In the last few years, much work has been done to improve the efficiency with which these devices convert sunlight into power, including the development of new materials, device structures and processing techniques.
In a new study, available online this week in the journal Nature Photonics, researchers at the UCLA Henry Samueli School of Engineering and Applied Science and UCLA's California Nanosystems Institute (CNSI) report that they have significantly enhanced polymer solar cells' performance by building a device with a new "tandem" structure that combines multiple cells with different absorption bands. The device had a certified power-conversion efficiency of 8.62 percent and set a world record in July 2011.
Further, after the researchers incorporated a new infrared-absorbing polymer material provided by Sumitomo Chemical of Japan into the device, the device's architecture proved to be widely applicable and the power-conversion efficiency jumped to 10.6 percent — a new record — as certified by the U.S. Department of Energy's National Renewable Energy Laboratory.
By using cells with different absorption bands, tandem solar cells provide an effective way to harvest a broader spectrum of solar radiation. However, the efficiency doesn't automatically increase by simply combining two cells. The materials for the tandem cells have to be compatible with each other for efficient light harvesting, the researchers said.
Until now, the performance of tandem devices lagged behind single-layer solar cells, mainly due to this lack of suitable polymer materials. UCLA Engineering researchers have demonstrated highly efficient single-layer and tandem polymer solar cells featuring a low-band-gap–conjugated polymer specially designed for the tandem structure. The band gap determines the portion of the solar spectrum a polymer absorbs.
"Envision a double-decker bus," said Yang Yang, a professor of materials science and engineering at UCLA Engineering and principal investigator on the research. "The bus can carry a certain number of passengers on one deck, but if you were to add a second deck, you could hold many more people for the same amount of space. That's what we've done here with the tandem polymer solar cell."
To use solar radiation more effectively, Yang's team stacked, in series, multiple photoactive layers with complementary absorption spectra to construct a tandem polymer solar cell. Their tandem structure consists of a front cell with a larger (or high) band gap material and a rear cell with a smaller (or low) band gap polymer, connected by a designed interlayer.
When compared to a single-layer device, the tandem device is more efficient in utilizing solar energy, particularly by minimizing other energy losses. By using more than one absorption material, each capturing a different part of the solar spectrum, the tandem cell is able to maintain the current and increase the output voltage. These factors enable the increase in efficiency, the researchers said.
"The solar spectra is very broad and covers the visible as well as the invisible, the infrared and the UV," said Shuji Doi, research group manager for Sumitomo Chemical. "We are very excited that Sumitomo's low–band gap polymer has contributed to the new record efficiency."
"We have been doing research in tandem solar cells for a much shorter length of time than in the single-junction devices," said Gang Li, a member of the research faculty at UCLA Engineering and a co-author of the Nature Photonics paper. "For us to achieve such success in improving the efficiency in this short time period truly demonstrates the great potential of tandem solar cell technology."
"Everything is done by a very low-cost wet-coating process," Yang said. "As this process is compatible with current manufacturing, I anticipate this technology will become commercially viable in the near future."
This study opens up a new direction for polymer chemists to pursue designs of new materials for tandem polymer solar cells. Furthermore, it indicates an important step towards the commercialization of polymer solar cells. Yang said his team hopes to reach 15 percent efficiency in the next few years.
Yang, who holds UCLA's Carol and Lawrence E. Tannas Jr. Endowed Chair in Engineering, is also faculty director of the Nano Renewable Energy Center at the California NanoSystems Institute at UCLA.
The study was supported by the National Science Foundation, the U.S Air Force Office of Scientific Research, the U.S. Office of Naval Research and the U.S. Department of Energy, together with the National Renewable Energy Laboratory.
Sumitomo Chemical is one of Japan's leading chemical companies, offering a diverse range of products globally in the fields of basic chemicals, petro-chemicals, IT-related chemicals and materials, agricultural chemicals, and pharmaceuticals. The company's consolidated net sales for fiscal year 2010 were $23.8 billion.
The UCLA Henry Samueli School of Engineering and Applied Science, established in 1945, offers 28 academic and professional degree programs and has an enrollment of more than 5,000 students. The school's distinguished faculty are leading research to address many of the critical challenges of the 21st century, including renewable energy, clean water, health care, wireless sensing and networking, and cybersecurity. Ranked among the top 10 engineering schools at public universities nationwide, the school is home to nine multimillion-dollar interdisciplinary research centers in wireless sensor systems, nanoelectronics, nanomedicine, renewable energy, customized computing, and the smart grid, all funded by federal and private agencies. (http://www.engineer.ucla.edu | http://www.twitter.com/uclaengineering)
For more UCLA news, visit the UCLA Newsroom and follow us on Twitter.
Wileen Wong Kromhout | EurekAlert!
Tangled magnetic fields power cosmic particle accelerators
14.12.2018 | DOE/SLAC National Accelerator Laboratory
In search of missing worlds, Hubble finds a fast evaporating exoplanet
14.12.2018 | NASA/Goddard Space Flight Center
The more objects we make "smart," from watches to entire buildings, the greater the need for these devices to store and retrieve massive amounts of data quickly without consuming too much power.
Millions of new memory cells could be part of a computer chip and provide that speed and energy savings, thanks to the discovery of a previously unobserved...
What if, instead of turning up the thermostat, you could warm up with high-tech, flexible patches sewn into your clothes - while significantly reducing your...
A widely used diabetes medication combined with an antihypertensive drug specifically inhibits tumor growth – this was discovered by researchers from the University of Basel’s Biozentrum two years ago. In a follow-up study, recently published in “Cell Reports”, the scientists report that this drug cocktail induces cancer cell death by switching off their energy supply.
The widely used anti-diabetes drug metformin not only reduces blood sugar but also has an anti-cancer effect. However, the metformin dose commonly used in the...
A research team from the University of Zurich has developed a new drone that can retract its propeller arms in flight and make itself small to fit through narrow gaps and holes. This is particularly useful when searching for victims of natural disasters.
Inspecting a damaged building after an earthquake or during a fire is exactly the kind of job that human rescuers would like drones to do for them. A flying...
Over the last decade, there has been much excitement about the discovery, recognised by the Nobel Prize in Physics only two years ago, that there are two types...
12.12.2018 | Event News
10.12.2018 | Event News
06.12.2018 | Event News
14.12.2018 | Power and Electrical Engineering
14.12.2018 | Physics and Astronomy
14.12.2018 | Physics and Astronomy