The research is reported in an article entitled, “Intercalation Pathway in Many-Particle LiFePO4 Electrode Revealed by Nanoscale State-of-Charge Mapping” in the journal Nano Letters, 2013, 13 (3), pp 866-872. Authors include Sandia physicist Farid El Gabaly and William Chueh of Stanford University.
LFP, a natural mineral of the olivine family, is one of the newer materials being used in lithium-ion batteries and is known to be safer and longer-lasting than the lithium cobalt oxide (LiCoO2) compound used in smart phones, laptops and other consumer electronics.
While LFP material is intriguing to researchers and battery manufacturers for those reasons, the process by which lithium ions move in and out of LFP as the battery stores and releases its energy is not well understood. This has proven to be a barrier to the material’s widespread adoption.
Cathode materials like LFP are critical in the search for higher-capacity, long-life, lithium-ion batteries for applications where batteries can’t be replaced as easily or as often as they are in consumer electronics. Larger applications where lithium cobalt oxide cells eventually could be replaced by LFP batteries include electric vehicles and aircraft.
Popcorn-like particle movements seen via microscopy technique
By observing complete battery cross-sections, the researchers have provided key insights on a controversy over the process that limits the battery charging and discharging rates.
Previous attempts to optimize the charging/discharging speed have included coating the particles to increase their electrical conductivity and reducing particle size to speed up their transformation, but have overlooked the initiation process that may well be the critical rate-limiting step in the way that lithium moves from a particle’s exterior to its interior.
By using X-ray microscopy to examine ultrathin slices of a commercial-grade battery, Sandia researchers found evidence that charging and discharging in LFP is limited by the initiation of phase transformation, or nucleation, and is unaffected by particle size.
The LFP electrode forms a mosaic of homogeneous particles that are in either a lithium-rich or lithium-poor state. The Sandia research confirms the particle-by-particle, or mosaic, pathway of phase transformations due to insertion of lithium ions into the cathode. The findings contradict previous assumptions.
“One propagation theory said that when all the particles were exposed to lithium, they would all start discharging slowly together in a concurrent phase transformation,” said El Gabaly. “We’ve now seen that the process is more like popcorn. One particle is completely discharged, then the next, and they go one-by-one like popcorn, absorbing the lithium.”
Slicing-and-dicing helps understanding of lithium-ion charging
Lithium ions move in and out of battery electrode materials as they are charged and discharged. When a rechargeable lithium-ion battery is charged, an external voltage source extracts lithium ions from the cathode (positive electrode) material, in a process known as “delithiation.” The lithium ions move through the electrolyte and are inserted (intercalated) in the anode (negative electrode) material, in a process known as “lithiation.” The same process happens in reverse when discharging energy from the battery.
“We observed that there were only two phases, where the particle either had lithium or it didn’t,” said El Gabaly. “In many previous studies, researchers have focused on understanding the charging process inside one particle.”
El Gabaly and his Sandia colleagues took a slice just a bit thicker than a human hair from a commercial-grade battery, just one layer of LFP particles, and mapped the locations of the lithium in about 450 particles when the battery was at different states of charge.
“Our discovery was made possible by mapping the lithium in a relatively large particle ensemble,” he said.
Many tools, facilities contribute to research
The researchers were able to build a commercial-grade coin-cell battery from raw materials using Sandia’s cell battery prototyping facility in New Mexico, which is the largest Department of Energy facility equipped to manufacture small lots of lithium-ion cells. The battery was then charged, tested for normal behavior, and disassembled at Sandia’s Livermore, Calif., facility through a new method of slicing layers that conserved the spatial arrangement from the cathode to the anode.
The Sandia researchers went to Lawrence Berkeley National Laboratory to characterize the materials with state-of-the-art scanning transmission X-ray microscopy (STXM) at the Advanced Light Source (ALS), and then returned to Sandia’s California site for study by transmission electron microscopy (TEM).
“The X-ray spectroscopy from the ALS tells you what’s inside an individual particle, or where the lithium is, but it has low spatial resolution. We needed the electron microscopy of the same slice to tell us where all the particles were distributed across the entire layer of the battery,” said Chueh, a former Sandia Truman Fellow who is lead author of the journal article and an assistant professor and center fellow at the Precourt Institute of Energy at Stanford University.
Sandia’s research team and others presented their technical findings at the recent Materials Research Society Spring Meeting in San Francisco. As a result of that presentation, El Gabaly said, other researchers are using the results to validate theoretical models. The team also may partner with industry, as one company has already indicated a strong interest in Sandia conducting similar studies on different, more complex battery materials.
The research team at Sandia has been funded internally, including support from the Sandia Truman Fellowship in National Security Science and Engineering, and by the Department of Energy’s Office of Science, which also supports the ALS.
Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin company, for the U.S. Department of Energy’s National Nuclear Security Administration. With main facilities in Albuquerque, N.M., and Livermore, Calif., Sandia has major R&D responsibilities in national security, energy and environmental technologies and economic competitiveness.
Sandia news media contact: Mike Janes, email@example.com, (925) 294-2447
Mike Janes | Newswise
Further reports about: > battery > LfP > LifePO4 > Lithium-Ion > Security Forum > X-ray microscopy > cobalt oxide > consumer electronics > electric vehicle > electrode material > electron microscopy > laboratories > lithium cobalt oxide > lithium ions > lithium-ion batteries > raw material > smart phone
A smart safe rechargeable zinc ion battery based on sol-gel transition electrolytes
20.07.2018 | Science China Press
Future electronic components to be printed like newspapers
20.07.2018 | Purdue University
A new manufacturing technique uses a process similar to newspaper printing to form smoother and more flexible metals for making ultrafast electronic devices.
The low-cost process, developed by Purdue University researchers, combines tools already used in industry for manufacturing metals on a large scale, but uses...
For the first time ever, scientists have determined the cosmic origin of highest-energy neutrinos. A research group led by IceCube scientist Elisa Resconi, spokesperson of the Collaborative Research Center SFB1258 at the Technical University of Munich (TUM), provides an important piece of evidence that the particles detected by the IceCube neutrino telescope at the South Pole originate from a galaxy four billion light-years away from Earth.
To rule out other origins with certainty, the team led by neutrino physicist Elisa Resconi from the Technical University of Munich and multi-wavelength...
For the first time a team of researchers have discovered two different phases of magnetic skyrmions in a single material. Physicists of the Technical Universities of Munich and Dresden and the University of Cologne can now better study and understand the properties of these magnetic structures, which are important for both basic research and applications.
Whirlpools are an everyday experience in a bath tub: When the water is drained a circular vortex is formed. Typically, such whirls are rather stable. Similar...
Physicists working with Roland Wester at the University of Innsbruck have investigated if and how chemical reactions can be influenced by targeted vibrational excitation of the reactants. They were able to demonstrate that excitation with a laser beam does not affect the efficiency of a chemical exchange reaction and that the excited molecular group acts only as a spectator in the reaction.
A frequently used reaction in organic chemistry is nucleophilic substitution. It plays, for example, an important role in in the synthesis of new chemical...
Optical spectroscopy allows investigating the energy structure and dynamic properties of complex quantum systems. Researchers from the University of Würzburg present two new approaches of coherent two-dimensional spectroscopy.
"Put an excitation into the system and observe how it evolves." According to physicist Professor Tobias Brixner, this is the credo of optical spectroscopy....
13.07.2018 | Event News
12.07.2018 | Event News
03.07.2018 | Event News
20.07.2018 | Power and Electrical Engineering
20.07.2018 | Information Technology
20.07.2018 | Materials Sciences