Atomic Design by Water
A central element in such diverse technological problems as corrosion protection, battery materials or hydrogen production via electrolysis or fuel cells is the contact between two conducting elements – the electrolyte and the solid electrode at which a voltage is applied.
Despite its importance for a multitude of key technologies hardly anything is known about the atomistic structure of the interface between the electrode and the electrolyte. In particular the atomic structure of the solid electrode has a decisive impact on the chemical reactions taking place at the interface.
The ability to selectively modify the structure of the surface at the scale of individual atoms would open completely new possibilities target and influence central chemical reactions.
Scientist from the Computational Materials Design department of the Max-Planck-Institut für Eisenforschung have come a great deal closer to achieving this goal. Within the framework of the Excellence-cluster RESOLV, a joint research initiative of seven research institutions in the Ruhr area, an unexpected phenomenon was found with the help of highly accurate quantum mechanical methods and powerful supercomputers.
Previous studies of metallic surfaces repeatedly show that the structure of the surface hardly changes in contact with a liquid electrolyte. The researchers were therefore very surprised when they brought a semi-conducting surface into contact with an electrolyte.
“We were completely surprised to see the formation of structures, which are unstable in the absence of water and are also not observed”, says Dr. Mira Todorova, head of the Electrochemistry and Corrosion group. The department head Prof. Neugebauer is equally enthusiastic:
“Our simulation methods allowed us not only to find a completely new and unexpected phenomenon, but also to identify the underlying mechanisms. This opens up totally new possibilities to shape and design surfaces with atomic precision.”
These studies not only offer new insights into future-oriented technologies, but also provide a new perception of a question intensely discussed in geology: The cause of the enhanced crack formation in minerals when they are exposed to a humid environment.
The work was published in the journal Physical Review Letters.
S. Yoo, M. Todorova and J. Neugebauer
Selective solvent-induced stabilization of polar oxide surfaces in an electrochemical environment
Physical Review Letters 120, 066101 (2018)
Authors of the press release: M. Todorova, J. Neugebauer
All latest news from the category: Life Sciences and Chemistry
Articles and reports from the Life Sciences and chemistry area deal with applied and basic research into modern biology, chemistry and human medicine.
Valuable information can be found on a range of life sciences fields including bacteriology, biochemistry, bionics, bioinformatics, biophysics, biotechnology, genetics, geobotany, human biology, marine biology, microbiology, molecular biology, cellular biology, zoology, bioinorganic chemistry, microchemistry and environmental chemistry.
Novel strategy discovered for FLT3-ITD-positive acute myeloid leukemia
A new type of targeting chaperon protein HSP70 inhibitor QL47 was recently discovered by a team led by Prof. LIU Qingsong from the Hefei Institutes of Physical Science (HFIPS) of the Chinese…
New way to simulate hydrogen storage efficiency of materials with high accuracy
Scientists develop new computational method that can simulate hydrogen storage on silicon carbide nanotubes much more accurately than conventional method. Hydrogen energy has the potential to be a key measure…