Many chemical processes run so fast that they are only roughly understood. To clarify these processes, a team from the Technical University of Munich (TUM) has now developed a methodology with a resolution of quintillionths of a second. The new technology stands to help better understand processes like photosynthesis and develop faster computer chips.
An important intermediary step in many chemical processes is ionization. A typical example of this is photosynthesis. The reactions take only a few femtoseconds (quadrillionths of a second) or even merely a few hundred attoseconds (quintillionths of a second). Because they run so extremely fast, only the initial and final products are known, but not the reaction paths or the intermediate products.
Prof. Dr. Birgitta Bernhardt measuring at the Department of Physics at the Technical University of Munich.
Photo: Michael Mittermair / TUM
To observe such ultrafast processes, science needs a measurement technology that is faster than the observed process itself. So-called “pump-probe spectroscopy” makes this possible.
Here, the sample is excited using an initial laser pulse, which sets the reaction into motion. A second, time-delayed pulse queries the momentary state of the process. Multiple repetitions of the reaction with different time delays result in individual stop-motion images, which can then be compiled into a “film clip”.
Two eyes see more than one
Now, a team of scientists headed by Birgitta Bernhardt, a former staff member at the Chair of Laser and X-ray Physics at TU Munich and meanwhile junior professor at the Institute of Applied Physics at the University of Jena, have for the first time succeeded in combining two pump-probe spectroscopy techniques using the inert gas krypton. This allowed them to shed light on the ultrafast ionization processes in a precision that has simply not been possible hitherto.
“Prior to our experiment, one could observe either which part of the exciting light was absorbed by the sample over time or measure what kind of and how many ions were created in the process,” explains Bernhardt. “We have now combined the two techniques, which allows us to observe the precise steps by which the ionization takes place, how long these intermediate products exist and what precisely the exciting laser pulse causes in the sample.”
Ultrafast processes under control
The combination of the two measuring techniques allows the scientists not only to record the ultrafast ionization processes. Thanks to the variation in the intensity of the second, probing laser pulse, they can now, for the first time, also control and in this way also influence the ionization dynamics.
“This kind of control is a very powerful instrument,” explains Bernhardt. “If we can precisely understand and even influence fast ionization processes, we are able to learn a lot about light-driven processes like photosynthesis – especially about the initial moments in which this complex machinery is set into motion and which is hardly understood to date.”
The technology developed by Bernhardt and her colleagues is also interesting for the development of new, faster computer chips in which the ionization of silicon plays a significant role. If the ionization states of silicon can not only be sampled on such a short time scale, but can also be set – as the first experiments with krypton suggest – scientists might one day be able to use this to develop novel and even faster computer technologies.
The work is the result of a collaboration between the workgroups led by Prof. Reinhard Kienberger, who heads the Chair of Laser and X-ray Physics at TU Munich and Stephan Fritzsche, professor at the Institute of Theoretical Physics of the Friedrich Schiller University of Jena.
The research was funded by the European Research Council (ERC), the German Federal Ministry of Education and Research (BMBF), the Max Planck Society, the Max Planck Institute of Quantum Optics, the German Research Foundation (in the context of the Cluster of Excellence Munich Center for Advanced Photonics, MAP), the Alexander von Humboldt Foundation, the Carl Zeiss Foundation, the Donostia International Physics Center of the Donostia-San Sebastián University (Spain) and the workgroup Small Quantum Systems of the European XFEL in Hamburg.
Konrad Hütten, Michael Mittermair, Sebastian O. Stock, Randolf Beerwerth, Vahe Shirvanyan, Johann Riemensberger, Andreas Duensing, Rupert Heider, Martin S. Wagner, Alexander Guggenmos, Stephan Fritzsche, Nikolay M. Kabachnik, Reinhard Kienberger and Birgitta Bernhardt.
Ultrafast Quantum Control of Ionization Dynamics in Krypton
Nature Communications, 9, 719 (218) – DOI: 10.1038/s41467-018-03122-1
Prof. Dr. Birgitta Bernhardt (Jun.-Prof.)
Abbe Center of Photonics
Albert-Einstein-Straße 6, 07745 Jena, Germany
Tel.: +49 3641 94 7818 – E-mail: Birgitta.Bernhardt@uni-jena.de
Prof. Dr. Reinhard Kienberger
Technical University of Munich
Chair for Laser and X-ray Physics, E11
James Frank Str., 85748 Garching, Germany
Tel.: +49 89 289 12840 – E-mail: firstname.lastname@example.org
https://www.tum.de/nc/en/about-tum/news/press-releases/detail/article/34499/ Link to the press release
Dr. Ulrich Marsch | Technische Universität München
Extremely energetic particles coupled with the violent death of a star for the first time
22.11.2019 | University of Copenhagen
First detection of gamma-ray burst afterglow in very-high-energy gamma light
21.11.2019 | Max-Planck-Institut für Kernphysik
Conventional light microscopes cannot distinguish structures when they are separated by a distance smaller than, roughly, the wavelength of light. Superresolution microscopy, developed since the 1980s, lifts this limitation, using fluorescent moieties. Scientists at the Max Planck Institute for Polymer Research have now discovered that graphene nano-molecules can be used to improve this microscopy technique. These graphene nano-molecules offer a number of substantial advantages over the materials previously used, making superresolution microscopy even more versatile.
Microscopy is an important investigation method, in physics, biology, medicine, and many other sciences. However, it has one disadvantage: its resolution is...
Nanooptical traps are a promising building block for quantum technologies. Austrian and German scientists have now removed an important obstacle to their practical use. They were able to show that a special form of mechanical vibration heats trapped particles in a very short time and knocks them out of the trap.
By controlling individual atoms, quantum properties can be investigated and made usable for technological applications. For about ten years, physicists have...
An international team of scientists, including three researchers from New Jersey Institute of Technology (NJIT), has shed new light on one of the central mysteries of solar physics: how energy from the Sun is transferred to the star's upper atmosphere, heating it to 1 million degrees Fahrenheit and higher in some regions, temperatures that are vastly hotter than the Sun's surface.
With new images from NJIT's Big Bear Solar Observatory (BBSO), the researchers have revealed in groundbreaking, granular detail what appears to be a likely...
The Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM in Dresden has succeeded in using Selective Electron Beam Melting (SEBM) to...
15.11.2019 | Event News
15.11.2019 | Event News
05.11.2019 | Event News
22.11.2019 | Life Sciences
22.11.2019 | Health and Medicine
22.11.2019 | Studies and Analyses