Water molecules can be split using solar energy to create hydrogen fuel. This is an important means for chemically storing the fluctuating incoming solar energy and replacing fossil fuels. Now an international team has succeeded in considerably increasing the efficiency for direct solar water splitting.
They are using a tandem solar cell whose surfaces have been selectively modified. The new record value is 14 % and thus considerably above the previous record of 12.4 % held by the National Renewable Energy Laboratory (NREL) in the USA, broken now for the first time in 17 years.
Researchers from TU Ilmenau, the Institute for Solar Fuels at the Helmholtz-Zentrum Berlin, the Fraunhofer Institute for Solar Energy Systems ISE in Freiburg, and the California Institute of Technology (Caltech) participated in the collaboration. The results have been published in Nature Communications (doi:10.1038/ncomms9286).
Solar energy is certainly abundantly available globally, but unfortunately not constantly and not everywhere. One especially interesting solution for storing this energy is artificial photosynthesis. This is what every leaf can do, namely converting sunlight to “chemical energy”.
That can take place with artificial systems based on semiconductors as well. These use the electrical power that sunlight creates in individual semiconductor components to split water into oxygen and hydrogen. Hydrogen possesses very high energy density, can be employed in many ways and could replace fossil fuels. In addition, no carbon dioxide harmful to the climate is released from hydrogen during combustion, instead only water.
Until now, manufacturing of solar hydrogen at the industrial level has failed due to the costs, however. This is because the efficiency of artificial photosynthesis, i.e. the energy content of the hydrogen compared to that of sunlight, has simply been too low to produce hydrogen from the sun economically. Scientific facilities worldwide have therefore been researching for many years how to break the existing record for artificial photosynthesis of 12.4 %, which has been held for 17 years by the NREL.
Now a team from TU Ilmenau, HZB, the California Institute of Technology as well as the Fraunhofer ISE has considerably exceeded this record value. Lead author Matthias May, active at TU Ilmenau and the HZB Institute for Solar Fuels, processed and surveyed about one hundred samples in his excellent doctoral dissertation to achieve this. The fundamental components are tandem solar cells of what are known as III-V semiconductors. Using a now patented photo-electrochemical process, May could modify certain surfaces of these semiconductor systems in such a way that they functioned better in water splitting.
“We have electronically and chemically passivated in situ the aluminium-indium-phosphide layers in particular and thereby efficiently coupled to the catalyst layer for hydrogen generation. In this way, we were able to control the composition of the surface at sub-nanometre scales”, explains May. There was enormous improvement in long-term stability as well. At the beginning, the samples only survived a few seconds before their power output collapsed. Following about a year of optimising, they remain stable for over 40 hours. Further steps toward a long-term stability goal of 1000 hours are already underway.
“Forecasts indicate that the generation of hydrogen from sunlight using high-efficiency semiconductors could be economically competitive to fossil energy sources at efficiency levels of 15 % or more. This corresponds to a hydrogen price of about four US dollars per kilogramme", says Prof. Thomas Hannappel, from the photovoltaics group at TU Ilmenau, who was academic advisor for the work.
Prof. Hans-Joachim Lewerenz from the Joint Center for Artificial Photosynthesis at the California Institute of Technology, who worked closely with May, said “We are nearly there. If we are successful now in reducing the charge carrier losses at the interfaces somewhat more, we might be able to chemically store more than even 17 % of the incident solar energy in the form of hydrogen using this semiconductor system.”
The scientific article is being published in the renowned science periodical Nature Communications [May, M. M. et al. Efficient direct solar-to-hydrogen conversion by in situ interface transformation of a tandem structure. Nat. Commun. 6:8286. Doi: 10. 1038/ncomms9286 (2015)].
Univ.-Prof. Dr. Thomas Hannappel
Technische Universität Ilmenau
Institute of Physics, Dep. Photovoltaics
Phone: +49 3677 69 2566
Bettina Wegner | Technische Universität Ilmenau
'Super yeast' has the power to improve economics of biofuels
18.10.2016 | University of Wisconsin-Madison
Engineers reveal fabrication process for revolutionary transparent sensors
14.10.2016 | University of Wisconsin-Madison
Researchers from the Institute for Quantum Computing (IQC) at the University of Waterloo led the development of a new extensible wiring technique capable of controlling superconducting quantum bits, representing a significant step towards to the realization of a scalable quantum computer.
"The quantum socket is a wiring method that uses three-dimensional wires based on spring-loaded pins to address individual qubits," said Jeremy Béjanin, a PhD...
In a paper in Scientific Reports, a research team at Worcester Polytechnic Institute describes a novel light-activated phenomenon that could become the basis for applications as diverse as microscopic robotic grippers and more efficient solar cells.
A research team at Worcester Polytechnic Institute (WPI) has developed a revolutionary, light-activated semiconductor nanocomposite material that can be used...
By forcefully embedding two silicon atoms in a diamond matrix, Sandia researchers have demonstrated for the first time on a single chip all the components needed to create a quantum bridge to link quantum computers together.
"People have already built small quantum computers," says Sandia researcher Ryan Camacho. "Maybe the first useful one won't be a single giant quantum computer...
COMPAMED has become the leading international marketplace for suppliers of medical manufacturing. The trade fair, which takes place every November and is co-located to MEDICA in Dusseldorf, has been steadily growing over the past years and shows that medical technology remains a rapidly growing market.
In 2016, the joint pavilion by the IVAM Microtechnology Network, the Product Market “High-tech for Medical Devices”, will be located in Hall 8a again and will...
'Ferroelectric' materials can switch between different states of electrical polarization in response to an external electric field. This flexibility means they show promise for many applications, for example in electronic devices and computer memory. Current ferroelectric materials are highly valued for their thermal and chemical stability and rapid electro-mechanical responses, but creating a material that is scalable down to the tiny sizes needed for technologies like silicon-based semiconductors (Si-based CMOS) has proven challenging.
Now, Hiroshi Funakubo and co-workers at the Tokyo Institute of Technology, in collaboration with researchers across Japan, have conducted experiments to...
14.10.2016 | Event News
14.10.2016 | Event News
12.10.2016 | Event News
21.10.2016 | Health and Medicine
21.10.2016 | Information Technology
21.10.2016 | Materials Sciences