Process offers a simple and scalable approach to particle self-assembly
Using just electrostatic charge, common microparticles can spontaneously organize themselves into highly ordered crystalline materials--the equivalent of table salt or opals, according to a new study led by New York University chemists and published in Nature.
On the left, tiny crystals are imaged using a scanning electron microscope, distinguishing the individual building blocks, which consist of spherical polystyrene beads. On the right, larger crystals are imaged with a regular iPhone camera, revealing bright colors similar to naturally occurring opals.
Credit: Theodore Hueckel, Sacanna Lab at NYU
"Our research shines new light on self-assembly processes that could be used to manufacture new functional materials," said Stefano Sacanna, associate professor of chemistry at NYU and the study's senior author.
Self-assembly is a process in which tiny particles recognize each other and bind in a predetermined manner. These particles come together and assemble into something useful spontaneously, after a triggering event, or a change in conditions.
One approach to programming particles to assemble in a particular manner is to coat them with DNA strands; the genetic code instructs the particles on how and where to bind with one another. However, because this approach requires a considerable amount of DNA, it can be expensive and is limited to making very small samples.
In their study in Nature, the researchers took a different approach to self-assembly using a much simpler method. Instead of using DNA, they used electrostatic charge.
The process is similar to what happens when you mix salt into a pot of water, Sacanna explained. When salt is added to water, the tiny crystals dissolve into negatively charged chlorine ions and positively charged sodium ions. When the water evaporates, the positively and negatively charged particles recombine into salt crystals.
"Instead of using atomic ions like those in salt, we used colloidal particles, which are thousands of times bigger. When we mix the colloidal particles together under the right conditions, they behave like atomic ions and self-assemble into crystals," said Sacanna.
The process allows for making large quantities of materials.
"Using the particles' natural surface charge, we managed to avoid doing any of the surface chemistry typically required for such elaborate assembly, allowing us to easily create large volumes of crystals," said Theodore Hueckel, postdoctoral researcher at NYU and the study's first author.
In addition to creating salt-like colloidal materials, the researchers used self-assembly to create colloidal materials that mimic gemstones--in particular, opals. Opals are iridescent and colorful, a result of their inner crystalline microstructure and its interaction with light. In the lab, the researchers created their test-tube gemstones with very similar inner microstructures to opals.
"If you take a highly magnified image of an opal, you will see the same tiny spherical building blocks lined up in a regular fashion," added Hueckel.
Using electrostatic charge for self-assembly enables researchers to both mimic materials found in nature but also has advantages beyond what naturally occurs. For instance, they can adjust size and shape of the positively and negatively charged particles, which allows for a wide range of different crystalline structures.
"We're inspired by nature's ionic crystals, but we believe we'll move beyond their structural complexity by utilizing all of the design elements uniquely available to colloidal building blocks," said Hueckel.
In addition to Sacanna and Hueckel, study authors include Glen M. Hocky of NYU and Jérémie Palacci of University of California, San Diego. The research was funded by a National Science Foundation CAREER award (DMR-1653465) and the NSF-funded NYU Materials Research Science and Engineering Center (DMR-1420073).
Rachel Harrison | EurekAlert!
Carbon-loving materials designed to reduce industrial emissions
06.07.2020 | DOE/Oak Ridge National Laboratory
Thermophones offer new route to radically simplify array design, research shows
03.07.2020 | University of Exeter
Kiel physics team observed extremely fast electronic changes in real time in a special material class
In physics, they are currently the subject of intensive research; in electronics, they could enable completely new functions. So-called topological materials...
Solar cells based on perovskite compounds could soon make electricity generation from sunlight even more efficient and cheaper. The laboratory efficiency of these perovskite solar cells already exceeds that of the well-known silicon solar cells. An international team led by Stefan Weber from the Max Planck Institute for Polymer Research (MPI-P) in Mainz has found microscopic structures in perovskite crystals that can guide the charge transport in the solar cell. Clever alignment of these "electron highways" could make perovskite solar cells even more powerful.
Solar cells convert sunlight into electricity. During this process, the electrons of the material inside the cell absorb the energy of the light....
Empa researchers have succeeded in applying aerogels to microelectronics: Aerogels based on cellulose nanofibers can effectively shield electromagnetic radiation over a wide frequency range – and they are unrivalled in terms of weight.
Electric motors and electronic devices generate electromagnetic fields that sometimes have to be shielded in order not to affect neighboring electronic...
A promising operating mode for the plasma of a future power plant has been developed at the ASDEX Upgrade fusion device at Max Planck Institute for Plasma...
Live event – July 1, 2020 - 11:00 to 11:45 (CET)
"Automation in Aerospace Industry @ Fraunhofer IFAM"
The Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM l Stade is presenting its forward-looking R&D portfolio for the first time at...
07.07.2020 | Event News
02.07.2020 | Event News
19.05.2020 | Event News
07.07.2020 | Life Sciences
07.07.2020 | Life Sciences
07.07.2020 | Life Sciences