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Patterning Oxide Nanopillars at the Atomic Scale by Phase Transformation

27.10.2015

A collaborative study by researchers in Japan aimed at precisely controlling phase transformations with high spatial precision, which represents a significant step forward in realizing new functionalities in confined dimensions.

Researchers at Tohoku University's Advanced Institute for Materials Research (AIMR) have carried out a collaborative study aimed at precisely controlling phase transformations with high spatial precision, which represents a significant step forward in realizing new functionalities in confined dimensions.


Atomic zip in SrNbO3.4. (a) HAADF STEM image taken before irradiation. The irradiation area is marked by a red open rectangle. (b) HAADF STEM image taken after the electron irradiation for ~300 s showing changes in atomic structure in the irradiated region. The zigzag-like slab in the rectangle is transformed to a chain-like connected structure, resulting in atomic merging of the two neighboring chain-like slabs. The new phase has adopted the structure of SrNbO3. The phase transformation can be well controlled with atomic precision.

Copyright : Tohoku University

The team, led by Prof. Yuichi Ikuhara, applied the focused electron beam of a scanning transmission electron microscope (STEM) to irradiate SrNbO3.4 crystals, and demonstrated a precise control of a phase transformation from layered SrNbO3.4 to perovskite SrNbO3 at the atomic scale.

Such a precise control of phase transformations opens up new avenues for materials design and processing, as well as advanced nanodevice fabrication. Full results of the study have been published in Nano Letters.

Background
Phase transformations in crystalline materials are of primary fundamental interest and practical significance in a wide range of fields, including materials science, information storage and geological science. To date, it remains highly desirable to precisely tailor the phase transformations in a material due to their potential impact on macroscopic properties and thus many advanced applications.

Despite decades of efforts, precisely controlling phase transformations at the atomic scale still poses a significant challenge due to the intricacies of governing thermodynamic conditions with atomic precision. Recent technical advances in aberration-corrected STEM offer fertile new ground for probing samples by a focused sub-Angström electron beam, opening an avenue for precisely triggering phase transformations.

Breakthrough
This work has demonstrated a successful control of a phase transformation from the layered SrNbO3.4 to the perovskite SrNbO3 with atomic precision by manipulating a focused sub-Angström electron beam to any selectable region.

Such a concept - of a precise control of phase transformations with an atomic spatial precision - should be, in principle, applicable not only to SrNbO3.4/SrNbO3 but also to other materials, finding applications in material processing and nanodevice fabrication.

Key points :
Precisely controlling phase transformation with high spatial precision
Patterning oxide nanopillars at the atomic scale by phase transformation

Publication information
Title: Patterning oxide nanopillars at the atomic scale by phase transformation
Authors: Chunlin Chen, Zhongchang Wang, Frank Lichtenberg, Yuichi Ikuhara and Johannes Georg Bednorz
Journal: Nano Letters, 2015
DOI: 10.1021/acs.nanolett.5b01847

For information about the research:
Prof. Yuichi Ikuhara
Advanced Institute for Materials Research, Tohoku University
Institute of Engineering Innovation, The University of Tokyo
Email: ikuhara sigma.t.u-tokyo.ac.jp
Tel: +81 3 5841-7688

Assist. Prof. Chunlin Chen and Assoc. Prof. Zhongchang Wang
Advanced Institute for Materials Research, Tohoku University
Email: chen.chunlinwpi-aimr.tohoku.ac.jp
Email: zcwangwpi-aimr.tohoku.ac.jp
Tel: +81 22 217-5933

For general enquiries:
Advanced Institute for Materials Research (AIMR), PR & Outreach Office
Tohoku University
Email: outreachwpi-aimr.tohoku.ac.jp
Tel: +81 22 217-6146


Associated links
Original article from Tohoku University

Ngaroma Riley | Research SEA
Further information:
http://www.researchsea.com

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