University of Toronto engineers study first single crystal perovskites for new solar cell and LED applications
University of Toronto engineers study first single crystal perovskites for new applications Engineers have shone new light on an emerging family of solar-absorbing materials that could clear the way for cheaper and more efficient solar panels and LEDs.
The materials, called perovskites, are particularly good at absorbing visible light, but had never been thoroughly studied in their purest form: as perfect single crystals.
Using a new technique, researchers grew large, pure perovskite crystals and studied how electrons move through the material as light is converted to electricity.
Led by Professor Ted Sargent of The Edward S. Rogers Sr. Department of Electrical & Computer Engineering at the University of Toronto and Professor Osman Bakr of the King Abdullah University of Science and Technology (KAUST), the team used a combination of laser-based techniques to measure selected properties of the perovskite crystals. By tracking down the rapid motion of electrons in the material, they have been able to determine the diffusion length--how far electrons can travel without getting trapped by imperfections in the material--as well as mobility--how fast the electrons can move through the material. Their work was published this week in the journal Science.
"Our work identifies the bar for the ultimate solar energy-harvesting potential of perovskites," says Riccardo Comin, a post-doctoral fellow with the Sargent Group. "With these materials it's been a race to try to get record efficiencies, and our results indicate that progress is slated to continue without slowing down.."
In recent years, perovskite efficiency has soared to certified efficiencies of just over 20 per cent, beginning to approach the present-day performance of commercial-grade silicon-based solar panels mounted in Spanish deserts and on Californian roofs.
"In their efficiency, perovskites are closely approaching conventional materials that have already been commercialized," says Valerio Adinolfi, a PhD candidate in the Sargent Group and co-first author on the paper. "They have the potential to offer further progress on reducing the cost of solar electricity in light of their convenient manufacturability from a liquid chemical precursor."
The study has obvious implications for green energy, but may also enable innovations in lighting. Think of a solar panel made of perovskite crystals as a fancy slab of glass: light hits the crystal surface and gets absorbed, exciting electrons in the material. Those electrons travel easily through the crystal to electrical contacts on its underside, where they are collected in the form of electric current. Now imagine the sequence in reverse--power the slab with electricity, inject electrons, and release energy as light. A more efficient electricity-to-light conversion means perovskites could open new frontiers for energy-efficient LEDs.
Parallel work in the Sargent Group focuses on improving nano-engineered solar-absorbing particles called colloidal quantum dots. "Perovskites are great visible-light harvesters, and quantum dots are great for infrared," says Professor Sargent. "The materials are highly complementary in solar energy harvesting in view of the sun's broad visible and infrared power spectrum."
"In future, we will explore the opportunities for stacking together complementary absorbent materials," says Dr. Comin. "There are very promising prospects for combining perovskite work and quantum dot work for further boosting the efficiency."
RJ Taylor | EurekAlert!
Did you know that the wrapping of Easter eggs benefits from specialty light sources?
13.04.2017 | Heraeus Noblelight GmbH
To e-, or not to e-, the question for the exotic 'Si-III' phase of silicon
05.04.2017 | Carnegie Institution for Science
More and more automobile companies are focusing on body parts made of carbon fiber reinforced plastics (CFRP). However, manufacturing and repair costs must be further reduced in order to make CFRP more economical in use. Together with the Volkswagen AG and five other partners in the project HolQueSt 3D, the Laser Zentrum Hannover e.V. (LZH) has developed laser processes for the automatic trimming, drilling and repair of three-dimensional components.
Automated manufacturing processes are the basis for ultimately establishing the series production of CFRP components. In the project HolQueSt 3D, the LZH has...
Reflecting the structure of composites found in nature and the ancient world, researchers at the University of Illinois at Urbana-Champaign have synthesized thin carbon nanotube (CNT) textiles that exhibit both high electrical conductivity and a level of toughness that is about fifty times higher than copper films, currently used in electronics.
"The structural robustness of thin metal films has significant importance for the reliable operation of smart skin and flexible electronics including...
The nearby, giant radio galaxy M87 hosts a supermassive black hole (BH) and is well-known for its bright jet dominating the spectrum over ten orders of magnitude in frequency. Due to its proximity, jet prominence, and the large black hole mass, M87 is the best laboratory for investigating the formation, acceleration, and collimation of relativistic jets. A research team led by Silke Britzen from the Max Planck Institute for Radio Astronomy in Bonn, Germany, has found strong indication for turbulent processes connecting the accretion disk and the jet of that galaxy providing insights into the longstanding problem of the origin of astrophysical jets.
Supermassive black holes form some of the most enigmatic phenomena in astrophysics. Their enormous energy output is supposed to be generated by the...
The probability to find a certain number of photons inside a laser pulse usually corresponds to a classical distribution of independent events, the so-called...
Microprocessors based on atomically thin materials hold the promise of the evolution of traditional processors as well as new applications in the field of flexible electronics. Now, a TU Wien research team led by Thomas Müller has made a breakthrough in this field as part of an ongoing research project.
Two-dimensional materials, or 2D materials for short, are extremely versatile, although – or often more precisely because – they are made up of just one or a...
20.04.2017 | Event News
18.04.2017 | Event News
03.04.2017 | Event News
26.04.2017 | Materials Sciences
26.04.2017 | Agricultural and Forestry Science
26.04.2017 | Physics and Astronomy