A paperlike battery electrode developed by a Kansas State University engineer may improve tools for space exploration or unmanned aerial vehicles.
Gurpreet Singh, associate professor of mechanical and nuclear engineering, and his research team created the battery electrode using silicon oxycarbide-glass and graphene.
The battery electrode has all the right characteristics. It is more than 10 percent lighter than other battery electrodes. It has close to 100 percent cycling efficiency for more than 1000 charge discharge cycles. It is made of low-cost materials that are byproducts of the silicone industry. And it functions at temperatures as low as minus 15 degrees C, which gives it numerous aerial and space applications.
The research appears in Nature Communications article "Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries."
Singh's research team has been exploring new material combinations for batteries and electrode design. It has been difficult to incorporate graphene and silicon into practical batteries because of challenges that arise at high mass loadings -- such as low capacity per volume, poor cycling efficiency and chemical-mechanical instability.
Singh's team has addressed these challenges by manufacturing a self-supporting and ready-to-go electrode that consists of a glassy ceramic called silicon oxycarbide sandwiched between large platelets of chemically modified graphene, or CMG. The electrode has a high capacity of approximately 600 miliampere-hours per gram -- 400 miliampere-hours per cubic centimeter -- that is derived from silicon oxycarbide. The paperlike design is made of 20 percent chemically modified graphene platelets.
"The paperlike design is markedly different from the electrodes used in present day batteries because it eliminates the metal foil support and polymeric glue -- both of which do not contribute toward capacity of the battery," Singh said.
The design that Singh's team developed saved approximately 10 percent in total weight of the cell. The result is a lightweight electrode capable of storing lithium-ion and electrons with near 100 percent cycling efficiency for more than 1000 charge discharge cycles. The most important aspect is that the material is able to demonstrate such performance at practical levels, Singh said.
The paper electrode cells also are able to deliver a capacity of 200 miliampere-hour per gram even when kept at minus 15 degrees C for about a month, which is quite remarkable considering that most batteries fail to perform at such low temperatures, Singh said.
"This suggests that rechargeable batteries from silicon-glass and graphene electrodes may also be suitable for unmanned aerial vehicles flying at high altitudes, or maybe even space applications," Singh said.
The silicon oxycarbide material itself is quite special, Singh said. It is prepared by heating a liquid resin to the point where it decomposes and transforms into sharp glasslike particles. The silicon, carbon and oxygen atoms get rearranged into random 3-D structure and any excess carbon precipitates out into cellular regions. Such an open 3-D structure creates large sites for reversible lithium storage and smooth channels for lithium-ion transportation. This structure and mechanism of lithium storage is different than crystalline silicon electrodes. Silicon oxycarbide electrodes are expected to be low cost because the raw material -- liquid resin -- is a byproduct of the silicone industry.
Moving forward, Singh and his team want to address practical challenges. Singh's goal is to produce this electrode material at even larger dimensions. For example, present-day pencil-cell batteries use graphite-coated copper foil electrodes that are more than one foot in length. The team also would like to perform mechanical bending tests to see how they affect performance parameters.
"Ultimately, we would like to work with industry to explore production of lithium-ion battery full-cells," Singh said. "Silicon oxycarbide can also be prepared by 3-D printing, which is another area of interest to us."
The research received funding from the National Science Foundation, including Singh's $500,000 CAREER award.
Other Kansas State University researchers involved include Lamuel David, 2015 doctoral graduate in mechanical engineering, Oak Ridge, Tennessee; Romil Bhandavat, 2013 doctoral graduate in mechanical engineering, Hillsboro, Oregon; and Uriel Barrera, 2015 bachelors graduate in mechanical engineering, Olathe.
Gurpreet Singh | EurekAlert!
Saving energy by taking a close look inside transistors
10.01.2019 | Friedrich-Alexander-Universität Erlangen-Nürnberg
Tandem Solar Cells – Record Efficiency for Silicon-based Multi-junction Solar Cell
08.01.2019 | Fraunhofer-Institut für Solare Energiesysteme ISE
Dead and alive at the same time? Researchers at the Max Planck Institute of Quantum Optics have implemented Erwin Schrödinger’s paradoxical gedanken experiment employing an entangled atom-light state.
In 1935 Erwin Schrödinger formulated a thought experiment designed to capture the paradoxical nature of quantum physics. The crucial element of this gedanken...
Cellulose obtained from wood has amazing material properties. Empa researchers are now equipping the biodegradable material with additional functionalities to produce implants for cartilage diseases using 3D printing.
It all starts with an ear. Empa researcher Michael Hausmann removes the object shaped like a human ear from the 3D printer and explains:
The phenomenon of so-called superlubricity is known, but so far the explanation at the atomic level has been missing: for example, how does extremely low friction occur in bearings? Researchers from the Fraunhofer Institutes IWM and IWS jointly deciphered a universal mechanism of superlubricity for certain diamond-like carbon layers in combination with organic lubricants. Based on this knowledge, it is now possible to formulate design rules for supra lubricating layer-lubricant combinations. The results are presented in an article in Nature Communications, volume 10.
One of the most important prerequisites for sustainable and environmentally friendly mobility is minimizing friction. Research and industry have been dedicated...
Just in time for Christmas, a Mars-analogue mission in Morocco, coordinated by the Robotics Innovation Center of the German Research Center for Artificial Intelligence (DFKI) as part of the SRC project FACILITATORS, has been successfully completed. SRC, the Strategic Research Cluster on Space Robotics Technologies, is a program of the European Union to support research and development in space technologies. From mid-November to mid-December 2018, a team of more than 30 scientists from 11 countries tested technologies for future exploration of Mars and Moon in the desert of the Maghreb state.
Close to the border with Algeria, the Erfoud region in Morocco – known to tourists for its impressive sand dunes – offered ideal conditions for the four-week...
Research opens doors in photonic quantum information processing, optical signal processing and microwave photonics
Researchers from the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) have developed a new integrated photonics platform that can...
16.01.2019 | Event News
14.01.2019 | Event News
12.12.2018 | Event News
17.01.2019 | Life Sciences
16.01.2019 | Life Sciences
16.01.2019 | Physics and Astronomy