Nanometer-Scale Light Source is First to Show Single-Molecule Electroluminescence

Using photon emissions from individual molecules of silver, researchers at the Georgia Institute of Technology have created what may be the world’s smallest electroluminescent light source.

Believed to be the first demonstration of electroluminescence from individual molecules, the work could lead to new types of nanometer-scale optical interconnects, high-resolution optical microscopy, nanometer-scale lithography and other applications that require very small light sources. And because single molecules are known to emit one photon at a time, the technique could ultimately be the basis for high-efficiency quantum information processing and cryptography.

Though the effect was first reported in silver clusters composed of 2-8 atoms, the researchers also demonstrated electroluminescence in similarly prepared copper clusters, suggesting the effect may broadly apply to other metals. Details of the research were reported in the August 6 issue of the Proceedings of the National Academy of Sciences.

“This is the first time that anyone has seen electroluminescence from individual molecules,” said Robert Dickson, assistant professor in Georgia Tech’s School of Chemistry and Biochemistry. “What we have observed involves sub-nanometer scale sources to which an electric field is applied. These molecules emit very strongly, and are very robust.”

Dickson and collaborators Tae-Hee Lee and Jose Gonzalez began with thin films of silver oxide that are not electroluminescent. By exposing the film to electrical current of approximately one amp, they “activated” some of the silver oxide molecules, which then appeared within “discolored” regions in the film. When electrodes were attached to the film and an alternating current applied, a thin line of silver clusters began to emit light in colors that varied depending on the size of the clusters. The system operated at room temperature.

“When you zoom in more closely, you can see the emissions coming from single molecules,” said Dickson. “They blink and have dipole emission patterns. You see an incredibly thin line of emissive species close to the middle of the sample.”

Electroluminescence occurs when an electron recombines with a positively charged molecule from which a single electron has been removed to create an electron-hole pair. First, an electron is removed from a molecule, creating a positive charge. Then, an electron is quickly injected into a different state of the same molecule. Because of the charge differences, the electron is attracted to the hole, and when they recombine, a photon is released.

While normally stimulated by applying direct current (DC), the Georgia Tech group observed a dramatically enhanced response from high frequency alternating current (AC).

While DC voltage produced electroluminescence in the activated silver clusters, Dickson and his colleagues found that high frequency AC voltage — above 150 megahertz — produced a response as much as 10,000 times greater. Dickson believes the AC voltage created rapid recombination within single molecules in a very narrow section of a sample, producing the enhanced response. Bulk materials normally cannot respond quickly enough to the alternating current to enhance the electroluminescence to such a large degree.

The AC current was more efficient than DC current at converting electrical current to light because it injects the electron charge at just the right time, minimizing the amount of energy lost to production of heat, Dickson explained. From a practical standpoint, that increases the operating life of the emitting clusters and reduces the amount of current required to produce light, he noted.

“We know that the charge is recombining in the molecules because you can simultaneously measure the electroluminescence and the current, and the peaks are correlated,” he said. “This is an extremely interesting materials system, not only because of the single-molecule electroluminescence, but also because of the resonance we see at relatively high frequencies.”

Though the discovery may have important implications for optoelectronic devices, Dickson’s group is focusing first on understanding the basic process.

“We are concentrating on understanding the very fundamental aspects of this: what the nature of the emission is, how the emission occurs, the different time scales for electron injection, hole injection and recombination,” he said. “We need to know how to better control this before we can begin to use it in nanometer scale devices or as nanometer scale optoelectronic components in circuitry. A lot of engineering will have to be done to make any potential optoelectronic devices both useful and stable.”

The electroluminescence research builds on earlier work done by Dickson and colleagues Lynn Peyser and Amy Vinson that demonstrated optical storage potential of thin-film silver oxide clusters. In that work, reported in the journal Science in January 2001, the researchers demonstrated binary optical storage by writing and reading simple images recorded on films of silver oxide nanoparticles activated by light of a specific frequency. That work is continuing, and advances have been made toward potential optical storage systems.

Support for Dickson’s research comes from the Sloan and Dreyfus Foundations, as well as internal Georgia Tech research funds.

RESEARCH NEWS & PUBLICATIONS OFFICE
Georgia Institute of Technology
430 Tenth Street, N.W., Suite N-116
Atlanta, Georgia 30318 USA

Media Contact

John Toon EurekAlert!

Alle Nachrichten aus der Kategorie: Power and Electrical Engineering

This topic covers issues related to energy generation, conversion, transportation and consumption and how the industry is addressing the challenge of energy efficiency in general.

innovations-report provides in-depth and informative reports and articles on subjects ranging from wind energy, fuel cell technology, solar energy, geothermal energy, petroleum, gas, nuclear engineering, alternative energy and energy efficiency to fusion, hydrogen and superconductor technologies.

Zurück zur Startseite

Kommentare (0)

Schreib Kommentar

Neueste Beiträge

Scientists solve big limitation of stratospheric balloon payloads

How do you cool a large telescope to absolute zero while flying it from a huge balloon at 130,000 feet? Nearly all photons emitted after the Big Bang are now…

Pumping a nanoparticle to lase at low power

A single nanoparticle can act like a laser at low power but still emit a sharp signal. Lasers are used in a range of everyday devices, harnessing the power of…

Ultrasensitive transistor for herbicide detection in water

A new polymer-based, solid-state transistor can more sensitively detect a weed killer in drinking water than existing hydrogel-based fluorescence sensor chips. The details were published in Chemistry-A European Journal. The…

Partners

By continuing to use the site, you agree to the use of cookies. more information

The cookie settings on this website are set to "allow cookies" to give you the best browsing experience possible. If you continue to use this website without changing your cookie settings or you click "Accept" below then you are consenting to this.

Close