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Atomic Design by Water

23.02.2018

Scientists at the Max-Planck-Institut für Eisenforschung show how geometric structures at surfaces can be formed with atomic precision by water

A central element in such diverse technological problems as corrosion protection, battery materials or hydrogen production via electrolysis or fuel cells is the contact between two conducting elements – the electrolyte and the solid electrode at which a voltage is applied.


Water shapes the surface which is completely smooth in vacuum. Geometric structures, as the triangle on the left appear under the influence of water. Grey represent zinc, red oxygen and blue hydrogen

Suhyun Yoo, Max-Planck-Institut für Eisenforschung GmbH

Despite its importance for a multitude of key technologies hardly anything is known about the atomistic structure of the interface between the electrode and the electrolyte. In particular the atomic structure of the solid electrode has a decisive impact on the chemical reactions taking place at the interface.

The ability to selectively modify the structure of the surface at the scale of individual atoms would open completely new possibilities target and influence central chemical reactions.

Scientist from the Computational Materials Design department of the Max-Planck-Institut für Eisenforschung have come a great deal closer to achieving this goal. Within the framework of the Excellence-cluster RESOLV, a joint research initiative of seven research institutions in the Ruhr area, an unexpected phenomenon was found with the help of highly accurate quantum mechanical methods and powerful supercomputers.

Previous studies of metallic surfaces repeatedly show that the structure of the surface hardly changes in contact with a liquid electrolyte. The researchers were therefore very surprised when they brought a semi-conducting surface into contact with an electrolyte.

“We were completely surprised to see the formation of structures, which are unstable in the absence of water and are also not observed”, says Dr. Mira Todorova, head of the Electrochemistry and Corrosion group. The department head Prof. Neugebauer is equally enthusiastic:

“Our simulation methods allowed us not only to find a completely new and unexpected phenomenon, but also to identify the underlying mechanisms. This opens up totally new possibilities to shape and design surfaces with atomic precision.”

These studies not only offer new insights into future-oriented technologies, but also provide a new perception of a question intensely discussed in geology: The cause of the enhanced crack formation in minerals when they are exposed to a humid environment.

The work was published in the journal Physical Review Letters.

Original publication:
S. Yoo, M. Todorova and J. Neugebauer
Selective solvent-induced stabilization of polar oxide surfaces in an electrochemical environment
Physical Review Letters 120, 066101 (2018)
DOI: 10.1103/PhysRevLett.120.066101
(Editors suggestion)

Authors of the press release: M. Todorova, J. Neugebauer

Weitere Informationen:

https://www.mpie.de/3757594/atomic-design-by-water

Yasmin Ahmed Salem M.A. | Max-Planck-Institut für Eisenforschung GmbH

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