Although they don't currently have as much conductivity, solid-state electrolytes designed for lithium-ion batteries (LIBs) are emerging as a safer alternative to their more prevalent--sometimes flammable--liquid-electrolyte counterparts.
However, a new study conducted at Oak Ridge National Laboratory's Spallation Neutron Source (SNS), a Department of Energy Office of Science user facility, has revealed promising results that could drastically boost the performance of solid-state electrolytes, and could potentially lead to a safer, even more efficient battery.
In situ neutron diffraction visualizes the synthesis mechanism, involving multi-phase evolutions, of garnet-type fast lithium-ion solid conductors. The neutron diffraction determines the lithium vacancy distribution in the garnet lattice, and reveals the governing mechanism of highly conductive pathways via the selective element doping.
Credit: Oak Ridge National Laboratory
Using neutron diffraction techniques via the VULCAN instrument, SNS beam line 7, lead instrument scientist Ke An and his team recently concluded an in-depth study probing the entire structure evolution of doped garnet-type electrolytes during the synthesis process to unravel the mechanism that boosts the lithium-ionic conductivity. Their findings were recently published in the journals Chemistry of Materials and the Journal of Materials Chemistry A.
"The question we want to answer is how can we correlate the material's structure with its performance," An said. "Finding an answer to this will be very useful to the materials community, particularly in the field of electrochemical devices like batteries."
The problem with liquid electrolytes, says An, is that while they can produce high levels of conductivity--which is good--in some cases, they become flammable under high voltages or high temperatures, causing the battery to "explode"--which is obviously very bad.
In general, solid electrolyte-based LIBs consist of two electrodes, a positive and a negative, and an electrolyte in the middle, forming the battery's core, which facilitates the movement of ions traveling back and forth between the electrodes. In order to achieve a desired level of conductivity in the electrolyte, ions require vacancies in the crystal structure, or tunnels for the ions to "hop" to and from--kind of like connecting the dots.
Lithium lanthanum zirconates, or materials based on Li7La3Zr2O12 with a garnet structure, are favorable for application as electrolytes because they promote fast lithium transport. However, explained An, synthesized garnets often develop unwanted low-conductivity secondary phases, which in some cases can be detrimental to electrolytic performance. Essentially what that means is that useful vacancies for ions to "hop" don't always develop where designers want them to.
During synthesis, myriad chemical reactions take place as the material goes through several different phases, beginning with the mixing of chemicals or materials, then annealing, or heating the structure for desired performance and consistency, followed by a cool down period in which the structure is hardened. Analyzing what's going on during each phase would be next to impossible without the use of special instruments and techniques.
"Getting better performance out of the electrolyte can't be done without first understanding what's going on inside the structure. We need to understand what the mechanisms are that drive the synthesis process," said materials scientist and lead author Yan Chen, a postdoctoral research associate at SNS. "VULCAN enables us to perform in situ experiments, visualizing the structure's evolution in real time without disturbing the garnet synthesis process."
With VULCAN's help they monitored the low-conductivity phases' formation during the thermal process, and found that it could be mitigated by doping the material--adding trace amounts of various elements that have high valences, or an affinity to create bonds, to reduce the effect. Being able to both suppress the formation of those unwanted phases and increase the number of useful vacancies for ion transport proved to be the key to unlocking garnets with high electrolytic performance.
"By tracking the lithium vacancies as functions of temperature and dopants, we found a common rule that the different dopants obey, and how they redistribute the vacancies in the framework of the garnets," Chen said. "Furthermore, a comprehensive analysis of neutron diffraction results revealed how the dopants tune vacancy quantity, control vacancy distribution, and alter the charge carrier pathways in solid electrolytes."
Thanks to the experiments by An and his team, materials researchers now have a proven method for achieving the best results in garnet structures--results that are sure to lead to safer materials with much needed savings of time and money.
"Now when people look at our work they can be guided how to make high ionic conductivity by choosing the right element with the right valence rather than repeatedly doing trial and error experiments on every single additional element--work that takes you a lot of time," said An. "Now we can give you a simple formula to do it, and you should end up with a better material."
Chen's coauthors include Ezhiylmurugan Rangasamy, Chengdu Liang, Clarina R. dela Cruz, and Ke An. Related research of this material was conducted at the POWGEN instrument, SNS beam line 11A, using time of flight neutron diffraction data, and published in Advanced Energy Materials.
This work was sponsored by DOE's Office of Science.
UT-Battelle manages ORNL for the DOE's Office of Science. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit http://science.
Jeremy Rumsey | idw - Informationsdienst Wissenschaft
The stacked colour sensor
16.11.2017 | Empa - Eidgenössische Materialprüfungs- und Forschungsanstalt
Counterfeits and product piracy can be prevented by security features, such as printed 3-D microstructures
16.11.2017 | Karlsruher Institut für Technologie (KIT)
The formation of stars in distant galaxies is still largely unexplored. For the first time, astron-omers at the University of Geneva have now been able to closely observe a star system six billion light-years away. In doing so, they are confirming earlier simulations made by the University of Zurich. One special effect is made possible by the multiple reflections of images that run through the cosmos like a snake.
Today, astronomers have a pretty accurate idea of how stars were formed in the recent cosmic past. But do these laws also apply to older galaxies? For around a...
Just because someone is smart and well-motivated doesn't mean he or she can learn the visual skills needed to excel at tasks like matching fingerprints, interpreting medical X-rays, keeping track of aircraft on radar displays or forensic face matching.
That is the implication of a new study which shows for the first time that there is a broad range of differences in people's visual ability and that these...
Computer Tomography (CT) is a standard procedure in hospitals, but so far, the technology has not been suitable for imaging extremely small objects. In PNAS, a team from the Technical University of Munich (TUM) describes a Nano-CT device that creates three-dimensional x-ray images at resolutions up to 100 nanometers. The first test application: Together with colleagues from the University of Kassel and Helmholtz-Zentrum Geesthacht the researchers analyzed the locomotory system of a velvet worm.
During a CT analysis, the object under investigation is x-rayed and a detector measures the respective amount of radiation absorbed from various angles....
The quantum world is fragile; error correction codes are needed to protect the information stored in a quantum object from the deteriorating effects of noise. Quantum physicists in Innsbruck have developed a protocol to pass quantum information between differently encoded building blocks of a future quantum computer, such as processors and memories. Scientists may use this protocol in the future to build a data bus for quantum computers. The researchers have published their work in the journal Nature Communications.
Future quantum computers will be able to solve problems where conventional computers fail today. We are still far away from any large-scale implementation,...
Pillared graphene would transfer heat better if the theoretical material had a few asymmetric junctions that caused wrinkles, according to Rice University...
15.11.2017 | Event News
15.11.2017 | Event News
30.10.2017 | Event News
17.11.2017 | Physics and Astronomy
17.11.2017 | Health and Medicine
17.11.2017 | Studies and Analyses