After six years of painstaking effort, a group of University of Wisconsin-Madison materials scientists believe the tiny sheets of the semiconductor zinc oxide they're growing could have huge implications for the future of a host of electronic and biomedical devices.
The group -- led by Xudong Wang, a UW-Madison professor of materials science and engineering, and postdoctoral researcher Fei Wang -- has developed a technique for creating nearly two-dimensional sheets of compounds that do not naturally form such thin materials. It is the first time such a technique has been successful.
The researchers described their findings in the journal Nature Communications on Jan. 20.
Essentially the microscopic equivalent of a single sheet of paper, a 2-D nanosheet is a material just a few atoms thick. Nanomaterials have unique electronic and chemical properties compared to identically composed materials at larger, conventional scales.
"What's nice with a 2-D nanomaterial is that because it's a sheet, it's much easier for us to manipulate compared to other types of nanomaterials," says Xudong Wang.
Until now, materials scientists were limited to working with naturally occurring 2-D nanosheets. These natural 2-D structures include graphene, a single layer of graphite, and a limited number of other compounds.
Developing a reliable method to synthesize and manufacture 2-D nanosheets from other materials has been a goal of materials researchers and the nanotechnology industry for years.
In their technique, the UW-Madison team applied a specially formulated surfactant -- a detergent-like substance -- onto the surface of a liquid containing zinc ions.
Due to its chemical properties, the surfactant assembles itself into a single layer at the surface of the liquid, with negatively charged sulfate ions pointed in the direction of the liquid. Those sulfate ions draw the positively charged zinc ions from within the liquid to the surface, and within a couple hours enough zinc ions are drawn up to form continuous zinc oxide nanosheets only a few atomic layers thick.
Xudong Wang first had the idea for using a surfactant to grow nanosheets during a lecture he was giving in a course on nanotechnology in 2009.
"The course includes a lecture about self-assembly of monolayers," he says. "Under the correct conditions, a surfactant will self-assemble to form a monolayer. This is a well-known process that I teach in class. So while teaching this, I wondered why we wouldn't be able to reverse this method and use the surfactant monolayer first to grow the crystalline face."
After five years of trial and error with different surfactant solutions, the idea paid off.
"We are very excited about this," says Xudong Wang. "This is definitely a new way to fabricate 2-D nanosheets, and it has great potential for different materials and for many different applications."
Already, the researchers have found that the 2-D zinc oxide nanosheets they've grown are able to function as semiconductor transistors called a p-type, the opposite electronic behavior of naturally occurring zinc oxide. Researchers have for some time attempted to produce zinc oxide with reliable p-type semiconductor properties.
Zinc oxide is a very useful component of electronic materials, and the new nanosheets have potential for use in sensors, transducers and optical devices.
But the zinc oxide nanosheets are only the first of what could be a revolution in 2-D nanomaterials. Already, the UW-Madison team is applying its surfactant method to growing 2-D nanosheets of gold and palladium, and the technique holds promise for growing nanosheets from all sorts of metals that wouldn't form them naturally.
"It brings a lot of new functional material to this 2-D material category," Wang says.
CONTACT: Xudong Wang, 608-890-2667, email@example.com
DOWNLOAD IMAGE: https:/
Will Cushman, 608-262-2481, firstname.lastname@example.org
Xudong Wang | EurekAlert!
New design improves performance of flexible wearable electronics
23.06.2017 | North Carolina State University
Plant inspiration could lead to flexible electronics
22.06.2017 | American Chemical Society
An international team of scientists has proposed a new multi-disciplinary approach in which an array of new technologies will allow us to map biodiversity and the risks that wildlife is facing at the scale of whole landscapes. The findings are published in Nature Ecology and Evolution. This international research is led by the Kunming Institute of Zoology from China, University of East Anglia, University of Leicester and the Leibniz Institute for Zoo and Wildlife Research.
Using a combination of satellite and ground data, the team proposes that it is now possible to map biodiversity with an accuracy that has not been previously...
Heatwaves in the Arctic, longer periods of vegetation in Europe, severe floods in West Africa – starting in 2021, scientists want to explore the emissions of the greenhouse gas methane with the German-French satellite MERLIN. This is made possible by a new robust laser system of the Fraunhofer Institute for Laser Technology ILT in Aachen, which achieves unprecedented measurement accuracy.
Methane is primarily the result of the decomposition of organic matter. The gas has a 25 times greater warming potential than carbon dioxide, but is not as...
Hydrogen is regarded as the energy source of the future: It is produced with solar power and can be used to generate heat and electricity in fuel cells. Empa researchers have now succeeded in decoding the movement of hydrogen ions in crystals – a key step towards more efficient energy conversion in the hydrogen industry of tomorrow.
As charge carriers, electrons and ions play the leading role in electrochemical energy storage devices and converters such as batteries and fuel cells. Proton...
Scientists from the Excellence Cluster Universe at the Ludwig-Maximilians-Universität Munich have establised "Cosmowebportal", a unique data centre for cosmological simulations located at the Leibniz Supercomputing Centre (LRZ) of the Bavarian Academy of Sciences. The complete results of a series of large hydrodynamical cosmological simulations are available, with data volumes typically exceeding several hundred terabytes. Scientists worldwide can interactively explore these complex simulations via a web interface and directly access the results.
With current telescopes, scientists can observe our Universe’s galaxies and galaxy clusters and their distribution along an invisible cosmic web. From the...
Temperature measurements possible even on the smallest scale / Molecular ruby for use in material sciences, biology, and medicine
Chemists at Johannes Gutenberg University Mainz (JGU) in cooperation with researchers of the German Federal Institute for Materials Research and Testing (BAM)...
19.06.2017 | Event News
13.06.2017 | Event News
13.06.2017 | Event News
26.06.2017 | Life Sciences
26.06.2017 | Physics and Astronomy
26.06.2017 | Information Technology