Conventional electronic devices use the flow of electrons to process and transmit information throughout the conducting and semiconducting circuits of a computer chip, which requires external power.
Scientists are striving to decrease this demand by electrically controlling a property of the electron called spin, which is the source of magnetization. Making so-called ‘spintronic chips’ from multiferroics, a new class of materials with strongly coupled ferroelectric and ferromagnetic properties, could enable electrical control of magnetization.
Yusuke Tokunaga from the RIKEN Advanced Science Institute, Wako and his colleagues have now discovered that the well-known ferromagnet gadolinium iron oxide (GdFeO3) is also ferroelectric and that its ferromagnetic and ferroelectric properties are strongly coupled.1. This means that new multifunctional devices based on this material are now a possibility, and could operate with much less power than their conventional counterparts.
A tale of two properties
Ferromagnetism and ferroelectricity, which rarely occur in the same material, arise from different physical processes.
Ferromagnetism occurs in materials, such as iron, below a certain temperature (the Curie temperature), and the magnetic moments of regions of atoms, called ferromagnetic domains, align to point in the same direction when placed in a strong magnetic field (Fig. 2). This alignment remains once the field is removed. Most common magnetic materials are ferromagnetic, including those used to store information electronically.
Ferroelectricity, on the other hand, occurs in materials in which oppositely charged atoms form regions of locally aligned dipoles, and the net polarity can be aligned by a strong electric field (Fig. 3). As with ferromagnetism, this polarization remains once the field is removed.
If the ferromagnetic and ferroelectric properties of a multiferroic material are linked, or coupled, they can be manipulated simultaneously, which would allow the development of multifunctional components. Indeed, the discovery by Tokunaga and co-workers of the multiferroic properties of GdFeO3 began with a series of materials that barely exhibited either property.
“We are always searching for new multiferroics,” says Tokunaga. “We started our search with the perovskite ortho-aluminate, DyAlO3. This material is known to be magnetoelectric, but in the absence of any applied field is neither ferromagnetic nor ferroelectric.”
Powerful combination for low-power electronics
Magnetoelectric materials, such as DyAlO3, are crystals in which charge polarization can be induced with a magnetic field as well as an electric field. In previous work, Tokunaga and co-workers tried substituting the aluminum (Al) atoms in this material with iron (Fe) atoms.2. They found that it did become weakly ferromagnetic and ferroelectric, but only while it was held in a magnetic field—when the field was removed both characteristics disappeared.
“As a next step, we searched for a material with the same magnetic structure as DyFeO3 in an applied field,” explains Tokunaga. Since the researchers knew that the arrangement and orientation of the magnetic moments of GdAlO3 are the same as those of DyAlO3, they suspected that GdFeO3 might be able to support a similar magnetic structure to that of the magnetic field-induced multiferroic state of DyFeO3, but without the need for a magnetic field.
When the researchers grew large crystals of GdFeO3 and measured their properties, they found that this material was indeed both ferroelectric and ferromagnetic without any applied field. Moreover, they discovered that its ferroelectric and ferromagnetic properties were intrinsically linked and its polarization could be altered with a magnetic field. But more significantly, they revealed that its magnetization could be changed with an electric field—a property that is particularly useful for making low-power electronics.
“Current-induced magnetization reversal is intensively studied as a means of making devices that use the spin of electrons, as well as their charge, for processing information,” notes Tokunaga. However, the metallic and semiconducting materials used in these devices require the flow of current, which dissipates energy. “The great advantage of multiferroic insulators, such as GdFeO3, is that their magnetization can be changed by an electric field with almost zero current and very little energy loss,” he says.
Composite domain walls
Interactions between the so-called domain walls, or boundaries between regions of different magnetization and polarization in a material, cause the coupling the ferromagnetic and ferroelectric properties of GdFeO3, according to the researchers.
When a strong magnetic field is applied to a ferromagnetic material, the changes in alignment of its magnetic moments occur gradually through the growth of smaller aligned regions, or domains. As they grow, the domain walls push through the material and, eventually, all the moments of the material align in the direction of the magnetic field. A similar process occurs to the electric dipoles of a ferroelectric when its polarization is switched in response to an electric field.
In a multiferroic material, ferromagnetic and ferroelectric domain walls can exist at different points of the material. A collision between these walls in GdFeO3 can result in the formation of a composite multiferroic domain wall that switches both the magnetization and the polarization of the material as it moves. Moreover, when a composite wall hits a defect in the material, it can decouple to form separate ferromagnetic and ferroelectric walls once more. The merging, propagation and separation of the walls allows the material’s magnetization to be switched with an electric field, and allows its polarization to be switched with a magnetic field.
The multiferroic behavior of GdFeO3 occurs only at temperatures below 2.5 K (-270.65 °C), so the researchers plan to search for materials that behave similarly at much higher temperatures. If successful, their endeavor will bring novel practical electronic devices a step closer to realization.
1. Tokunaga, Y., Furukawa, N., Sakai, H., Taguchi, Y., Arima, T. & Tokura, Y. Composite domain walls in a multiferroic perovskite ferrite. Nature Materials 8, 558–562 (2009).
2. Tokunaga, Y., Iguchi, S., Arima, T. & Tokura, Y. Magnetic-field-induced ferroelectric state in DyFeO3. Physical Review Letters 101, 087205 (2008).
The corresponding author for this highlight is based at the RIKEN Cross-Correlated Materials Research Group, Exploratory Materials Team
About the Author
Yusuke Tokunaga was born in Tokyo, Japan, in 1977. He graduated from Department of Applied Physics, the University of Tokyo, in 2000, and obtained his PhD in 2005 from the same university. Since then, he has been working as a postdoctoral researcher. After spending two years at ERATO Tokura Spin Superstructure Project, JST, he moved to ERATO Tokura Multiferroics Project, JST. His working place was changed from AIST, Tsukuba, Japan to RIKEN in 2008. He is now working as a visiting researcher at the RIKEN Advanced Science Institute. His current area of interest is in strongly correlated electron systems including multiferroics.
Tokunaga, Y., Furukawa, N., Sakai, H., Taguchi, Y., Arima, T. & Tokura, Y. Composite domain walls in a multiferroic perovskite ferrite. Nature Materials 8, 558–562 (2009), . Tokunaga, Y., Iguchi, S., Arima, T. & Tokura, Y. Magnetic-field-induced ferroelectric state in DyFeO3. Physical Review Letters 101, 087205 (2008).
Saeko Okada | Research asia research news
Further reports about: > DyAlO3 > DyFeO3 > ERATO > Ferromagnetism > GdFeO3 > Magnetic-field-induced > Multiferroics > Nature Immunology > RIKEN > Synthetic Composite > electric field > electronic devices > ferroelectricity > magnetic field > magnetic material > magnetic moment > multifunctional devices > semiconducting circuits > spintronic chips
Large-scale battery storage system in field trial
11.12.2017 | FIZ Karlsruhe – Leibniz-Institut für Informationsinfrastruktur GmbH
New test procedure for developing quick-charging lithium-ion batteries
07.12.2017 | Forschungszentrum Jülich
Tiny pores at a cell's entryway act as miniature bouncers, letting in some electrically charged atoms--ions--but blocking others. Operating as exquisitely sensitive filters, these "ion channels" play a critical role in biological functions such as muscle contraction and the firing of brain cells.
To rapidly transport the right ions through the cell membrane, the tiny channels rely on a complex interplay between the ions and surrounding molecules,...
The miniaturization of the current technology of storage media is hindered by fundamental limits of quantum mechanics. A new approach consists in using so-called spin-crossover molecules as the smallest possible storage unit. Similar to normal hard drives, these special molecules can save information via their magnetic state. A research team from Kiel University has now managed to successfully place a new class of spin-crossover molecules onto a surface and to improve the molecule’s storage capacity. The storage density of conventional hard drives could therefore theoretically be increased by more than one hundred fold. The study has been published in the scientific journal Nano Letters.
Over the past few years, the building blocks of storage media have gotten ever smaller. But further miniaturization of the current technology is hindered by...
With innovative experiments, researchers at the Helmholtz-Zentrums Geesthacht and the Technical University Hamburg unravel why tiny metallic structures are extremely strong
Light-weight and simultaneously strong – porous metallic nanomaterials promise interesting applications as, for instance, for future aeroplanes with enhanced...
An interdisciplinary group of researchers interfaced individual bacteria with a computer to build a hybrid bio-digital circuit - Study published in Nature Communications
Scientists at the Institute of Science and Technology Austria (IST Austria) have managed to control the behavior of individual bacteria by connecting them to a...
Physicists in the Laboratory for Attosecond Physics (run jointly by LMU Munich and the Max Planck Institute for Quantum Optics) have developed an attosecond electron microscope that allows them to visualize the dispersion of light in time and space, and observe the motions of electrons in atoms.
The most basic of all physical interactions in nature is that between light and matter. This interaction takes place in attosecond times (i.e. billionths of a...
11.12.2017 | Event News
08.12.2017 | Event News
07.12.2017 | Event News
11.12.2017 | Information Technology
11.12.2017 | Power and Electrical Engineering
11.12.2017 | Event News