cells.
To rapidly transport the right ions through the cell membrane, the tiny channels rely on a complex interplay between the ions and surrounding molecules,...
The miniaturization of the current technology of storage media is hindered by fundamental limits of quantum mechanics. A new approach consists in using so-called spin-crossover molecules as the smallest possible storage unit. Similar to normal hard drives, these special molecules can save information via their magnetic state. A research team from Kiel University has now managed to successfully place a new class of spin-crossover molecules onto a surface and to improve the molecule’s storage capacity. The storage density of conventional hard drives could therefore theoretically be increased by more than one hundred fold. The study has been published in the scientific journal Nano Letters.
Over the past few years, the building blocks of storage media have gotten ever smaller. But further miniaturization of the current technology is hindered by...
11.12.2017 | Event News
08.12.2017 | Event News
07.12.2017 | Event News
15.12.2017 | Power and Electrical Engineering
15.12.2017 | Materials Sciences
15.12.2017 | Life Sciences