The elusive nature of liquid brines on Mars

Determining the conditions in which brines are stable could be key to better understanding the climate and potential habitability of Mars.

More than a hundred years ago, astronomer Percival Lowell made the case for the existence of canals on Mars designed to redistribute water from the Martian ice caps to its lower, drier latitudes. This necessarily meant the existence of Martians to build the canals.

While Lowell was proven wrong by better telescopes, the question of whether there’s liquid water on Mars continues to tantalize researchers. Liquid water is a critical precondition for a habitable planet. Yet the combination of low temperature, atmospheric pressure and water vapor pressure on Mars means any liquid water found there would likely freeze, boil or evaporate immediately, making its presence unlikely.

Yet researchers continue to make the case for the presence of liquid water on Mars.

Of particular interest has been the discovery of the “recurring slope lineae,” or RSL, which are dark linear features found on steep slopes in specific regions of Mars. RSL display seasonal changes, appearing in warmer seasons and fading in colder seasons, in a way that is consistent with the behavior of liquid water. Distinct striped and polygonal features in Martian permafrost have also been pointed to as possible evidence of thermal cycles. A further case has also been made for an assortment of potential liquid brines.

But a new paper published in the Proceedings of the National Academy of Sciences of the United States of America, the official journal of the National Academy of Sciences, throws cold water on the notion that we are likely find liquid water on Mars in RSLs, permafrost or brines anytime soon.

The paper, “The Elusive Nature of Martian Liquid Brines,” was co-authored by Vincent Chevrier, an associate research professor at the University of Arkansas’ Center for Space and Planetary Sciences, and Rachel Slank, a postdoctoral fellow at The Lunar and Planetary Institute in Houston, Texas. Slank earned her Ph.D. at the U of A while working with Chevrier, who has spent the last 20 years studying Mars for signs of liquid water. In short, he’s as invested as anyone in there being liquid water on Mars, but he thinks the evidence just isn’t there yet.

The goal of the paper is to educate the public on the current state of knowledge regarding the existence of liquid water on Mars.

“I wanted to write this paper for a very long time,” Chevrier said, “because I think there is a lot of confusion, a lot of misunderstanding, and a lot of erroneous interpretations of what the research papers are saying about the state of liquid water on Mars.”

The authors suggest that a closer look at RSLs indicates their behavior is consistent with sand and dust flows with no water needed to create them. Nor can available data from Martian orbiters confirm liquid water plays any role in RSL development.

Other researchers think that brines, which are solutions with a high concentration of salts, such as Earth’s oceans, may hold the key to finding liquid water on Mars. Brines can freeze at much lower temperatures, and there is an abundance of salts on Mars. Of those salts, perchlorates would seem to be the most promising, since they have extremely low eutectic temperatures (which is when the melting point of a mixture is lower than any single ingredient). For instance, a calcium perchlorate brine solidifies at -75 degrees Celsius, while Mars has an average surface temperature of -50 C at the equator, theoretically suggesting there could be a zone where calcium perchlorate brine could stay liquid, particularly in the subsurface.

The authors then examine all of the arguments for and against brines potentially forming stable liquids. Ultimately, they concluded that the various limiting factors, including the relatively low amounts of the most promising salts, water vapor pressure and ice location “strongly limit the abundances of brines on the surface or shallow subsurface.” And even if brines did form, they would “remain highly un-habitable by terrestrial standards.”

In the last section of the paper, the authors state: “Despite these drawbacks and limitations, there is always the possibility that Martian life adapted to those brines and some terrestrial organisms could survive in them, which is a consideration for planetary protection because life on Mars might exist today in that case. Hence, detecting brines in situ remains a major objective of the exploration of the red planet.”

Moving forward, the authors suggest the next hurdles will be improving the instruments needed to detect small amounts of brines, doing a better job of identifying the best places to look for them, and being able to conduct more laboratory measurements under Martian conditions.

“Despite our best efforts to prove otherwise,” Chevrier concludes, “Mars still remains a cold, dry and utterly unhabitable desert.”

Journal: Proceedings of the National Academy of Sciences
DOI: 10.1073/pnas.2321067121
Method of Research: Commentary/editorial
Subject of Research: Not applicable
Article Title: The elusive nature of Martian liquid brines
Article Publication Date: 16-Dec-2024
COI Statement: No conflicts to report