An energy-efficient way of enriching hydrogen isotopes in silicon

Schematic illustration of the hydrogen-to-deuterium exchange reactions at a hydrogen-terminated n-Si surface in the presence of HDO molecules (Deuterium: red spheres, Hydrogen: pink spheres, Oxygen: green spheres, Silicon: blue spheres).
Credit: Takahiro Matsumoto from NCU Japan

Heavily enriched…

The discovery of isotopes in the early 20th century marked a key moment in the history of physics and led to a much more refined understanding of the atomic nucleus. Isotopes are ‘versions’ of a given element of the periodic table that bear the same number of protons but a different number of neutrons, and therefore vary in mass. These differences in mass can radically alter certain physical properties of the atoms, such as their radioactive decay rates, their possible reaction pathways in nuclear fission reactors, and much more.

While most isotopes of an element share similar chemical properties, there is one notable exception: hydrogen isotopes. Most hydrogen atoms on Earth contain only one proton and one electron, but there exist hydrogen isotopes which also have one neutron (deuterium) or two neutrons (tritium). Deuterium, which essentially weighs twice as much as ‘normal’ hydrogen, has found many practical and scientific uses. For example, it can be used to label and track molecules such as proteins to investigate biochemical processes. It can also be strategically used in drugs to reduce their metabolic rate and increase their half-life in the body.

Another important application of deuterium exists in the field of semiconductor electronics. The surface of silicon-based semiconductors has to be ‘passivated’ with hydrogen to ensure silicon atoms don’t come off (desorb) easily, thereby increasing the durability of microchips, batteries, and solar cells. However, through mechanisms that are still not completely understood, passivation with deuterium instead of hydrogen results in desorption probabilities about one hundred times lower, implying that deuterium may soon become an indispensable ingredient in electronic devices. Unfortunately, both the procurement of deuterium and available techniques to enrich silicon surfaces with it are very energy inefficient or require very expensive deuterium gas.

Fortunately, at Nagoya City University (NCU), Japan, a team of scientists led by Professor Takahiro Matsumoto have found an energy-efficient strategy to enrich silicon surfaces using a dilute deuterium solution. This study, which was published in Physical Review Materials, was carried out in collaboration with Dr. Takashi Ohhara of Japan Atomic Energy Agency and Dr. Yoshihiko Kanemitsu from Kyoto University.

The researchers found that a peculiar exchange reaction from hydrogen to deuterium can occur on the surface of nanocrystalline silicon (n-Si). They demonstrated this reaction in thin n-Si films submerged in a deuterium-containing solution using inelastic neutron scattering. This spectroscopy technique involves irradiating neutrons onto a sample and analyzing the resulting atomic motions or crystal vibrations. These experiments, coupled with other spectroscopy methods and energy calculations based on quantum mechanics, revealed the underlying mechanisms that favor the replacement of hydrogen terminations on the surface of n-Si with deuterium: The exchange process is closely related to differences in the surface vibrational modes between hydrogen- and deuterium-terminated n-Si. “We achieved a fourfold increase in the concentration of surface deuterium atoms on n-Si in our experiments performed in the liquid phase,” highlights Dr. Matsumoto, “We also proposed a gas-phase enrichment protocol for n-Si that, according to our theoretical calculations, could enhance the rate of deuterium enrichment 15-fold.

This innovative strategy of exploiting quantum effects on the surface of n-Si could pave the way to new methods to procure and utilize deuterium. “The efficient hydrogen-to-deuterium exchange reaction we reported may lead to sustainable, economically feasible, and environment-friendly deuterium enrichment protocols, leading to more durable semiconductor technology,” concludes Dr. Matsumoto.

The NCU team also stated that “It has been theoretically predicted that the heavier the hydrogen is, the higher the efficiency of the exchange reaction is. Thus, we can expect more efficient enrichment of tritium atoms on n-Si, which leads to the possibility of purifying tritium contaminated water. We believe that this is an issue that must be urgently solved.

Let us hope the findings of this work allow us to benefit more from the heavier isotopes of hydrogen without taking a toll on our planet.

Reference

Title of original paper: Determination of localized surface phonons in nanocrystalline silicon by inelastic neutron scattering spectroscopy and its application to deuterium isotope enrichment

Journal: Physical Review Materials

DOI: https://doi.org/10.1103/PhysRevMaterials.5.066003

 

About Nagoya City University, Japan

Nagoya City University (NCU), a public university established in 1950, began with the Medical School and the Faculty of Pharmaceutical Sciences. Its origins, however, stretch back to the Nagoya School of Pharmacy, founded in 1884, and the Nagoya Municipal Women’s Higher Medical School, founded in 1943. NCU has grown into an urban-style public university in the center of Nagoya, Japan, with around 4,000 students and 1,600 faculty members. In the last 60 years, NCU has graduated over 26,000 students. NCU continues to expand as an advanced education and research center to assist in the improvement of local health and welfare, as well as the development of the local economy and culture.
Website: https://www.nagoya-cu.ac.jp/english/

About Professor Takahiro Matsumoto from Nagoya City University, Japan

Takahiro Matsumoto has been a Professor at Nagoya City University since 2015. Before this, he researched at Stanley Electric Co., Japan, for 15 years. He obtained a Master’s degree in physics from the University of Tokyo, Japan, in 1988. He is a member of the Society of Muon and Meson Science of Japan and The Japan Society of Applied Physics, among others. He has authored four books and over a hundred papers on the topics of nanomaterials, photonics, optics, quantum electronics, and nanostructure chemistry and physics.

Funding information

This study was supported by JSPS KAKENHI Grant No. 20H04455 and the Collaborative Research Program of the Institute for Chemical Research, Kyoto University (Grant No. 2020-97).

Journal: Physical Review Materials
DOI: 10.1103/PhysRevMaterials.5.066003
Method of Research: Experimental study
Subject of Research: Not applicable
Article Title: Determination of localized surface phonons in nanocrystalline silicon by inelastic neutron scattering spectroscopy and its application to deuterium isotope enrichment
Article Publication Date: 27-Jun-2021

Media Contact

Takuya Kurata
ncu_public@sec.nagoya-cu.ac.jp

Expert Contact

Takahiro Matsumoto
matsumoto@sda.nagoya-cu.ac.jp

Media Contact

Takuya Kurata
Nagoya City University

All latest news from the category: Physics and Astronomy

This area deals with the fundamental laws and building blocks of nature and how they interact, the properties and the behavior of matter, and research into space and time and their structures.

innovations-report provides in-depth reports and articles on subjects such as astrophysics, laser technologies, nuclear, quantum, particle and solid-state physics, nanotechnologies, planetary research and findings (Mars, Venus) and developments related to the Hubble Telescope.

Back to home

Comments (0)

Write a comment

Newest articles

Innovative vortex beam technology

…unleashes ultra-secure, high-capacity data transmission. Scientists have developed a breakthrough optical technology that could dramatically enhance the capacity and security of data transmission (Fig. 1). By utilizing a new type…

Tiny dancers: Scientists synchronise bacterial motion

Researchers at TU Delft have discovered that E. coli bacteria can synchronise their movements, creating order in seemingly random biological systems. By trapping individual bacteria in micro-engineered circular cavities and…

Primary investigation on ram-rotor detonation engine

Detonation is a supersonic combustion wave, characterized by a shock wave driven by the energy release from closely coupled chemical reactions. It is a typical form of pressure gain combustion,…