"What's important is that you can process all kinds of available biomass -- wood chips, switch grass, corn stover, rice husks, wheat straw …," said Rakesh Agrawal, the Winthrop E. Stone Distinguished Professor of Chemical Engineering.
The approach sidesteps a fundamental economic hurdle in biofuels: Transporting biomass is expensive because of its bulk volume, whereas liquid fuel from biomass is far more economical to transport, he said.
"Material like corn stover and wood chips has low energy density," Agrawal said. "It makes more sense to process biomass into liquid fuel with a mobile platform and then take this fuel to a central refinery for further processing before using it in internal combustion engines."
The new method, called fast-hydropyrolysis-hydrodeoxygenation, works by adding hydrogen into the biomass-processing reactor. The hydrogen for the mobile plants would be derived from natural gas or the biomass itself. However, Agrawal envisions the future use of solar power to produce the hydrogen by splitting water, making the new technology entirely renewable.
The method, which has the shortened moniker of H2Bioil -- pronounced H Two Bio Oil -- has been studied extensively through modeling, and experiments are under way at Purdue to validate the concept.
Findings are detailed in a research paper appearing online in June in the journal Environmental Science & Technology. The paper was written by former chemical engineering doctoral student Navneet R. Singh, Agrawal, chemical engineering professor Fabio H. Ribeiro and W. Nicholas Delgass, the Maxine Spencer Nichols Professor of Chemical Engineering.
The article can be accessed online at http://pubs.acs.org/doi/abs/10.1021/es100316z
Agrawal, Ribeiro and Delgass are developing reactors and catalysts to experimentally demonstrate the concept. Another paper by Agrawal and Singh addressing various biofuels processes, including fast-hydropyrolysis-hydrodeoxygenation, also appeared in June in the Annual Review of Chemical and Biomolecular Engineering. This paper can be accessed online at http://arjournals.annualreviews.org/eprint/gmGjKYuY7iQexh8Dd7XT/full/10.1146/annurev-chembioeng-073009-100955
The Environmental Science & Technology paper outlines the process, showing how a portion of the biomass is used as a source of hydrogen to convert the remaining biomass to liquid fuel.
"Another major thrust of this research is to provide guidelines on the potential liquid-fuel yield from various self-contained processes and augmented processes, where part of the energy comes from non-biomass sources such as solar energy and fossil fuel such as natural gas," said Singh, who is now a researcher working at Bayer CropScience.
The new method would produce about twice as much biofuel as current technologies when hydrogen is derived from natural gas and 1.5 times the liquid fuel when hydrogen is derived from a portion of the biomass itself.
Biomass along with hydrogen will be fed into a high-pressure reactor and subjected to extremely fast heating, rising to as hot as 500 degrees Celsius, or more than 900 degrees Fahrenheit in less than a second. The hydrogen containing gas is to be produced by "reforming" natural gas, with the hot exhaust directly fed into the biomass reactor.
"The biomass will break down into smaller molecules in the presence of hot hydrogen and suitable catalysts," Agrawal said. "The reaction products will then be subsequently condensed into liquid oil for eventual use as fuel. The uncondensed light gases such as methane, carbon monoxide, hydrogen and carbon dioxide, are separated and recycled back to the biomass reactor and the reformer."
Purdue has filed a patent application on the method.
The general concept of combining biomass and carbon-free hydrogen to increase the liquid fuel yield has been pioneered at Purdue. The researchers previously invented an approach called a "hybrid hydrogen-carbon process," or H2CAR. A news release describing the process is at http://news.uns.purdue.edu/x/2007a/070314AgrawalBiomass.html
Both H2CAR and H2Bioil use additional hydrogen to boost the liquid-fuel yield. However, H2Bioil is more economical and mobile than H2CAR, Singh said.
"It requires less hydrogen, making it more economical," he said. "It is also less capital intensive than conventional processes and can be built on a smaller scale, which is one of the prerequisites for the conversion of the low-energy density biomass to liquid fuel. So H2Bioil offers a solution for the interim time period, when crude oil prices might be higher but natural gas and biomass to supply hydrogen to the H2Bioil process might be economically competitive."
The research was funded by the U.S. Department of Energy, the National Science Foundation and the U.S. Air Force Office of Scientific Research, and is affiliated with the Energy Center at Purdue's Discovery Park.
Writer: Emil Venere, (765) 494-4709, email@example.com
Sources: Rakesh Agrawal, (765) 494-2257, firstname.lastname@example.orgNavneet R. Singh, email@example.com
Emil Venere | EurekAlert!
Zebrafish's near 360 degree UV-vision knocks stripes off Google Street View
22.06.2018 | University of Sussex
New cellular pathway helps explain how inflammation leads to artery disease
22.06.2018 | Cedars-Sinai Medical Center
In a recent publication in the renowned journal Optica, scientists of Leibniz-Institute of Photonic Technology (Leibniz IPHT) in Jena showed that they can accurately control the optical properties of liquid-core fiber lasers and therefore their spectral band width by temperature and pressure tuning.
Already last year, the researchers provided experimental proof of a new dynamic of hybrid solitons– temporally and spectrally stationary light waves resulting...
Scientists from the University of Freiburg and the University of Basel identified a master regulator for bone regeneration. Prasad Shastri, Professor of...
Moving into its fourth decade, AchemAsia is setting out for new horizons: The International Expo and Innovation Forum for Sustainable Chemical Production will take place from 21-23 May 2019 in Shanghai, China. With an updated event profile, the eleventh edition focusses on topics that are especially relevant for the Chinese process industry, putting a strong emphasis on sustainability and innovation.
Founded in 1989 as a spin-off of ACHEMA to cater to the needs of China’s then developing industry, AchemAsia has since grown into a platform where the latest...
The BMBF-funded OWICELLS project was successfully completed with a final presentation at the BMW plant in Munich. The presentation demonstrated a Li-Fi communication with a mobile robot, while the robot carried out usual production processes (welding, moving and testing parts) in a 5x5m² production cell. The robust, optical wireless transmission is based on spatial diversity; in other words, data is sent and received simultaneously by several LEDs and several photodiodes. The system can transmit data at more than 100 Mbit/s and five milliseconds latency.
Modern production technologies in the automobile industry must become more flexible in order to fulfil individual customer requirements.
An international team of scientists has discovered a new way to transfer image information through multimodal fibers with almost no distortion - even if the fiber is bent. The results of the study, to which scientist from the Leibniz-Institute of Photonic Technology Jena (Leibniz IPHT) contributed, were published on 6thJune in the highly-cited journal Physical Review Letters.
Endoscopes allow doctors to see into a patient’s body like through a keyhole. Typically, the images are transmitted via a bundle of several hundreds of optical...
13.06.2018 | Event News
08.06.2018 | Event News
05.06.2018 | Event News
22.06.2018 | Materials Sciences
22.06.2018 | Earth Sciences
22.06.2018 | Life Sciences