Controlling nano surface roughness of porous silicon
A research team from Tokyo Institute of Technology (Tokyo Tech) and Waseda University have successfully produced high-quality thin film monocrystalline silicon with a reduced crystal defect density down to the silicon wafer level at a growth rate that is more than 10 times higher than before. In principle, this method can improve the raw material yield to nearly 100%. Therefore, it can be expected that this technology will make it possible to drastically reduce manufacturing costs while maintaining the power generation efficiency of monocrystalline silicon solar cells, which are used in most high efficient solar cells.
Solar power generation is a method of generating power where solar light energy is converted directly into electricity using a device called a "solar cell." Efficiently converting the solar energy that is constantly striking the earth to generate electricity is an effective solution to the problem of global warming related to CO2 emissions. By making the monocrystalline Si solar cells that are at the core of solar power generation systems thinner, it is possible to greatly reduce raw material costs, which account for about 40% of the current module, and by making them flexible and lighter, usage can be expected to expand and installation costs can be expected to decrease.
In addition, as a method of reducing manufacturing cost, thin-film monocrystalline Si solar cells that use porous silicon (Double Porous Silicon Layer: DPSL) via lift-off are attracting attention as having a competitive edge in the future.
Among the technical challenges related to monocrystalline Si solar cells using lift-off are 1) the formation of a high-quality thin film Si at the Si wafer level, 2) achieving a porous structure that can easily be lifted off (peeled off), 3) improving the growth rate and Si raw material yield (necessary equipment costs are determined by the growth rate), and 4) being able to use the substrate after lift-off without any waste.
In order to overcome challenge 1), it was necessary to clarify the main factors that determine the quality of thin film crystals grown on porous silicon, and to develop a technique for controlling these.
Overview of Research Achievement
A joint research team consisting of Professor Manabu Ihara and Assistant Professor Kei Hasegawa of the Tokyo Tech, and Professor Suguru Noda of Waseda University has developed a high-quality thin film monocrystalline silicon with a thickness of about 10 μm and a reduced crystal defect density down to the silicon wafer level at a growth rate that is more than 10 times higher than before. First, double-layer nano-order porous silicon is generated on the surface of a monocrystalline wafer using an electrochemical technique. Next, the surface was smoothed to a roughness of 0.2 to 0.3 nm via a unique zone heating recrystallization method (ZHR method), and this substrate was used for high-speed growth to obtain a moonocrystalline thin film with high crystal quality. The grown film can easily be peeled off using the double-layer porous Si layer, and the substrate can be reused or used as an evaporation source for thin film growth, which greatly reduces material loss. When the surface roughness of the underlying substrate is reduced by changing the ZHR method conditions, the defect density of the thin film crystal that was grown decreased, and the team eventually succeeded in reducing it to the Si wafer level of about 1/10th. This quantitatively shows that a surface roughness in the range of only 0.1-0.2 nm (level of atoms to several tens of layers) has an important impact on the formation of crystal defects, which is also of interest as a crystal growth mechanism.
The film formation rate and the conversion rate of the Si source to the thin film Si are bottlenecks in the production of thin-film monocrystalline Si. With chemical vapor deposition (CVD), which is mainly used for epitaxy, the maximum film forming rate is a few μm/h and the yield is about 10%. At the Noda Laboratory of Waseda University, instead of the regular physical vapor deposition (PVD) where raw Si is vaporized at around its melting point of 1414 ?C, by vaporizing the raw Si at much higher temperature of >2000 ?C, a rapid evaporation method (RVD) was developed with a high Si vapor pressure capable of depositing Si at 10 μm/min.
It was found that the ZHR technology developed this time can resolves technical problems and drastically reduce the manufacturing cost of the lift-off process.
Based on the results of this study, not only did the team discover the main factors for improving the quality of crystals during rapid growth on porous silicon used for the lift-off process, they succeeded in controlling these. In the future, measurement of the carrier lifetime of the thin film, which is directly connected to the performances of solar cells, and fabrication of solar cells will be carried out with the goal of putting the technology into practical use. The use of this Si thin films as low cost bottom cells in tandem type solar cells with an efficiency of over 30% will also be considered.
The results are published in the Royal Society of Chemistry (RSC) journal CrystEngComm and will be featured on the inside front cover of the issue.
About Tokyo Institute of Technology
Tokyo Institute of Technology stands at the forefront of research and higher education as the leading university for science and technology in Japan. Tokyo Tech researchers excel in a variety of fields, such as material science, biology, computer science and physics. Founded in 1881, Tokyo Tech has grown to host 10,000 undergraduate and graduate students who become principled leaders of their fields and some of the most sought-after scientists and engineers at top companies. Embodying the Japanese philosophy of "monotsukuri," meaning technical ingenuity and innovation, the Tokyo Tech community strives to make significant contributions to society through high-impact research. http://www.
About Waseda University
Waseda University is a leading private, non-profit institution of higher education based in central Tokyo, with over 50,000 students in 13 undergraduate and 20 graduate schools. Founded in 1882, Waseda cherishes three guiding principles: academic independence, practical innovation and the education of enlightened citizens. Established to mold future leaders, Waseda continues to fulfill this mission, counting among its alumni seven prime ministers and countless other politicians, business leaders, journalists, diplomats, scholars, scientists, actors, writers, athletes and artists. The University is also number one in Japan in international activities, including the number of international students, with the broadest range of degree programs fully taught in English.
Emiko Kawaguchi | EurekAlert!
Improved stability of plastic light-emitting diodes
19.04.2018 | Max-Planck-Institut für Polymerforschung
Intelligent components for the power grid of the future
18.04.2018 | Christian-Albrechts-Universität zu Kiel
University of Connecticut researchers have created a biodegradable composite made of silk fibers that can be used to repair broken load-bearing bones without the complications sometimes presented by other materials.
Repairing major load-bearing bones such as those in the leg can be a long and uncomfortable process.
Study published in the journal ACS Applied Materials & Interfaces is the outcome of an international effort that included teams from Dresden and Berlin in Germany, and the US.
Scientists at the Helmholtz-Zentrum Dresden-Rossendorf (HZDR) together with colleagues from the Helmholtz-Zentrum Berlin (HZB) and the University of Virginia...
Novel highly efficient and brilliant gamma-ray source: Based on model calculations, physicists of the Max PIanck Institute for Nuclear Physics in Heidelberg propose a novel method for an efficient high-brilliance gamma-ray source. A giant collimated gamma-ray pulse is generated from the interaction of a dense ultra-relativistic electron beam with a thin solid conductor. Energetic gamma-rays are copiously produced as the electron beam splits into filaments while propagating across the conductor. The resulting gamma-ray energy and flux enable novel experiments in nuclear and fundamental physics.
The typical wavelength of light interacting with an object of the microcosm scales with the size of this object. For atoms, this ranges from visible light to...
Stable joint cartilage can be produced from adult stem cells originating from bone marrow. This is made possible by inducing specific molecular processes occurring during embryonic cartilage formation, as researchers from the University and University Hospital of Basel report in the scientific journal PNAS.
Certain mesenchymal stem/stromal cells from the bone marrow of adults are considered extremely promising for skeletal tissue regeneration. These adult stem...
In the fight against cancer, scientists are developing new drugs to hit tumor cells at so far unused weak points. Such a “sore spot” is the protein complex...
13.04.2018 | Event News
12.04.2018 | Event News
09.04.2018 | Event News
20.04.2018 | Physics and Astronomy
20.04.2018 | Interdisciplinary Research
20.04.2018 | Physics and Astronomy