Unlike the slow ferroelastic domain switching expected for ceramics, high-speed sub-microsecond ferroelastic domain switching and simultaneous lattice deformation are directly observed for the Pb(Zr0.4Ti0.6)O3 thin films. This exciting finding paves the way for high-frequency ultrafast electromechanical switches and sensors.
Piezo micro electro mechanical systems (piezoMEMS) are miniaturized devices exhibiting piezoelectricity, i.e., the appearance of an electric charge under applied mechanical stress. These devices have many diverse applications in energy harvesters, micropumps, sensors, inkjet printer heads, switches, and so on. In permanently polarized (ferroelectric) materials, ferroelastic domain switching affects the piezoelectric properties significantly, and this behavior can be exploited for piezoMEMS applications.
Pb(Zr1-xTix)O3 (PZT) thin films have excellent piezoelectric and ferroelectric properties; therefore, they are potential candidates for MEMS applications. Under an applied electric field, both lattice elongation and 90° ferroelastic domain switching are observed in tetragonal PZT thin films. In particular, non-180° ferroelastic domain switching has important implications for the future realization of high-performance piezoMEMS devices.
However, before the recent investigation, the speed of this 90° domain switching was unknown. In addition, the relationship between the speeds of the lattice deformation and ferroelastic domain switching had not been determined. To investigate these speeds, the research team led by Hiroshi Funakubo examined the switching behavior of Pb(Zr0.4Ti0.6)O3 thin films under applied rectangular electric field pulses.
To observe the changes in the lattice and the domain structure, time-resolved in situ synchrotron X-ray diffraction was carried out in synchronization with a high-speed pulse generator. These observations were performed at the BL13XU beamline at the SPring-8 synchrotron radiation facility. The electric field pulses were applied to the PZT thin films through Pt top electrodes, which were fabricated on top of the films.
Investigation of the diffraction peaks in the PZT thin films revealed elongation of the surface normal c-axis lattice parameter of the c-domain with a simultaneous decrease in the surface normal a-axis lattice parameter of the a-domain under the applied electric field. The intensities of the diffraction peaks also changed under the electric field. These observations provided direct evidence of 90° domain switching.
To determine the switching speed, the lattice elongation and domain switching behaviors were plotted as functions of time (Figure 1). These plots revealed that these processes were completed within 40 ns and occurred simultaneously in response to the applied electric field. The switching behavior was also shown to be perfectly repeatable.
The high-speed switching observed in these experiments was limited by the present electrical equipment, but is faster than that reported in previous studies. Further, this high-speed 90° switching is reversible and can be used to enhance the piezoelectric response in piezoMEMS devices by several tens of nanoseconds. Therefore, this finding is of considerable importance for the ongoing development of ultrafast electromechanical switches and sensors.
Yoshitaka Ehara, Shintaro Yasui, Takahiro Oikawa, Takahisa Shiraishi, Takao Shimizu, Hiroki Tanaka, Noriyuki Kanenko, Ronald Maran, Tomoaki Yamada, Yasuhiko Imai, Osami Sakata, Nagarajan Valanoor, and Hiroshi Funakubo*,
In-situ observation of ultrafast 90° domain switching under application of an electric field in (100)/ (001)-oriented tetragonal epitaxial Pb(Zr0.4Ti0.6)O3 thin films, Scientific Reports, 10.1038/s41598-017-09389-6
1. Department of Innovative and Engineered Material, Tokyo Institute of Technology
2. Laboratory for Materials and Structures, Tokyo Institute of Technology
3. Institute for Materials Research, Tohoku University
4. Materials Research Center for Element Strategy, Tokyo Institute of Technology
5. School of Materials and Chemical Technology, Tokyo Institute of Technology
6. School of Materials Science and Engineering, University of New South Wales
7. Department of Materials, Physics and Energy Engineering, Nagoya University
8. PRESTO, Japan Science and Technology Agency
9. Japan Synchrotron Radiation Research Institute (JASRI)
10. Synchrotron X-ray Station at SPring-8 and Synchrotron X-ray Group, National Institute for Materials Science (NIMS)
*Corresponding author's email: email@example.com
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Nagoya University has a history of 146 years, with its roots in a temporary medical school/hospital established in 1871. Once the last university to become a Japanese Imperial University in 1939, our University has since then continued to achieve significant growth. We've maintained a tradition of having a free and vibrant academic culture, and after setting a high basic objective in the 2000 Nagoya University Academic Charter, we have worked hard to achieve that objective. The fact that 6 out of the 16 Japanese Nobel laureates who were awarded in the 21st century clearly shows that our research abilities are top class on a global scale. Nagoya University, throughout its long history, has produced many leaders in various areas of society and introduced them to the world, and thus contributed to the development and growth of not only Japan but also the world.
About the National Institute for Materials Science (NIMS)
NIMS is Japan's only national research institute specializing in R&D related to materials science. It was founded in April 2001 by merging the National Research Institute for Metals and the National Institute for Research in Inorganic Materials, under the jurisdiction of the Ministry of Education, Culture, Sports, Science and Technology (MEXT). Within its fourth mid- to long-term project, which was started in April 2016, NIMS is further strengthening its research capabilities and international competitiveness. Its core goal is to "speedily leverage research results for the good of society".
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