A new material that is both highly transparent and electrically conductive could make large screen displays, smart windows and even touch screens and solar cells more affordable and efficient, according to the Penn State materials scientists and engineers who discovered it.
Indium tin oxide, the transparent conductor that is currently used for more than 90 percent of the display market, has been the dominant material for the past 60 years. However, in the last decade, the price of indium has increased dramatically. Displays and touchscreen modules have become a main cost driver in smartphones and tablets, making up close to 40 percent of the cost.
While memory chips and processors get cheaper, displays get more expensive from generation to generation. Manufacturers have searched for a possible ITO replacement, but until now, nothing has matched ITO's combination of optical transparency, electrical conductivity and ease of fabrication.
A team led by Roman Engel-Herbert, assistant professor of materials science and engineering, reports today (Dec 15) online in Nature Materials a new design strategy that approaches the problem from a different angle. The researchers use thin -- 10 nanometer -- films of an unusual class of materials called correlated metals in which the electrons flow like a liquid.
While in most conventional metals, such as copper, gold, aluminum or silver, electrons flow like a gas, in correlated metals, such as strontium vanadate and calcium vanadate, they move like a liquid. According to the researchers, this electron flow produces high optical transparency along with high metal-like conductivity.
"We are trying to make metals transparent by changing the effective mass of their electrons," Engel-Herbert said. "We are doing this by choosing materials in which the electrostatic interaction between negatively charged electrons is very large compared to their kinetic energy. As a result of this strong electron correlation effect, electrons 'feel' each other and behave like a liquid rather than a gas of non-interacting particles. This electron liquid is still highly conductive, but when you shine light on it, it becomes less reflective, thus much more transparent."
To better understand how they achieved this fine balance between transparency and conductivity, Engel-Herbert and his team turned to a materials theory expert, Professor Karin Rabe of Rutgers University.
"We realized that we needed her help to put a number on how 'liquid' this electron liquid in strontium vanadate is," Engel-Herbert said.
Rabe helped the Penn State team put together all the theoretical and mathematical puzzle pieces they needed to build transparent conductors in the form of a correlated metal. Now that they understand the essential mechanism behind their discovery, the Penn State researchers are confident they will find many other correlated metals that behave like strontium vanadate and calcium vanadate.
Lei Zhang, lead author on the Nature Materials paper and a graduate student in Engel-Herbert's group, was the first to recognize what they had discovered.
"I came from Silicon Valley where I worked for two years as an engineer before I joined the group," said Zhang. "I was aware that there were many companies trying hard to optimize those ITO materials and looking for other possible replacements, but they had been studied for many decades and there just wasn't much room for improvement. When we made the electrical measurements on our correlated metals, I knew we had something that looked really good compared to standard ITO."
Currently indium costs around $750 per kilogram, whereas strontium vanadate and calcium vanadate are made from elements with orders of magnitude higher abundance in the earth's crust. Vanadium sells for around $25 a kilogram, less than 5 percent of the cost of indium, while strontium is even cheaper than vanadium.
"Our correlated metals work really well compared to ITO," said Engel-Herbert. "Now, the question is how to implement these new materials into a large-scale manufacturing process. From what we understand right now, there is no reason that strontium vanadate could not replace ITO in the same equipment currently used in industry."
Along with display technologies, Engel-Herbert and his group are excited about combining their new materials with a very promising type of solar cell that uses a class of materials called organic perovskites. Developed only within the last half dozen years, these materials outperform commercial silicon solar cells but require an inexpensive transparent conductor. Strontium vanadate, also a perovskite, has a compatible structure that makes this an interesting possibility for future inexpensive, high-efficiency solar cells.
Engel-Herbert and Zhang have applied for a patent on their technology.
Along with Zhang and Engel-Herbert, Hai-Tian Zhang, Craig Eaton, Yuanxia Zheng and Matthew Brahlek, all students or postdoctoral Fellows in Engel-Herbert's group, worked on this paper, "Correlated metals as transparent conductors." Others from Penn State and the Materials Research Institute on this project were Moses Chan, Evan Pugh professor of physics, and his postdoctoral Fellow, Weiwei Zhao; and Venkatraman Gopalan, professor of materials science and engineering and his student Lu Guo.
With Rabe was her student Yuanjun Zhou from Rutgers University. Anna Barnes, Hamna Haneef and associate professor Nikolas Podraza of Univesity of Toledo also worked on this project.
The Office of Naval Research, the National Science Foundation and the Department of Energy funded this work. Fabrication of the correlated metals was performed at the Materials Research Institute in the laboratory facilities of Penn State's Millennium Science Complex.
A'ndrea Elyse Messer | EurekAlert!
New biomaterial could replace plastic laminates, greatly reduce pollution
21.09.2017 | Penn State
Stopping problem ice -- by cracking it
21.09.2017 | Norwegian University of Science and Technology
Our brains house extremely complex neuronal circuits, whose detailed structures are still largely unknown. This is especially true for the so-called cerebral cortex of mammals, where among other things vision, thoughts or spatial orientation are being computed. Here the rules by which nerve cells are connected to each other are only partly understood. A team of scientists around Moritz Helmstaedter at the Frankfiurt Max Planck Institute for Brain Research and Helene Schmidt (Humboldt University in Berlin) have now discovered a surprisingly precise nerve cell connectivity pattern in the part of the cerebral cortex that is responsible for orienting the individual animal or human in space.
The researchers report online in Nature (Schmidt et al., 2017. Axonal synapse sorting in medial entorhinal cortex, DOI: 10.1038/nature24005) that synapses in...
Whispering gallery mode (WGM) resonators are used to make tiny micro-lasers, sensors, switches, routers and other devices. These tiny structures rely on a...
Using ultrafast flashes of laser and x-ray radiation, scientists at the Max Planck Institute of Quantum Optics (Garching, Germany) took snapshots of the briefest electron motion inside a solid material to date. The electron motion lasted only 750 billionths of the billionth of a second before it fainted, setting a new record of human capability to capture ultrafast processes inside solids!
When x-rays shine onto solid materials or large molecules, an electron is pushed away from its original place near the nucleus of the atom, leaving a hole...
For the first time, physicists have successfully imaged spiral magnetic ordering in a multiferroic material. These materials are considered highly promising candidates for future data storage media. The researchers were able to prove their findings using unique quantum sensors that were developed at Basel University and that can analyze electromagnetic fields on the nanometer scale. The results – obtained by scientists from the University of Basel’s Department of Physics, the Swiss Nanoscience Institute, the University of Montpellier and several laboratories from University Paris-Saclay – were recently published in the journal Nature.
Multiferroics are materials that simultaneously react to electric and magnetic fields. These two properties are rarely found together, and their combined...
MBM ScienceBridge GmbH successfully negotiated a license agreement between University Medical Center Göttingen (UMG) and the biotech company Tissue Systems Holding GmbH about commercial use of a multi-well tissue plate for automated and reliable tissue engineering & drug testing.
MBM ScienceBridge GmbH successfully negotiated a license agreement between University Medical Center Göttingen (UMG) and the biotech company Tissue Systems...
19.09.2017 | Event News
12.09.2017 | Event News
06.09.2017 | Event News
21.09.2017 | Physics and Astronomy
21.09.2017 | Life Sciences
21.09.2017 | Health and Medicine