Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Microbullet hits confirm graphene’s strength

01.12.2014

Rice University lab test material for suitability in body armor, spacecraft protection

Graphene’s great strength appears to be determined by how well it stretches before it breaks, according to Rice University scientists who tested the material’s properties by peppering it with microbullets.


Rice University scientists fired microbullets at supersonic speeds in experiments that show graphene is 10 times better than steel at absorbing the energy of a penetrating projectile. (Credit: Jae-Hwang Lee/Rice University)

The two-dimensional carbon honeycomb discovered a decade ago is thought to be much stronger than steel. But the Rice lab of materials scientist Edwin “Ned” Thomas didn’t need even close to a pound of graphene to prove the material is on average 10 times better than steel at dissipating kinetic energy.

The researchers report in the latest edition of Science that firing microscopic projectiles at multilayer sheets of graphene allowed the scientists to determine just how hard it is to penetrate at the nano level – and how strong graphene could be in macroscopic applications.

Thomas suggested the technique he and his research group developed could help measure the strength of a wide range of materials.

While other labs have looked extensively at graphene’s electronic properties and tensile strength, nobody had taken comprehensive measurements of its ability to absorb an impact, Thomas said. His lab found graphene’s ability to simultaneously be stiff, strong and elastic gives it extraordinary potential for use as body armor or for shielding spacecraft.

The lab pioneered its laser-induced projectile impact test (LIPIT), which uses the energy from a laser to drive microbullets away from the opposite side of an absorbing gold surface at great speed. In 2012, they first used an earlier version of LIPIT to determine the properties of multiblock copolymers that could not only stop microbullets but also completely encase them.

Since that study, Thomas and lead author Jae-Hwang Lee, a former research scientist at Rice and now an assistant professor at the University of Massachusetts at Amherst, have enhanced their technique to fire single microscopic spheres with great precision at speeds approaching 3 kilometers per second, much faster than a speeding bullet from an AK-47.

The researchers built a custom stage to line up multilayer graphene sheets mechanically drawn from bulk graphite. They tested sheets ranging from 10 to 100 nanometers thick (up to 300 graphene layers). They then used a high-speed camera to capture images of the projectiles before and after hits to judge their speed and viewed microscope images of the damage to the sheets.

In every case, the 3.7-micron spheres punctured the graphene. But rather than a neat hole, the spheres left a fractured pattern of “petals” around the point of impact, indicating the graphene stretched before breaking.

“We started writing the paper about the petals, but as we went along, it became evident that wasn’t really the story,” said Thomas, the William and Stephanie Sick Dean of Rice’s George R. Brown School of Engineering. “The bullet’s kinetic energy interacts with the graphene, pushes forward, stretches the film and is slowed down.”

The experiments revealed graphene to be a stretchy membrane that, in about 3 nanoseconds before puncture, distributes the stress of the bullet over a wide area defined by a shallow cone centered at the point of impact. Tensile stress cannot travel faster than the speed of sound in materials, and in graphene, it’s much faster than the speed of sound in air (1,125 feet per second).

“For graphene, we calculated the speed at 22.2 kilometers per second, which is higher than any other known material,” Thomas said.

As a microbullet impacts the graphene, the diameter of the cone it creates – determined by later examination of the petals – provides a way to measure how much energy the graphene absorbs before breaking.

“The game in protection is getting the stress to distribute over a large area,” Thomas said. “It’s a race. If the cone can move out at an appreciable velocity compared with the velocity of the projectile, the stress isn’t localized beneath the projectile.”

Controlled layering of graphene sheets could lead to lightweight, energy-absorbing materials. “Ideally you would have a lot of independent layers that aren’t too far apart or so close that they’re touching, because the loading goes from tensile to compressive,” Thomas said. That, he said, would defeat the purpose of spreading the strain away from the point of impact.

He expects LIPIT will be used to test many experimental materials. “Before you scale a project up, you’ve got to know what will work,” he said. “LIPIT lets us develop rapid methodologies to test nanoscale materials and find promising candidates. We’re working to demonstrate to NASA and the military that these microscopic tests are relevant to macroscopic properties.”

The paper’s co-authors are Rice graduate student Phillip Loya and Jun Lou, an associate professor of materials science and nanoengineering. The Defense Threat Reduction Agency and the Welch Foundation supported the research.

Ned Thomas shows how firing microbullets at graphene quantify its strength in this video: http://youtu.be/Sevm_DHu05o

Read the abstract at http://www.sciencemag.org/content/346/6213/1092.short

David Ruth | EurekAlert!

Further reports about: graphene graphene sheets kinetic kinetic energy materials microscopic properties technique

More articles from Materials Sciences:

nachricht New material could lead to erasable and rewriteable optical chips
07.12.2016 | University of Texas at Austin

nachricht Porous crystalline materials: TU Graz researcher shows method for controlled growth
07.12.2016 | Technische Universität Graz

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Significantly more productivity in USP lasers

In recent years, lasers with ultrashort pulses (USP) down to the femtosecond range have become established on an industrial scale. They could advance some applications with the much-lauded “cold ablation” – if that meant they would then achieve more throughput. A new generation of process engineering that will address this issue in particular will be discussed at the “4th UKP Workshop – Ultrafast Laser Technology” in April 2017.

Even back in the 1990s, scientists were comparing materials processing with nanosecond, picosecond and femtosesecond pulses. The result was surprising:...

Im Focus: Shape matters when light meets atom

Mapping the interaction of a single atom with a single photon may inform design of quantum devices

Have you ever wondered how you see the world? Vision is about photons of light, which are packets of energy, interacting with the atoms or molecules in what...

Im Focus: Novel silicon etching technique crafts 3-D gradient refractive index micro-optics

A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.

Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...

Im Focus: Quantum Particles Form Droplets

In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.

“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...

Im Focus: MADMAX: Max Planck Institute for Physics takes up axion research

The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.

The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

ICTM Conference 2017: Production technology for turbomachine manufacturing of the future

16.11.2016 | Event News

Innovation Day Laser Technology – Laser Additive Manufacturing

01.11.2016 | Event News

#IC2S2: When Social Science meets Computer Science - GESIS will host the IC2S2 conference 2017

14.10.2016 | Event News

 
Latest News

NTU scientists build new ultrasound device using 3-D printing technology

07.12.2016 | Health and Medicine

The balancing act: An enzyme that links endocytosis to membrane recycling

07.12.2016 | Life Sciences

How to turn white fat brown

07.12.2016 | Health and Medicine

VideoLinks
B2B-VideoLinks
More VideoLinks >>>