Joseph Wang has successfully printed thick-film electrochemical sensors directly on flexible wetsuit material, paving the way for nano devices to detect underwater explosives or ocean contamination.
“We have a long-term interest in on-body electrochemical monitoring for medical and security applications,” said Wang, a professor in the Department of NanoEngineering in UC San Diego’s Jacobs School of Engineering. “In the past three years we’ve been working on flexible, printable sensors, and the capabilities of our group made it possible to extend these systems for use underwater.”
Wang notes that some members of his team – including electrical-engineering graduate student Joshua Windmiller – are surfers. Given the group’s continued funding from the U.S. Navy, and its location in La Jolla, it was a logical leap to see if it would be possible to print sensors on neoprene, the synthetic-rubber fabric typically used in wetsuits for divers and surfers.
The result: development of “wearable electrochemical sensors for in situ analysis in marine environments.” The paper, published last month in the journal Analyst*, was co-authored by UCSD’s Wang, Windmiller and visiting scholar Gabriela Valdés-Ramírez from Mexico, as well as Michael J. Schöning and Kerstin Malzahn from the Institute of Nano- and Biotechnologies of Germany’s Aachen University of Applied Sciences. (Malzahn is currently a visiting graduate student at UCSD from the German university.)
UCSD has a full U.S. patent pending on the technology, and has begun talks on licensing the system to a Fortune 500 company.
Wang’s 20-person research group is a world leader in the field of printable sensors. But to prove that the sensors printed on neoprene could take a beating and continue working, some of Wang’s colleagues took to the water.
“Anyone trying to take chemical readings under the water will typically have to carry a portable analyzer if they want to detect pollutants,” said Wang, whose group is based in the California Institute for Telecommunications and Information Technology (Calit2) at UCSD. “Instead, we printed a three-electrode sensor directly on the arm of the wetsuit, and inside the neoprene we embedded a 3-volt battery and electronics.”
The electrochemical sensors are based on applying voltage to drive a reduction-oxidation (redox) reaction in a target threat or contaminant – which loses or gains electrons – then measuring the current output. The wearable microsystem provides a visual indication and alert if the levels of harmful contaminants or explosives exceed a pre-defined threshold. It does so by mixing different enzymes into the carbon ink layer before printing on the fabric. (For example, if the enzyme tyrosinase interacts with the pollutant phenol, the LED light switches from green to red.)
The electronics are packed into a device known as a potentiostat that is barely 19mm by 19mm. (The battery is stored on the reverse side of the circuit board.)
In the experiments described in the Analyst article, Wang and his team tested sensors for three potential hazards: a toxic metal (copper); a common industrial pollutant, phenol; and an explosive (TNT). The device also has the potential to detect multiple hazards. “In the paper we used only one electrode,” noted Wang, “but you can have an array of electrodes, each with its own reagent to detect simultaneously multiple contaminants.”
The researchers believe that neoprene is a particularly good fabric on which to print sensors because it is elastic and repels water. It permits high-resolution printing with no apparent defects.
The UCSD team tested the sensor for explosives because of the security hazard highlighted by the 2000 attack on the USS Cole in Yemen. The Navy commonly checks for underwater explosives using a bulky device that a diver must carry underwater to scan the ship’s hull. Using the microsystem developed by Wang and his team, the sensor printed on a wetsuit can quickly and easily alert the diver to nearby explosives.
Wang’s lab has extensive experience printing sensors on flexible fabrics, most recently demonstrating that biosensors printed on the rubber waistband of underwear can be used continuously to monitor the vital signs of soldiers or athletes. The researchers were uncertain, however, about whether bending the printed sensors under water – and in seawater – would still let them continue functioning properly.
In the end, even underwater, and with bending and other deformations, the sensors continued to perform well. “We still need to validate and test it with the Navy,” said Wang. “While the primary security interest will be in the detection of explosives, the Navy in San Diego bay has also detected large concentrations of toxic metals from the paint on Navy ships, so in principle we should be able to print sensors that can detect metals and explosives simultaneously.”
Wang’s work in flexible sensors grew out of 20 years’ experience with innovations in glucose monitoring, ultimately in the form of flexible glucose strips that now account for a $10 billion market worldwide.
Work on the underwater sensors was supported by the Office of Naval Research.
* Wearable electrochemical sensors for in situ analysis in marine environments, Kerstin Malzahn, Joshua Ray Windmiller, Gabriela Valdés-Ramírez, Michael J. Schöning and Joseph Wang, Analyst, June 2011.
Doug Ramsey | Newswise Science News
Further reports about: > Applied Science > Autonomous underwater vehicle > Flexible Arbeitszeiten > Hazards > Navy > Printable Sensors > Sensors > UCSD > Underwater Hazards > chemical sensor > electrochemical sensors > light switch > marine environment > on-body electrochemical monitoring > security applications > thick-film electrochemical sensors > toxic metal
Energy Flow in the Nano Range
18.10.2019 | Julius-Maximilians-Universität Würzburg
Biologically inspired skin improves robots' sensory abilities (Video)
11.10.2019 | Technical University of Munich (TUM)
A very special kind of light is emitted by tungsten diselenide layers. The reason for this has been unclear. Now an explanation has been found at TU Wien (Vienna)
It is an exotic phenomenon that nobody was able to explain for years: when energy is supplied to a thin layer of the material tungsten diselenide, it begins to...
Researchers at Ludwig-Maximilians-Universitaet (LMU) in Munich have explored the initial consequences of the interaction of light with molecules on the surface of nanoscopic aerosols.
The nanocosmos is constantly in motion. All natural processes are ultimately determined by the interplay between radiation and matter. Light strikes particles...
Particles that are mere nanometers in size are at the forefront of scientific research today. They come in many different shapes: rods, spheres, cubes, vesicles, S-shaped worms and even donut-like rings. What makes them worthy of scientific study is that, being so tiny, they exhibit quantum mechanical properties not possible with larger objects.
Researchers at the Center for Nanoscale Materials (CNM), a U.S. Department of Energy (DOE) Office of Science User Facility located at DOE's Argonne National...
A new research project at the TH Mittelhessen focusses on the development of a novel light weight design concept for leisure boats and yachts. Professor Stephan Marzi from the THM Institute of Mechanics and Materials collaborates with Krake Catamarane, which is a shipyard located in Apolda, Thuringia.
The project is set up in an international cooperation with Professor Anders Biel from Karlstad University in Sweden and the Swedish company Lamera from...
Superconductivity has fascinated scientists for many years since it offers the potential to revolutionize current technologies. Materials only become superconductors - meaning that electrons can travel in them with no resistance - at very low temperatures. These days, this unique zero resistance superconductivity is commonly found in a number of technologies, such as magnetic resonance imaging (MRI).
Future technologies, however, will harness the total synchrony of electronic behavior in superconductors - a property called the phase. There is currently a...
02.10.2019 | Event News
02.10.2019 | Event News
19.09.2019 | Event News
18.10.2019 | Power and Electrical Engineering
18.10.2019 | Medical Engineering
18.10.2019 | Physics and Astronomy