Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:


UCLA chemists devise technology that could transform solar energy storage


The materials in most of today's residential rooftop solar panels can store energy from the sun for only a few microseconds at a time. A new technology developed by chemists at UCLA is capable of storing solar energy for up to several weeks -- an advance that could change the way scientists think about designing solar cells.

The findings are published June 19 in the journal Science.

The new design is inspired by the way that plants generate energy through photosynthesis.

Pictured above are polymer donors and fullerene acceptors.

Courtesy of UCLA Chemistry

'Biology does a very good job of creating energy from sunlight,' said Sarah Tolbert, a UCLA professor of chemistry and one of the senior authors of the research. 'Plants do this through photosynthesis with extremely high efficiency.'

'In photosynthesis, plants that are exposed to sunlight use carefully organized nanoscale structures within their cells to rapidly separate charges -- pulling electrons away from the positively charged molecule that is left behind, and keeping positive and negative charges separated,' Tolbert said. 'That separation is the key to making the process so efficient.'

To capture energy from sunlight, conventional rooftop solar cells use silicon, a fairly expensive material. There is currently a big push to make lower-cost solar cells using plastics, rather than silicon, but today's plastic solar cells are relatively inefficient, in large part because the separated positive and negative electric charges often recombine before they can become electrical energy.

'Modern plastic solar cells don't have well-defined structures like plants do because we never knew how to make them before,' Tolbert said. 'But this new system pulls charges apart and keeps them separated for days, or even weeks. Once you make the right structure, you can vastly improve the retention of energy.'

The two components that make the UCLA-developed system work are a polymer donor and a nano-scale fullerene acceptor. The polymer donor absorbs sunlight and passes electrons to the fullerene acceptor; the process generates electrical energy.

The plastic materials, called organic photovoltaics, are typically organized like a plate of cooked pasta -- a disorganized mass of long, skinny polymer 'spaghetti' with random fullerene 'meatballs.' But this arrangement makes it difficult to get current out of the cell because the electrons sometimes hop back to the polymer spaghetti and are lost.

The UCLA technology arranges the elements more neatly -- like small bundles of uncooked spaghetti with precisely placed meatballs. Some fullerene meatballs are designed to sit inside the spaghetti bundles, but others are forced to stay on the outside. The fullerenes inside the structure take electrons from the polymers and toss them to the outside fullerene, which can effectively keep the electrons away from the polymer for weeks.

'When the charges never come back together, the system works far better,' said Benjamin Schwartz, a UCLA professor of chemistry and another senior co-author. 'This is the first time this has been shown using modern synthetic organic photovoltaic materials.'

In the new system, the materials self-assemble just by being placed in close proximity.

'We worked really hard to design something so we don't have to work very hard,' Tolbert said.

The new design is also more environmentally friendly than current technology, because the materials can assemble in water instead of more toxic organic solutions that are widely used today.

'Once you make the materials, you can dump them into water and they assemble into the appropriate structure because of the way the materials are designed,' Schwartz said. 'So there's no additional work.'

The researchers are already working on how to incorporate the technology into actual solar cells.

Yves Rubin, a UCLA professor of chemistry and another senior co-author of the study, led the team that created the uniquely designed molecules. 'We don't have these materials in a real device yet; this is all in solution,' he said. 'When we can put them together and make a closed circuit, then we will really be somewhere.'

For now, though, the UCLA research has proven that inexpensive photovoltaic materials can be organized in a way that greatly improves their ability to retain energy from sunlight.


Tolbert and Schwartz also are members of UCLA's California NanoSystems Institute. The study's other co-lead authors were UCLA graduate students Rachel Huber and Amy Ferreira. UCLA's Electron Imaging Center for NanoMachines imaged the assembled structure in a lab led by Hong Zhou.

The research was supported by the National Science Foundation (grant CHE-1112569) and by the Center for Molecularly Engineered Energy Materials, an Energy Frontier Research Center funded by the U.S. Department of Energy (DE-AC06-76RLO-1830). Ferreira received support from the Clean Green IGERT (grant DGE-0903720).

Stuart Wolpert | EurekAlert!

More articles from Materials Sciences:

nachricht Researchers demonstrate existence of new form of electronic matter
15.03.2018 | University of Illinois at Urbana-Champaign

nachricht Boron can form a purely honeycomb, graphene-like 2-D structure
15.03.2018 | Science China Press

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Locomotion control with photopigments

Researchers from Göttingen University discover additional function of opsins

Animal photoreceptors capture light with photopigments. Researchers from the University of Göttingen have now discovered that these photopigments fulfill an...

Im Focus: Surveying the Arctic: Tracking down carbon particles

Researchers embark on aerial campaign over Northeast Greenland

On 15 March, the AWI research aeroplane Polar 5 will depart for Greenland. Concentrating on the furthest northeast region of the island, an international team...

Im Focus: Unique Insights into the Antarctic Ice Shelf System

Data collected on ocean-ice interactions in the little-researched regions of the far south

The world’s second-largest ice shelf was the destination for a Polarstern expedition that ended in Punta Arenas, Chile on 14th March 2018. Oceanographers from...

Im Focus: ILA 2018: Laser alternative to hexavalent chromium coating

At the 2018 ILA Berlin Air Show from April 25–29, the Fraunhofer Institute for Laser Technology ILT is showcasing extreme high-speed Laser Material Deposition (EHLA): A video documents how for metal components that are highly loaded, EHLA has already proved itself as an alternative to hard chrome plating, which is now allowed only under special conditions.

When the EU restricted the use of hexavalent chromium compounds to special applications requiring authorization, the move prompted a rethink in the surface...

Im Focus: Radar for navigation support from autonomous flying drones

At the ILA Berlin, hall 4, booth 202, Fraunhofer FHR will present two radar sensors for navigation support of drones. The sensors are valuable components in the implementation of autonomous flying drones: they function as obstacle detectors to prevent collisions. Radar sensors also operate reliably in restricted visibility, e.g. in foggy or dusty conditions. Due to their ability to measure distances with high precision, the radar sensors can also be used as altimeters when other sources of information such as barometers or GPS are not available or cannot operate optimally.

Drones play an increasingly important role in the area of logistics and services. Well-known logistic companies place great hope in these compact, aerial...

All Focus news of the innovation-report >>>



Industry & Economy
Event News

Ultrafast Wireless and Chip Design at the DATE Conference in Dresden

16.03.2018 | Event News

International Tinnitus Conference of the Tinnitus Research Initiative in Regensburg

13.03.2018 | Event News

International Virtual Reality Conference “IEEE VR 2018” comes to Reutlingen, Germany

08.03.2018 | Event News

Latest News

Wandering greenhouse gas

16.03.2018 | Earth Sciences

'Frequency combs' ID chemicals within the mid-infrared spectral region

16.03.2018 | Physics and Astronomy

Biologists unravel another mystery of what makes DNA go 'loopy'

16.03.2018 | Life Sciences

Science & Research
Overview of more VideoLinks >>>