According to a new theory by Rice University scientists, imperfections in certain two-dimensional materials create the conditions by which nanoscale magnetic fields arise.
Calculations by the lab of Rice theoretical physicist Boris Yakobson show these imperfections, called grain boundaries, in two-dimensional semiconducting materials known as dichalcogenides can be magnetic. This may lead to new strategies for the growing field of spintronics, which takes advantage of the intrinsic spin of electrons and their associated magnetic fields for electronic and computing devices.
The discovery by Yakobson, lead author Zhuhua Zhang and their colleagues was reported online this week in the American Chemical Society journal ACS Nano.
Dichalcogenides are hybrids that combine transition metal and chalcogen atoms, which include sulfur, selenium and tellurium. The Yakobson group focused on semiconducting molybdenum disulfide (MDS) that, like atom-thick graphene, can be grown via chemical vapor deposition (CVD), among other methods. In a CVD furnace, atoms arrange themselves around a catalyst seed into familiar hexagonal patterns; however, in the case of MDS, sulfur atoms in the lattice alternately float above and below the layer of molybdenum.
When two growing blooms meet, they're highly unlikely to line up, so the atoms find a way to connect along the border, or grain boundary. Instead of regular hexagons, the atoms are forced to find equilibrium by forming adjoining rings known as dislocations, with either five-plus-seven nodes or four-plus-eight nodes.
In graphene, which is generally considered the strongest material on Earth, these dislocations are weak points. But in MDS or other dichalcogenides, they have unique properties.
"It doesn't matter how you grow them," Yakobson said. "These misoriented areas eventually collide, and that's where you find topological defects. It turns out that – and I like this mechanistic metaphor – they squeeze magnetism out of nonmagnetic material."
In previous work, Yakobson found dislocations create atom-width conducting lines and dreidel-shaped polyhedra in MDS. This time, the team dug deeper to find that dislocation cores turn magnetic where they force spinning electrons to align in ways that don't cancel each other out, as they do in a flawless lattice. The strength of the magnets depends on the angle of the boundary and rises with the number of dislocations necessary to keep the material energetically stable.
"Every electron has charge and spin, both of which can carry information," Zhang said. "But in conventional transistors, we only exploit the charge, as in field-effect transistors. For newly emerged spintronic devices, we need to control both charge and spin for enhanced efficiency and enriched functions."
"Our work suggests a new degree of freedom -- a new controlling knob -- for electronics that use MDS," Yakobson said. "The ability to control the magnetic properties of this 2-D material makes it superior to graphene in certain respects."
He said the dislocation rings of four and eight atoms are not energetically favored in graphene and unlikely to occur there. But in the materials that mix two elements, certain grain boundary configurations will very likely create conditions where similar elements, wishing to avoid contact with each other, will instead bond with their chemical opposites.
"The system avoids mono-elemental bonds," Yakobson said. "The chemistry doesn't like it, so four-eight offers a benefit." Those defects are also the strongest sources of magnetism at certain grain boundary angles, he said; at some angles, the boundaries become ferromagnetic.
The team proved its theory through computer models designed to isolate and control the effects of the nanoribbons' edges and grain boundary dipoles that could skew the results. They also determined that grain boundary angles between 13 and 32 degrees force a progressive overlap between the dislocations' spins. With sufficient overlap, the spins become magnetically coupled and broaden into electronic bands that support spin-polarized charge transport along the boundary.
Now, Yakobson said, "The challenge is to find a way to experimentally detect these things. It's quite difficult to resolve it at this spatial resolution, especially when some of the experimental methods, like electron beams, would destroy the material."
Co-authors of the paper are Rice postdoctoral researcher Xiaolong Zou and Vincent Crespi, distinguished professor of physics, materials science and engineering, and chemistry at The Pennsylvania State University. Yakobson is Rice's Karl F. Hasselmann Professor of Mechanical Engineering and Materials Science, a professor of chemistry and a member of the Richard E. Smalley Institute for Nanoscale Science and Technology.
A U.S. Army Research Office Multidiscipline University Research Initiative grant, the National Science Foundation and the Robert Welch Foundation supported the research. Computations were performed on the Data Analysis and Visualization Cyberinfrastructure supercomputer administered by Rice's Ken Kennedy Institute for Information Technology.
Read the abstract at http://pubs.acs.org/doi/abs/10.1021/nn4052887
This news release can be found online at http://news.rice.edu/2013/11/13/nano-magnets-arise-at-2-d-boundaries/
Follow Rice News and Media Relations via Twitter @RiceUNewsRelated Materials:
Atomic dislocations can become magnetically charged when two-dimensional sheets of molybdenum disulfide and other dichalcogenides meet at an angle, according to calculations by theorists at Rice University. The grain boundaries force atoms out of their hexagonal patterns (left) and keep electron spins from canceling each other out, creating nanoscale magnetic fields (right, in blue) in the process. (Credit: Zhuhua Zhang/Rice University)
In a perfect sheet of molybdenum disulfide, at left, sulfur (yellow) atoms and molybdenum (blue) atoms appear in a perfect hexagonal pattern when seen from above, though the sulfur atoms float just above and below the molybdenum layer. When two sheets join at an angle, right, dislocations disrupt the hexagons. At those points, according to new research at Rice University, magnetic fields can form. The discovery may boost research into spintronics for electronics and computing. (Credit: Zhuhua Zhang/Rice University)
Located on a 300-acre forested campus in Houston, Rice University is consistently ranked among the nation's top 20 universities by U.S. News & World Report. Rice has highly respected schools of Architecture, Business, Continuing Studies, Engineering, Humanities, Music, Natural Sciences and Social Sciences and is home to the Baker Institute for Public Policy. With 3,708 undergraduates and 2,374 graduate students, Rice's undergraduate student-to-faculty ratio is 6-to-1. Its residential college system builds close-knit communities and lifelong friendships, just one reason why Rice has been ranked No. 1 for best quality of life multiple times by the Princeton Review and No. 2 for "best value" among private universities by Kiplinger's Personal Finance. To read "What they're saying about Rice," go to http://tinyurl.com/AboutRiceU.
David Ruth | EurekAlert!
Supercomputers without waste heat
07.12.2018 | Universität Konstanz
DF-PGT, now possible through massive sequencing techniques
06.12.2018 | Universitat Autonoma de Barcelona
What if a sensor sensing a thing could be part of the thing itself? Rice University engineers believe they have a two-dimensional solution to do just that.
Rice engineers led by materials scientists Pulickel Ajayan and Jun Lou have developed a method to make atom-flat sensors that seamlessly integrate with devices...
Scientists at the University of Stuttgart and the Karlsruhe Institute of Technology (KIT) succeed in important further development on the way to quantum Computers.
Quantum computers one day should be able to solve certain computing problems much faster than a classical computer. One of the most promising approaches is...
New Project SNAPSTER: Novel luminescent materials by encapsulating phosphorescent metal clusters with organic liquid crystals
Nowadays energy conversion in lighting and optoelectronic devices requires the use of rare earth oxides.
Scientists have discovered the first synthetic material that becomes thicker - at the molecular level - as it is stretched.
Researchers led by Dr Devesh Mistry from the University of Leeds discovered a new non-porous material that has unique and inherent "auxetic" stretching...
Scientists from the Theory Department of the Max Planck Institute for the Structure and Dynamics of Matter (MPSD) at the Center for Free-Electron Laser Science (CFEL) in Hamburg have shown through theoretical calculations and computer simulations that the force between electrons and lattice distortions in an atomically thin two-dimensional superconductor can be controlled with virtual photons. This could aid the development of new superconductors for energy-saving devices and many other technical applications.
The vacuum is not empty. It may sound like magic to laypeople but it has occupied physicists since the birth of quantum mechanics.
06.12.2018 | Event News
03.12.2018 | Event News
28.11.2018 | Event News
07.12.2018 | Life Sciences
07.12.2018 | Materials Sciences
07.12.2018 | Physics and Astronomy