Materials researchers at Penn State University have reported the highest known breakdown strength for a bulk glass ever measured. Breakdown strength, along with dielectric constant, determines how much energy can be stored in an insulating material before it fails and begins to conduct electricity.
A bulk glass with high breakdown strength and high dielectric constant would make an ideal candidate for the next generation of high energy density storage capacitors to power more efficient electric vehicles, as well as other portable and pulsed power applications.
The highest dielectric breakdown strengths for bulk glasses are typically in the 4-9MV/cm range. The breakdown strength for the tested samples were in the 12MV/cm range, which in conjunction with a relatively high permittivity, resulted in energy densities of 35 J/cm3, as compared to a maximum energy density of 10 J/cm3 for polypropylene, the most common dielectric for pulsed power applications.
“For a bulk glass, this is extraordinary,” says Nick Smith, a Ph.D. candidate in materials science and engineering at Penn State, who is lead author on the report and performed the testing. Smith used samples of 50 micron-thick commercial glass, which he etched for testing with hydrofluoric acid until the samples were only 10-20 microns thick. The resulting glass was so thin it could be flexed like a piece of plastic film, yet so delicate it could easily disintegrate if mishandled. The thinner the glass, the more electric field can be applied before failure.
The etched glass was placed in a polymer fluid for testing and up to 30,000 volts were applied. When the breakdown point was reached, electricity began to flow through the glass suddenly, with a flash and a bang that resembles a lightning bolt conducting through air. The polymer fluid was used to contain the lightning. In each case, failure occurred within 40 to 80 seconds.
The bulk glass tested is an alkali-free barium boroaluminosilicate glass produced in large quantities for flat panel displays and microelectronics packaging. Its high energy storage capability is attributed to the highly polarizable barium atoms, which contribute to the enhanced permittivity, and the alkali-free composition, which inhibits energy loss. Also a factor is the nearly defect-free quality of the glass. The specific process used to manufacture this glass yields a more flaw-free material, especially at the surface, which further enhances resistance to breakdown. Sheets of 30-micron-thick glass, which are expected to be available commercially in the near future, are likely to have even higher breakdown strength than the etched glass due to an even more uniform flaw-free surface. “This opens a potentially new market for glass,” says Smith. “We are always looking for new functionalities in glass. Ideally, manufacturing will get to a point where they can make any size sheet they need for any size capacitor.”
Contributing author Michael Lanagan points out that engineering challenges remain as they scale up from the small size glass capacitors tested to those ready for commercial production. “We’ll lose some of the energy density as we increase in volume," he says, “but we should still end up with some remarkable capacitance.”
A paper reporting their results, titled “Glass as a High Energy Density Dielectric Material,” is currently available online and in the June 2009 edition of Materials Letters. In addition to Smith, the authors are graduate student Badri Rangarajan, engineering science and mechanics, Michael T. Lanagan, associate professor of engineering science and mechanics, and Carlo G. Pantano, distinguished professor of materials science and engineering.
This research was supported by the Office of Naval Research, the Pennsylvania State University Materials Research Institute, the National Science Foundation, the Center for Optical Technologies, and Bayer MaterialScience LLC.
The Materials Research Institute coordinates the research of more than 200 materials scientists at Penn State. The Millennium Science Complex, now under construction, is a $225M facility for materials and life sciences research scheduled to open at University Park in summer 2011.
Metal too 'gummy' to cut? Draw on it with a Sharpie or glue stick, science says
19.07.2018 | Purdue University
Machine-learning predicted a superhard and high-energy-density tungsten nitride
18.07.2018 | Science China Press
For the first time ever, scientists have determined the cosmic origin of highest-energy neutrinos. A research group led by IceCube scientist Elisa Resconi, spokesperson of the Collaborative Research Center SFB1258 at the Technical University of Munich (TUM), provides an important piece of evidence that the particles detected by the IceCube neutrino telescope at the South Pole originate from a galaxy four billion light-years away from Earth.
To rule out other origins with certainty, the team led by neutrino physicist Elisa Resconi from the Technical University of Munich and multi-wavelength...
For the first time a team of researchers have discovered two different phases of magnetic skyrmions in a single material. Physicists of the Technical Universities of Munich and Dresden and the University of Cologne can now better study and understand the properties of these magnetic structures, which are important for both basic research and applications.
Whirlpools are an everyday experience in a bath tub: When the water is drained a circular vortex is formed. Typically, such whirls are rather stable. Similar...
Physicists working with Roland Wester at the University of Innsbruck have investigated if and how chemical reactions can be influenced by targeted vibrational excitation of the reactants. They were able to demonstrate that excitation with a laser beam does not affect the efficiency of a chemical exchange reaction and that the excited molecular group acts only as a spectator in the reaction.
A frequently used reaction in organic chemistry is nucleophilic substitution. It plays, for example, an important role in in the synthesis of new chemical...
Optical spectroscopy allows investigating the energy structure and dynamic properties of complex quantum systems. Researchers from the University of Würzburg present two new approaches of coherent two-dimensional spectroscopy.
"Put an excitation into the system and observe how it evolves." According to physicist Professor Tobias Brixner, this is the credo of optical spectroscopy....
Ultra-short, high-intensity X-ray flashes open the door to the foundations of chemical reactions. Free-electron lasers generate these kinds of pulses, but there is a catch: the pulses vary in duration and energy. An international research team has now presented a solution: Using a ring of 16 detectors and a circularly polarized laser beam, they can determine both factors with attosecond accuracy.
Free-electron lasers (FELs) generate extremely short and intense X-ray flashes. Researchers can use these flashes to resolve structures with diameters on the...
13.07.2018 | Event News
12.07.2018 | Event News
03.07.2018 | Event News
19.07.2018 | Earth Sciences
19.07.2018 | Power and Electrical Engineering
19.07.2018 | Materials Sciences