Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Nanospace-Controlled Gold Material Created Using Molecular Technology

22.05.2015

Method Developed to Freely Adjust Pore Size in Nanoporous Gold Material

A research group led by Yusuke Yamauchi at National Institute for Materials Science (NIMS) in cooperation with other research organizations in Japan and overseas, successfully developed a nanoporous gold material with a regular, uniform pore arrangement using polymers as a template.


Figure: Electron micrographs of nanoporous gold materials that were fabricated using different sizes of micelles. Pore size increases from left to right.

Copyright : NIMS

A research group led by Yusuke Yamauchi, an Independent Scientist at the International Center for Materials Nanoarchitectonics (MANA), NIMS (Sukekatsu Ushioda, President), in cooperation with other research organizations in Japan and overseas, successfully developed a nanoporous gold material with a regular, uniform pore arrangement using polymers as a template.

This research result had been published in the Nature Communications on 23 March 2015 (Cuiling Li, Ömer Dag, Thang Duy Dao, Tadaaki Nagao, Yasuhiro Sakamoto, Tatsuo Kimura, Osamu Terasaki and Yusuke Yamauchi, Article title: “Electrochemical synthesis of mesoporous Au films toward mesospace-stimulated optical properties”, doi:10.1038/ncomms7608).

Nanoporous materials, having internal pores of several-nanometers in diameter and a large surface-to-volume ratio, have the potential of producing novel chemical reactions, and thus have been vigorously studied in the pursuit of developing new catalyst and absorbent materials.

In particular, it has been proposed to apply nanoporous gold materials to various fields such as electronics, catalysts and medicine, and it has been reported that they were processed into various forms such as gold nanoparticles, gold nanorods and gold nanowires. However, these conventional nanoporous gold materials have rather irregular pore arrangements, and it had been hoped to fabricate nanoporous gold materials whose pore size can be freely manipulated.

In recent years, it has become feasible to synthesize mesoporous metals with a metal framework by using amphipathic molecules (e.g., surfactants) as a template. In this study, we created uniformly sized spherical micelles (molecular assembly) by adjusting the concentration of polymers that possess both hydrophobic and hydrophilic properties (amphipathic block copolymers) in a dilute solution.

Using these polymers as a template, we reduced gold ions while precisely controlling electrolytic deposition, resulting in the successful formation of nanopores, whose sizes corresponded to the sizes of the micelles used, over the surfaces of the gold films.

In the pores of the nanoporous gold materials, we observed a strong electric field and surface enhanced Raman scattering (SERS). It is expected that these distinctive properties will have various applications such as a SERS-activate substrate for molecular sensing and electrode catalyst.

Also, this technology is applicable to various metals and alloys in addition to gold. Furthermore, since pore size can be adjusted to various diameters by changing the molecular size of the block copolymers, it is feasible to design metal nanospace materials that meet specific needs of users in terms of composition and structure.

This research was conducted as a part of the bioelectronics and biophotonics project sponsored by the JST’s program “Infrastructure Development for Promoting International Science and Technology Cooperation.” It had been published in the British scientific journal Nature Communications (DOI: 10.1038/ncomms7608) at 19:00 on March 23, 2015, Japan time (10:00 on the 23rd British time).


Associated links
NIMS article

Mikiko Tanifuji | ResearchSEA
Further information:
http://www.researchsea.com

More articles from Materials Sciences:

nachricht One in 5 materials chemistry papers may be wrong, study suggests
15.12.2017 | Georgia Institute of Technology

nachricht Scientists channel graphene to understand filtration and ion transport into cells
11.12.2017 | National Institute of Standards and Technology (NIST)

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Error-free into the Quantum Computer Age

A study carried out by an international team of researchers and published in the journal Physical Review X shows that ion-trap technologies available today are suitable for building large-scale quantum computers. The scientists introduce trapped-ion quantum error correction protocols that detect and correct processing errors.

In order to reach their full potential, today’s quantum computer prototypes have to meet specific criteria: First, they have to be made bigger, which means...

Im Focus: Search for planets with Carmenes successful

German and Spanish researchers plan, build and use modern spectrograph

Since 2016, German and Spanish researchers, among them scientists from the University of Göttingen, have been hunting for exoplanets with the “Carmenes”...

Im Focus: First-of-its-kind chemical oscillator offers new level of molecular control

DNA molecules that follow specific instructions could offer more precise molecular control of synthetic chemical systems, a discovery that opens the door for engineers to create molecular machines with new and complex behaviors.

Researchers have created chemical amplifiers and a chemical oscillator using a systematic method that has the potential to embed sophisticated circuit...

Im Focus: Long-lived storage of a photonic qubit for worldwide teleportation

MPQ scientists achieve long storage times for photonic quantum bits which break the lower bound for direct teleportation in a global quantum network.

Concerning the development of quantum memories for the realization of global quantum networks, scientists of the Quantum Dynamics Division led by Professor...

Im Focus: Electromagnetic water cloak eliminates drag and wake

Detailed calculations show water cloaks are feasible with today's technology

Researchers have developed a water cloaking concept based on electromagnetic forces that could eliminate an object's wake, greatly reducing its drag while...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

See, understand and experience the work of the future

11.12.2017 | Event News

Innovative strategies to tackle parasitic worms

08.12.2017 | Event News

AKL’18: The opportunities and challenges of digitalization in the laser industry

07.12.2017 | Event News

 
Latest News

Single-photon detector can count to 4

18.12.2017 | Information Technology

Quantum memory with record-breaking capacity based on laser-cooled atoms

18.12.2017 | Physics and Astronomy

How much soil goes down the drain -- New data on soil lost due to water

18.12.2017 | Agricultural and Forestry Science

VideoLinks
B2B-VideoLinks
More VideoLinks >>>