Energy Flow in the Nano Range

Energy transport in biomimetic nanotubes (left) and a three-dimensional spectrum (right). Bjoern Kriete (l.) / Stefan Mueller (r.)

Plants and bacteria lead the way: They can capture the energy of sunlight with light-harvesting antennas and transfer it to a reaction centre. Transporting energy efficiently and in a targeted fashion in a minimum of space – this is also of interest to mankind. If scientists were to master it perfectly, they could significantly improve photovoltaics and optoelectronics.

Two new spectroscopic methods

But how can the flow of energy be observed? This is what Tobias Brixner's group at the Institute of Physical and Theoretical Chemistry at Julius-Maximilians-Universität (JMU) Würzburg in Bavaria, Germany, is working on.

In the journal Nature Communications, the team now presents two new spectroscopic methods with which energy transport on the nanoscale can be observed. According to the JMU professor, the new findings provide valuable information for the design of artificial light-harvesting antennas.

These research successes were achieved in cooperation with the working groups of Christoph Lambert and Todd Marder (JMU Würzburg), Uwe Bunz and Andreas Dreuw (University of Heidelberg) as well as Jasper Knoester and Maxim Pshenichnikov (University of Groningen, Netherlands).

Nanotubes imitate nature

Using the new methods, the research teams have succeeded in deciphering the energy transport in double-walled nanotubes made up of thousands of dye molecules. These tiny tubes serve as models for the light-harvesting antennas of photosynthetically active bacteria.

At low light intensities, the energetic excitations are transported from the outer to the inner wall of the tubes. At high intensities, on the other hand, the excitations only move along the outer wall – if two excitations meet there, one of them disappears. “This effect, which has been known for some time, can be made directly visible with our method for the first time,” says Brixner.

The measurements could be carried out by combining the exciton-exciton-interaction-two-dimensional spectroscopy (EEI2D spectroscopy) method developed in the Brixner group with a microfluidic arrangement of the Groningen group.

Data acquisition is much faster

In the second paper, the research teams also demonstrate a new approach to measuring energy flows. The highlight: The speed of the data recording could be extremely increased compared to the state of the art. Within just eight minutes, it was possible to measure up to 15 different 3D spectra simultaneously in a single experiment. Traditional methods, on the other hand, typically require several hours for only a single spectrum.

As a basis for measuring coherent spectra over three frequency dimensions, the researchers employed a fast method of varying the temporal sequence of ultrashort laser pulses. “The expansion from 2D to 3D frequency analysis and the increase in the number of light-matter interactions from the four usual in the literature to six now provides detailed insights into the dynamics of highly excited states,” says Brixner.

Funding

This work was funded by the Solar Technologies Go Hybrid research network of the Free State of Bavaria, the German Research Foundation (DFG), and the European Research Council (ERC) as part of the ERC consolidator grant “MULTISCOPE”.

Prof. Dr. Tobias Brixner, Institute of Physical and Theoretical Chemistry, JMU Würzburg, brixner@phys-chemie.uni-wuerzburg.de

S. Mueller, J. Lüttig, P. Malý, L. Ji, J. Han, M. Moos, T. B. Marder, U. H. F. Bunz, A. Dreuw, C. Lambert, and T. Brixner, “Rapid multiple‐quantum three‐dimensional fluorescence spectroscopy disentangles quantum pathways”, Nature Communications, https://doi.org/10.1038/s41467-019-12602-x (2019)

B. Kriete, J. Lüttig, T. Kunsel, P. Malý, T. L. C. Jansen, J. Knoester, T. Brixner, and M. S. Pshenichnikov, “Interplay between structural hierarchy and exciton diffusion in artificial light harvesting”, Nature Communications, https://doi.org/10.1038/s41467-019-12345-9 (2019)

http://www.phys-chemie.uni-wuerzburg.de/en/arbeitsgruppen/prof-dr-tobias-brixner… Webseite Prof. Tobias Brixner

Media Contact

Robert Emmerich Julius-Maximilians-Universität Würzburg

Alle Nachrichten aus der Kategorie: Power and Electrical Engineering

This topic covers issues related to energy generation, conversion, transportation and consumption and how the industry is addressing the challenge of energy efficiency in general.

innovations-report provides in-depth and informative reports and articles on subjects ranging from wind energy, fuel cell technology, solar energy, geothermal energy, petroleum, gas, nuclear engineering, alternative energy and energy efficiency to fusion, hydrogen and superconductor technologies.

Zurück zur Startseite

Kommentare (0)

Schreib Kommentar

Neueste Beiträge

Taking 2D materials for a spin

Scientists at the University of Tsukuba and the Institute of High Pressure Physics fabricate a novel molybdenum disulfide transistor and create an image of the spins of the electrons passing…

Life’s rich pattern

Researchers use sound to shape the future of printing. Researchers in the UK have developed a way to coax microscopic particles and droplets into precise patterns by harnessing the power…

Tantalizing signs of phase-change ‘turbulence’ in RHIC collisions

Fluctuations in net proton production hint at a possible ‘critical point’ marking a change in the way nuclear matter transforms from one phase to another. Physicists studying collisions of gold…

Partners & Sponsors