Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

First Atomic-Scale Real-Time Movies of Platinum Nanocrystal Growth in Liquids

20.04.2012
Berkeley Scientists Create Graphene Liquid Cells for Electron Microscopy Studies of Nanocrystal Formation

They won’t be coming soon to a multiplex near you, but movies showing the growth of platinum nanocrystals at the atomic-scale in real-time have blockbuster potential.

A team of scientists with the Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California (UC) Berkeley has developed a technique for encapsulating liquids of nanocrystals between layers of graphene so that chemical reactions in the liquids can be imaged with an electron microscope. With this technique, movies can be made that provide unprecedented direct observations of physical, chemical and biological phenomena that take place in liquids on the nanometer scale.

“Watching real-time chemical reactions in liquids at the atomic-scale is a dream for chemists and physicists,” says Jungwon Park, a member of the team who holds joint appointments with Berkeley Lab’s Materials Sciences Division and UC Berkeley’s chemistry department. “Using our new graphene liquid cell, we’re able to capture a small amount of liquid sample under a high vacuum condition for taking real-time movies of nanoparticle growth reactions. Since graphene is chemically inert and extremely thin, our liquid cell provides realistic sample conditions for achieving high resolution and contrast.”

Park was the lead author, along with Jong Min Yuk, of a paper in the journal Science that describes this research titled “High-Resolution EM of Colloidal Nanocrystal Growth Using Graphene Liquid Cells.” The research was done as a collaboration between the research groups of Paul Alivisatos, director of Berkeley Lab and UC Berkeley’s Larry and Diane Bock Professor of Nanotechnology, and Alex Zettl, who holds joint appointments with Berkeley Lab’s Materials Sciences Division and UC Berkeley’s Physics Department where he directs the Center of Integrated Nanomechanical Systems. Both are corresponding authors of the Science paper along with Jeong Yong Lee of Korea’s Advanced Institute of Science and Technology (KAIST). Other authors were Peter Ercius, Kwanpyo Kim, Daniel Hellebusch and Michael Crommie.

In using a beam of electrons rather than a beam of light for illumination and magnification, electron microscopes can “see” objects hundreds and even thousands of times smaller than what can be resolved with an optical microscope. However, electron microscopes can only operate in a high vacuum as molecules in the air disrupt the electron beam. Since liquids evaporate in high vacuum, liquid samples must be hermetically sealed in special solid containers – called cells – with a viewing window before they can be imaged in an electron microscope. Until now, such liquid cells have featured viewing windows made from silicon nitride or silicon oxide. While this has permitted studies of some nanoscale phenomena in liquids, the silicon-based cell windows are too thick to allow strong penetration by the electron beam and this has limited resolution to only a few nanometers. In addition to not allowing true atomic-resolution, the thick silicon-based cell windows also appear to perturb the natural state of the liquid or sample suspended in the liquid.

“Graphene is single carbon atom in thickness, making it one of the thinnest known membranes,” says Park, a member of the Alivisatos’ research group. “It does not scatter the electron beam but lets it pass through. Furthermore, graphene is also very strong and impermeable, as well as being chemically non-reactive, and this helps protects the sample in the liquid cell from the high-energy beam of an electron microscope.”

To make their graphene liquid cell, the Alivisatos-Zettl collaboration encapsulated a platinum growth solution between two laminated graphene layers that were suspended over holes in a conventional transmission electron microscope (TEM) grid. The graphene was grown on a copper foil substrate via chemical vapor deposition and then directly transferred onto a gold TEM mesh with a perforated amorphous carbon support. The platinum growth solution was pipetted directly atop two graphene-coated TEM grids facing in opposite directions.

“Upon wetting the system, the solution wicks between the graphene and amorphous carbon layers, allowing one of the graphene sheets to detach from its associated TEM grid,” says co-author Kim, a member of the Zettl research group. “Because the van derWaals interaction between graphene sheets is relatively strong, liquid droplets ranging in thickness from six to 200 nanometers can be securely trapped in a pocket or blister between the graphene sheets.”

To test their graphene liquid cells, the collaborators used the world’s most powerful electron microscope, the TEAM I at the National Center for Electron Microscopy (NCEM), which is housed at Berkeley Lab. TEAM stands for Transmission Electron Aberration-corrected Microscope and the TEAM I instrument is capable of producing images with a half-angstrom resolution, which is less than the diameter of a single hydrogen atom. With TEAM I and their new graphene liquid cells, the Alivisatos-Zettl collaboration was able to directly observe at the highest resolution possible to date and with minimal sample perturbation, the growth of nanocrystals of platinum, one of the best metal catalysts in use today.

“Direct atomic-resolution imaging allowed us to visualize critical steps in the platinum nanocrystal growth process, including a host of previously unexpected phenomena, such as site-selective coalescence, structural reshaping after coalescence, and surface faceting,” says Park.

Three years ago, Park and Alivisatos were part of a team that used another TEM at NCEM and liquid cells featuring silicon nitride windows to record the first ever images of colloidal platinum nanocrystals growing in solution at subnanometer resolution. Their results showed that while some crystals in solution grew steadily in size via classical nucleation and aggregation – meaning molecules collide and join together – others grew in fits and spurts, driven by “coalescence events,” in which small crystals randomly collide and fuse together into larger crystals. Despite their distinctly different growth trajectories, these two processes ultimately yielded nanocrystals of approximately the same size and shape.

“In that earlier study, however, we lacked the resolution to fully understand how these nanoparticles merge and reorganize their shape in the coalescence growth trajectory,” Park says. “With the graphene liquid cells we used in this study, we were able to resolve the oriented coalescence along a specific crystal direction and see how they reorganized their overall structure into a final shape.”

With the graphene liquid cells and the greater resolution of TEAM I, the Alivisatos-Zettl collaboration was able to observe that most coalescence events proceed along the same crystallographic direction – the {111} plane of the crystal. This points to a specific nanocrystal orientation for coalescence not seen before in metal nanoparticles.

“We were able to resolve atomistic arrangement at the moment two of the platinum nanoparticles merged and visualize oriented attachment, a phenomenon known to be one the of major growth mechanisms of anisotropic particles,” Park says. “This oriented coalescence could be one of the formation mechanisms behind another phenomenon we observed, twin boundaries, which occurs when nanoparticles merge together along the same {111} direction but on a mirror plane in the crystal.”

In the future, the collaborators plan to use their graphene liquid cells to study the growth of many different types of nanoparticles, including metals, semiconductors and other useful materials. The graphene cells could also be applied to biomaterials, such as DNA and proteins, which exist naturally in solution.

“The one atom thick graphene membranes are ideal for liquid encapsulation,” says co-author Ercius, the NCEM staff member who ran the TEAM I microscope for this study. “When combined with the aberration corrected imaging of TEAM I, we can reach the ultimate in image contrast and resolution for in-situ liquid experiments. The graphene liquid cell technique could be easily applied to other electron microscopes and I think it will become instrumental in answering questions regarding the synthesis of materials in liquids at the atomic scale.”

This work was supported by the U.S. Department of Energy’s Office of Science, and in part through the National Research Foundation of Korea.

Lawrence Berkeley National Laboratory addresses the world’s most urgent scientific challenges by advancing sustainable energy, protecting human health, creating new materials, and revealing the origin and fate of the universe. Founded in 1931, Berkeley Lab’s scientific expertise has been recognized with 13 Nobel prizes. The University of California manages Berkeley Lab for the U.S. Department of Energy’s Office of Science.

Lynn Yarris | EurekAlert!
Further information:
http://www.lbl.gov
http://newscenter.lbl.gov/feature-stories/2012/04/19/atomic-scale-real-time-movies-of-nanocrystal-growth-in-liquids/

More articles from Physics and Astronomy:

nachricht Excitation of robust materials
07.07.2020 | Christian-Albrechts-Universität zu Kiel

nachricht FAST detects neutral hydrogen emission from extragalactic galaxies for the first time
02.07.2020 | Chinese Academy of Sciences Headquarters

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Excitation of robust materials

Kiel physics team observed extremely fast electronic changes in real time in a special material class

In physics, they are currently the subject of intensive research; in electronics, they could enable completely new functions. So-called topological materials...

Im Focus: Electrons in the fast lane

Solar cells based on perovskite compounds could soon make electricity generation from sunlight even more efficient and cheaper. The laboratory efficiency of these perovskite solar cells already exceeds that of the well-known silicon solar cells. An international team led by Stefan Weber from the Max Planck Institute for Polymer Research (MPI-P) in Mainz has found microscopic structures in perovskite crystals that can guide the charge transport in the solar cell. Clever alignment of these "electron highways" could make perovskite solar cells even more powerful.

Solar cells convert sunlight into electricity. During this process, the electrons of the material inside the cell absorb the energy of the light....

Im Focus: The lightest electromagnetic shielding material in the world

Empa researchers have succeeded in applying aerogels to microelectronics: Aerogels based on cellulose nanofibers can effectively shield electromagnetic radiation over a wide frequency range – and they are unrivalled in terms of weight.

Electric motors and electronic devices generate electromagnetic fields that sometimes have to be shielded in order not to affect neighboring electronic...

Im Focus: Gentle wall contact – the right scenario for a fusion power plant

Quasi-continuous power exhaust developed as a wall-friendly method on ASDEX Upgrade

A promising operating mode for the plasma of a future power plant has been developed at the ASDEX Upgrade fusion device at Max Planck Institute for Plasma...

Im Focus: ILA Goes Digital – Automation & Production Technology for Adaptable Aircraft Production

Live event – July 1, 2020 - 11:00 to 11:45 (CET)
"Automation in Aerospace Industry @ Fraunhofer IFAM"

The Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM l Stade is presenting its forward-looking R&D portfolio for the first time at...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

VideoLinks
Industry & Economy
Event News

Contact Tracing Apps against COVID-19: German National Academy Leopoldina hosts international virtual panel discussion

07.07.2020 | Event News

International conference QuApps shows status quo of quantum technology

02.07.2020 | Event News

Dresden Nexus Conference 2020: Same Time, Virtual Format, Registration Opened

19.05.2020 | Event News

 
Latest News

Quick notes in the genome

07.07.2020 | Life Sciences

Limitations of Super-Resolution Microscopy Overcome

07.07.2020 | Life Sciences

Put into the right light - Reproducible and sustainable coupling reactions

07.07.2020 | Life Sciences

VideoLinks
Science & Research
Overview of more VideoLinks >>>